Skip to main content
Erschienen in: Journal of Materials Science 20/2021

07.04.2021 | Review

A review of main characterization methods for identifying two-dimensional organic–inorganic halide perovskites

verfasst von: Shouwu Yu, Peirong Liu, Shujuan Xiao

Erschienen in: Journal of Materials Science | Ausgabe 20/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Two-dimensional (2D) halide perovskite has attracted widespread attention because of their structural diversity and adjustable material properties. Their material properties are closely related to structural features, especially the inorganic layers (n) in each structural unit of 2D halide perovskite. The optical properties of 2D perovskite that vary with n can be used to manufacture various optoelectronic devices. This review introduces the basic structure and properties of 2D halide perovskite and then summarizes various experimental methods that can be used to directly or indirectly identify the n value, such as X-ray diffraction (XRD), grazing incidence wide-angle X-ray scattering (GIWAXS), photoluminescence spectra (PL), ultraviolet–visible spectra (UV–vis), atomic force microscopy (AFM), second harmonic generation (SHG) spectroscopy or third harmonic generation (THG) spectroscopy, etc. Moreover, the existence of different n-value phases in 2D halide perovskites has been discussed in terms of the energy transfer characteristics. Finally, we summarize advantages and disadvantages of characterization methods and some issues that still need to be explored in the 2D halide perovskite itself.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
4.
Zurück zum Zitat Kim HS, Lee CR, Im JH, Lee KB, Moehl T, Marchioro A, Moon SJ, Humphry-Baker R, Yum JH, Moser JE, Gratzel M, Park NG (2012) Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci Rep 2(591):1–7. https://doi.org/10.1038/srep00591CrossRef Kim HS, Lee CR, Im JH, Lee KB, Moehl T, Marchioro A, Moon SJ, Humphry-Baker R, Yum JH, Moser JE, Gratzel M, Park NG (2012) Lead iodide perovskite sensitized all-solid-state submicron thin film mesoscopic solar cell with efficiency exceeding 9%. Sci Rep 2(591):1–7. https://​doi.​org/​10.​1038/​srep00591CrossRef
8.
Zurück zum Zitat Brinkmann K, Zhao J, Pourdavoud N, Becker T, Hu T, Olthof S, Meerholz K, Hoffmann L, Gahlmann T, Heiderhoff R (2017) Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells. Nat Commun 8(1):1–9. https://doi.org/10.1038/ncomms13938CrossRef Brinkmann K, Zhao J, Pourdavoud N, Becker T, Hu T, Olthof S, Meerholz K, Hoffmann L, Gahlmann T, Heiderhoff R (2017) Suppressed decomposition of organometal halide perovskites by impermeable electron-extraction layers in inverted solar cells. Nat Commun 8(1):1–9. https://​doi.​org/​10.​1038/​ncomms13938CrossRef
9.
15.
Zurück zum Zitat Zhang Y, Wang P, Tang M-C, Barrit D, Ke W, Liu J, Luo T, Liu Y, Niu T, Smilgies D-M (2019) Dynamical transformation of two-dimensional perovskites with alternating cations in the interlayer space for high-performance photovoltaics. J Am Chem Soc 141(6):2684–2694. https://doi.org/10.1021/jacs.8b13104CrossRef Zhang Y, Wang P, Tang M-C, Barrit D, Ke W, Liu J, Luo T, Liu Y, Niu T, Smilgies D-M (2019) Dynamical transformation of two-dimensional perovskites with alternating cations in the interlayer space for high-performance photovoltaics. J Am Chem Soc 141(6):2684–2694. https://​doi.​org/​10.​1021/​jacs.​8b13104CrossRef
21.
Zurück zum Zitat Lee S, Kim DB, Hamilton I, Daboczi M, Nam YS, Lee BR, Zhao B, Jang CH, Friend RH, Kim JS, Song MH (2018) Control of interface defects for efficient and stable quasi-2D perovskite light-emitting diodes using nickel oxide hole injection layer. Adv Sci 5(11):1801350. https://doi.org/10.1002/advs.201801350CrossRef Lee S, Kim DB, Hamilton I, Daboczi M, Nam YS, Lee BR, Zhao B, Jang CH, Friend RH, Kim JS, Song MH (2018) Control of interface defects for efficient and stable quasi-2D perovskite light-emitting diodes using nickel oxide hole injection layer. Adv Sci 5(11):1801350. https://​doi.​org/​10.​1002/​advs.​201801350CrossRef
24.
