A sustainable filtering material for efficient removal of volatile organic compounds from their aqueous mixtures

Volatile organic compounds (VOCs) are hazardous to the environment and human health. Thus, tremendous effort has gone into developing effective/efficient techniques for separation of VOCs from their aqueous mixtures. In this work, a simple and versatile strategy was proposed to fabricate a new material for hydrophobic VOC separations, in which a self-assembling hydrogel consisting of TEMPO-oxidized cellulose nanofibers (TOCNs) and cationic guar gum (CGG) was used. Specifically, TOCNs and CGG were deposited onto a filter paper via a layer-by-layer procedure, resulting in a TOCN/CGG hydrogel-coated filtering material, in which no crosslinking agent was used. The hydrogel is spontaneously formed by electrostatic interactions and hydrogen bonding. The as-prepared filtering material exhibits oil-repellence and underwater oleophobicity resulting from the formation of hydration layer on hydrogel, thus demonstrating good VOC separation performance. One-layer of TOCN/CGG hydrogel coating (dried mass of 0.032 g·m^− 2) was proved to realize the VOC separation (separation efficiency of around 99 % and water flux of as high as 905.14 L·m^− 2·h^− 1). Further increase of the hydrogel layers has negligible influence on the separation efficiency although it decreases the water flux. This filtering material also exhibits good stability during recycling. Consequently, this TOCN/CGG self-assembling hydrogel-coated filtering material has great potential in VOCs-contaminated wastewater treatment.