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15.03.2024 | Original Article

Acetylene/argon mixture plasma to build ultrathin carbon bridge of CF_x/C/MnO₂ for high-rate lithium primary battery

verfasst von: Da-Wei Zou, Xing-Guang Fu, Gao-Bang Chen, Yi-Fan Liu, Bao-Shan Wu, Xian Jian

Erschienen in: Rare Metals | Ausgabe 6/2024

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Abstract

Forming an ultrathin conducting layer on a fluorinated carbon (CF_x) surface for reducing severe electrochemical polarization in lithium/fluorinated carbon primary batteries (Li/CF_x) remains a considerable challenge for achieving batteries with excellent rate capability. Herein, CF_x was modified by using acetylene/argon mixture plasma combined with MnO₂ particles. The CF_x/C/MnO₂ composite effectively reduced the voltage hysteresis and improved the electrochemical performance of Li/CF_x. The excellent rate performance of CF_x/C/MnO₂ was due to the high electrochemical activity provided by the atomic-scale conductive carbon layer and ultrafine MnO₂ particles. Compared with pristine CF_x, the charge transfer resistance of the optimized CF_x/C/MnO₂ decreased from 218.5 to 48.2 Ω, the discharge rate increased from 2C to 10C, and the power density increased from 3.11 to 13.44 kW·g⁻¹. The intrinsic reason for the enhanced rate performance was attributed to the fact that the ultrathin carbon layer acted as a conductive bridge to reduce the voltage hysteresis at the initial stage of the Li/CF_x discharge, and the high electrochemical activity of the ultrafine MnO₂ particles provided a faster lithium-ion diffusion rate.

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Vorheriger Artikel Carbon dots-derived three-dimensional-ordered macroporous host with high penetrability and catalytic activity for LSBs under lean electrolyte

Nächster Artikel Structural regulation of coal-derived hard carbon anode for sodium-ion batteries via pre-oxidation

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Titel: Acetylene/argon mixture plasma to build ultrathin carbon bridge of CFx/C/MnO2 for high-rate lithium primary battery
verfasst von: Da-Wei Zou
Xing-Guang Fu
Gao-Bang Chen
Yi-Fan Liu
Bao-Shan Wu
Xian Jian
Publikationsdatum: 15.03.2024
Verlag: Nonferrous Metals Society of China
Erschienen in: Rare Metals / Ausgabe 6/2024
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02599-0

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