Zurück zum Zitat Liu Y, Cui J, Du K, Tian H, He Z, Zhou Q, Yang Z, Deng Y, Chen D, Zuo X, Ren Y, Wang L, Zhu H, Zhao B, Di D, Wang J, Friend RH, Jin Y (2019) Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures. Nat Photonics 13(11):760–764. https://doi.org/10.1038/s41566-019-0505-4CrossRef Liu Y, Cui J, Du K, Tian H, He Z, Zhou Q, Yang Z, Deng Y, Chen D, Zuo X, Ren Y, Wang L, Zhu H, Zhao B, Di D, Wang J, Friend RH, Jin Y (2019) Efficient blue light-emitting diodes based on quantum-confined bromide perovskite nanostructures. Nat Photonics 13(11):760–764. https://​doi.​org/​10.​1038/​s41566-019-0505-4CrossRef
28.
Zurück zum Zitat Zhu L, Zhang H, Lu Q, Wang Y, Deng Z, Hu Y, Lou Z, Cui Q, Hou Y, Teng F (2018) Synthesis of ultrathin two-dimensional organic–inorganic hybrid perovskite nanosheets for polymer field-effect transistors. J Mater Chem C 6(15):3945–3950. https://doi.org/10.1039/C8TC00289DCrossRef Zhu L, Zhang H, Lu Q, Wang Y, Deng Z, Hu Y, Lou Z, Cui Q, Hou Y, Teng F (2018) Synthesis of ultrathin two-dimensional organic–inorganic hybrid perovskite nanosheets for polymer field-effect transistors. J Mater Chem C 6(15):3945–3950. https://​doi.​org/​10.​1039/​C8TC00289DCrossRef
43.
Zurück zum Zitat Smith IC, Hoke ET, Solis-Ibarra D, McGehee MD, Karunadasa HI (2014) A layered hybrid perovskite solar-cell absorber with enhanced moisture stability. Angew Chem Int Ed 53(42):11232–11235CrossRef Smith IC, Hoke ET, Solis-Ibarra D, McGehee MD, Karunadasa HI (2014) A layered hybrid perovskite solar-cell absorber with enhanced moisture stability. Angew Chem Int Ed 53(42):11232–11235CrossRef
45.
Zurück zum Zitat Sutton RJ, Eperon GE, Miranda L, Parrott ES, Kamino BA, Patel JB, Hörantner MT, Johnston MB, Haghighirad AA, Moore DT, Snaith HJ (2016) Bandgap-tunable cesium lead halide perovskites with high thermal stability for efficient solar cells. Adv Energy Mater 6(8):1502458. https://doi.org/10.1002/aenm.201502458CrossRef Sutton RJ, Eperon GE, Miranda L, Parrott ES, Kamino BA, Patel JB, Hörantner MT, Johnston MB, Haghighirad AA, Moore DT, Snaith HJ (2016) Bandgap-tunable cesium lead halide perovskites with high thermal stability for efficient solar cells. Adv Energy Mater 6(8):1502458. https://​doi.​org/​10.​1002/​aenm.​201502458CrossRef
48.
Zurück zum Zitat Soe CMM, Stoumpos CC, Kepenekian M, Traoré B, Tsai H, Nie W, Wang B, Katan C, Seshadri R, Mohite AD (2017) New type of 2D perovskites with alternating cations in the interlayer space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, properties, and photovoltaic performance. J Am Chem Soc 139(45):16297–16309. https://doi.org/10.1021/jacs.7b09096CrossRef Soe CMM, Stoumpos CC, Kepenekian M, Traoré B, Tsai H, Nie W, Wang B, Katan C, Seshadri R, Mohite AD (2017) New type of 2D perovskites with alternating cations in the interlayer space, (C(NH2)3)(CH3NH3)nPbnI3n+1: Structure, properties, and photovoltaic performance. J Am Chem Soc 139(45):16297–16309. https://​doi.​org/​10.​1021/​jacs.​7b09096CrossRef
54.
Zurück zum Zitat Aurivillius B (1949) Mixed bismuth oxides with layer lattices I. The structure type of CaNb2Bi2O9. Arkiv kemi 1:463–480 Aurivillius B (1949) Mixed bismuth oxides with layer lattices I. The structure type of CaNb2Bi2O9. Arkiv kemi 1:463–480
65.
Zurück zum Zitat Koh TM, Shanmugam V, Schlipf J, Oesinghaus L, Müller-Buschbaum P, Ramakrishnan N, Swamy V, Mathews N, Boix PP, Mhaisalkar SG (2016) Nanostructuring mixed-dimensional perovskites: A route toward tunable, efficient photovoltaics. Adv Mater 28(19):3653–3661. https://doi.org/10.1002/adma.201506141CrossRef Koh TM, Shanmugam V, Schlipf J, Oesinghaus L, Müller-Buschbaum P, Ramakrishnan N, Swamy V, Mathews N, Boix PP, Mhaisalkar SG (2016) Nanostructuring mixed-dimensional perovskites: A route toward tunable, efficient photovoltaics. Adv Mater 28(19):3653–3661. https://​doi.​org/​10.​1002/​adma.​201506141CrossRef
72.
