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Polymer Bulletin

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06.07.2020 | Original Paper

A novel synthesis of polybutadiene-based polyurethane binder and conductive graphene–polyurethane nanocomposites: a new approach to polybutadiene recycling

verfasst von: Zahra Rahmatpanah, Mir Mohammad Alavi Nikje

Erschienen in: Polymer Bulletin | Ausgabe 7/2021

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Abstract

Synthesis and characterization of a new class of polybutadiene polyol polyurethanes were investigated with three consecutive reactions, namely polybutadiene (PB) chain cleavage by a two-step oxidation reaction using meta-chloroperbenzoic acid (m-CPBA) and periodic acid (H₅IO₆) in order to prepare polybutadiene polyol precursor, continued by telechelic amine polyol synthesis by an amination reaction using diethanolamine (DEA) in the presence of sodium borohydride (NaBH₄) and finally telechelic polyurethane preparation by the reaction of synthesized polyol and toluene diisocyanate (TDI). Nanocomposites were prepared through an in situ polymerization reaction by incorporation of 1–3 wt% of graphene conductive nanosheets. Successful structural elucidation of the synthesized polymeric binder and nanocomposites was investigated by using well-known methods. TGA analysis revealed slower degradation and moderate thermal stability in higher weight percent nanocomposite. SEM images and XRD patterns resulted in fine nanoparticle distribution, lack of agglomeration and approximately constant nanoparticle size. Conductometry confirmed higher electrical conductivity data for nanocomposites by increasing graphene nanosheet contents.

Graphic abstract

Vorheriger Artikel Swelling equilibria of novel propenamide/2-acrylamido-2-methyl-1-propanesulfonic acid/guar gum/clinoptilolite biohybrid hydrogels and application as a sorbent for BV1 removal

Nächster Artikel Synthesis and evaluation of the efficiency of antibacterial hydrogel beads based on the sodium alginate–ferula gum for delayed release of quercetin

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Titel: A novel synthesis of polybutadiene-based polyurethane binder and conductive graphene–polyurethane nanocomposites: a new approach to polybutadiene recycling
verfasst von: Zahra Rahmatpanah
Mir Mohammad Alavi Nikje
Publikationsdatum: 06.07.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 7/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-020-03288-z

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