77.
Zurück zum Zitat Hintermayr VA, Richter AF, Ehrat F, Döblinger M, Vanderlinden W, Sichert JA, Tong Y, Polavarapu L, Feldmann J, Urban AS (2016) Tuning the optical properties of perovskite nanoplatelets through composition and thickness by ligand-assisted exfoliation. Adv Mater 28(43):9478–9485. https://doi.org/10.1002/adma.201602897CrossRef Hintermayr VA, Richter AF, Ehrat F, Döblinger M, Vanderlinden W, Sichert JA, Tong Y, Polavarapu L, Feldmann J, Urban AS (2016) Tuning the optical properties of perovskite nanoplatelets through composition and thickness by ligand-assisted exfoliation. Adv Mater 28(43):9478–9485. https://​doi.​org/​10.​1002/​adma.​201602897CrossRef
78.
Zurück zum Zitat Zhao L, Rolston N, Lee KM, Zhao X, Reyes-Martinez MA, Tran NL, Yeh Y-W, Yao N, Scholes GD, Loo Y-L (2018) Influence of bulky organo-ammonium halide additive choice on the flexibility and efficiency of perovskite light-emitting devices. Adv Funct Mater 28(31):1802060. https://doi.org/10.1002/adfm.201802060CrossRef Zhao L, Rolston N, Lee KM, Zhao X, Reyes-Martinez MA, Tran NL, Yeh Y-W, Yao N, Scholes GD, Loo Y-L (2018) Influence of bulky organo-ammonium halide additive choice on the flexibility and efficiency of perovskite light-emitting devices. Adv Funct Mater 28(31):1802060. https://​doi.​org/​10.​1002/​adfm.​201802060CrossRef
79.
80.
Zurück zum Zitat Soe CMM, Nie W, Stoumpos CC, Tsai H, Blancon JC, Liu F, Even J, Marks TJ, Mohite AD, Kanatzidis MG (2018) Understanding film formation morphology and orientation in high member 2D ruddlesden–popper perovskites for high-efficiency solar cells. Adv Energy Mater 8(1):1700979. https://doi.org/10.1002/aenm.201700979CrossRef Soe CMM, Nie W, Stoumpos CC, Tsai H, Blancon JC, Liu F, Even J, Marks TJ, Mohite AD, Kanatzidis MG (2018) Understanding film formation morphology and orientation in high member 2D ruddlesden–popper perovskites for high-efficiency solar cells. Adv Energy Mater 8(1):1700979. https://​doi.​org/​10.​1002/​aenm.​201700979CrossRef
88.
Zurück zum Zitat Tsai H, Nie W, Blancon JC, Stoumpos CC, Asadpour R, Harutyunyan B, Neukirch AJ, Verduzco R, Crochet JJ, Tretiak S, Pedesseau L, Even J, Alam MA, Gupta G, Lou J, Ajayan PM, Bedzyk MJ, Kanatzidis MG (2016) High-efficiency two-dimensional ruddlesden-popper perovskite solar cells. Nature 536(7616):312–316. https://doi.org/10.1038/nature18306CrossRef Tsai H, Nie W, Blancon JC, Stoumpos CC, Asadpour R, Harutyunyan B, Neukirch AJ, Verduzco R, Crochet JJ, Tretiak S, Pedesseau L, Even J, Alam MA, Gupta G, Lou J, Ajayan PM, Bedzyk MJ, Kanatzidis MG (2016) High-efficiency two-dimensional ruddlesden-popper perovskite solar cells. Nature 536(7616):312–316. https://​doi.​org/​10.​1038/​nature18306CrossRef
94.
105.
Zurück zum Zitat Wei M, de Arquer FPG, Walters G, Yang Z, Quan LN, Kim Y, Sabatini R, Quintero-Bermudez R, Gao L, Fan JZ, Fan F, Gold-Parker A, Toney MF, Sargent EH (2019) Ultrafast narrowband exciton routing within layered perovskite nanoplatelets enables low-loss luminescent solar concentrators. Nat Energy 4(3):197–205. https://doi.org/10.1038/s41560-018-0313-yCrossRef Wei M, de Arquer FPG, Walters G, Yang Z, Quan LN, Kim Y, Sabatini R, Quintero-Bermudez R, Gao L, Fan JZ, Fan F, Gold-Parker A, Toney MF, Sargent EH (2019) Ultrafast narrowband exciton routing within layered perovskite nanoplatelets enables low-loss luminescent solar concentrators. Nat Energy 4(3):197–205. https://​doi.​org/​10.​1038/​s41560-018-0313-yCrossRef
106.
Zurück zum Zitat Hu J, Oswald IWH, Stuard SJ, Nahid MM, Zhou N, Williams OF, Guo Z, Yan L, Hu H, Chen Z, Xiao X, Lin Y, Yang Z, Huang J, Moran AM, Ade H, Neilson JR, You W (2019) Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites. Nat Commun 10(1):1276. https://doi.org/10.1038/s41467-019-08980-xCrossRef Hu J, Oswald IWH, Stuard SJ, Nahid MM, Zhou N, Williams OF, Guo Z, Yan L, Hu H, Chen Z, Xiao X, Lin Y, Yang Z, Huang J, Moran AM, Ade H, Neilson JR, You W (2019) Synthetic control over orientational degeneracy of spacer cations enhances solar cell efficiency in two-dimensional perovskites. Nat Commun 10(1):1276. https://​doi.​org/​10.​1038/​s41467-019-08980-xCrossRef
110.
113.
Zurück zum Zitat Rebecca LWX, Saheed MSM, Saheed MSM, Burhanudin ZA Formation of quasi-2D layered crystallite using long chain halide to form hybrid perovskite film. In: 2018 IEEE 7th International Conference on Photonics (ICP), 2018. IEEE, pp 1–3 Rebecca LWX, Saheed MSM, Saheed MSM, Burhanudin ZA Formation of quasi-2D layered crystallite using long chain halide to form hybrid perovskite film. In: 2018 IEEE 7th International Conference on Photonics (ICP), 2018. IEEE, pp 1–3
114.
Zurück zum Zitat Zhang F, Kim DH, Lu H, Park JS, Larson BW, Hu J, Gao L, Xiao C, Reid OG, Chen X, Zhao Q, Ndione PF, Berry JJ, You W, Walsh A, Beard MC, Zhu K (2019) Enhanced charge transport in 2D perovskites via fluorination of organic cation. J Am Chem Soc 141(14):5972–5979. https://doi.org/10.1021/jacs.9b00972CrossRef Zhang F, Kim DH, Lu H, Park JS, Larson BW, Hu J, Gao L, Xiao C, Reid OG, Chen X, Zhao Q, Ndione PF, Berry JJ, You W, Walsh A, Beard MC, Zhu K (2019) Enhanced charge transport in 2D perovskites via fluorination of organic cation. J Am Chem Soc 141(14):5972–5979. https://​doi.​org/​10.​1021/​jacs.​9b00972CrossRef
122.
Zurück zum Zitat Blancon JC, Stier AV, Tsai H, Nie W, Stoumpos CC, Traore B, Pedesseau L, Kepenekian M, Katsutani F, Noe GT, Kono J, Tretiak S, Crooker SA, Katan C, Kanatzidis MG, Crochet JJ, Even J, Mohite AD (2018) Scaling law for excitons in 2D perovskite quantum wells. Nat Commun 9(1):2254. https://doi.org/10.1038/s41467-018-04659-xCrossRef Blancon JC, Stier AV, Tsai H, Nie W, Stoumpos CC, Traore B, Pedesseau L, Kepenekian M, Katsutani F, Noe GT, Kono J, Tretiak S, Crooker SA, Katan C, Kanatzidis MG, Crochet JJ, Even J, Mohite AD (2018) Scaling law for excitons in 2D perovskite quantum wells. Nat Commun 9(1):2254. https://​doi.​org/​10.​1038/​s41467-018-04659-xCrossRef
126.
Zurück zum Zitat Leng K, Abdelwahab I, Verzhbitskiy I, Telychko M, Chu L, Fu W, Chi X, Guo N, Chen Z, Chen Z, Zhang C, Xu QH, Lu J, Chhowalla M, Eda G, Loh KP (2018) Molecularly thin two-dimensional hybrid perovskites with tunable optoelectronic properties due to reversible surface relaxation. Nature Mater 17(10):908–914. https://doi.org/10.1038/s41563-018-0164-8CrossRef Leng K, Abdelwahab I, Verzhbitskiy I, Telychko M, Chu L, Fu W, Chi X, Guo N, Chen Z, Chen Z, Zhang C, Xu QH, Lu J, Chhowalla M, Eda G, Loh KP (2018) Molecularly thin two-dimensional hybrid perovskites with tunable optoelectronic properties due to reversible surface relaxation. Nature Mater 17(10):908–914. https://​doi.​org/​10.​1038/​s41563-018-0164-8CrossRef
127.
Zurück zum Zitat Shen Y-R (1984) The principles of nonlinear optics. Wiley Press, New York Shen Y-R (1984) The principles of nonlinear optics. Wiley Press, New York
128.
Metadaten
Titel
A review of main characterization methods for identifying two-dimensional organic–inorganic halide perovskites
verfasst von
Shouwu Yu
Peirong Liu
Shujuan Xiao
Publikationsdatum
07.04.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 20/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-021-06038-2

Weitere Artikel der Ausgabe 20/2021

Journal of Materials Science 20/2021 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.