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2019 | OriginalPaper | Buchkapitel

Activation of Lipase-Catalyzed Reactions Using Ionic Liquids for Organic Synthesis

verfasst von : Toshiyuki Itoh

Erschienen in: Application of Ionic Liquids in Biotechnology

Verlag: Springer International Publishing

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Abstract

The use of ionic liquids to replace organic or aqueous solvents in biocatalysis processes has recently received great attention, and much progress has been made in this area; the lipase-catalyzed reactions are the most successful. Recent developments in the application of ionic liquids as solvents in lipase-catalyzed reactions for organic synthesis are reviewed, focusing on the ionic liquid mediated activation method of lipase-catalyzed reactions.

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Vorheriges Kapitel Ionic Liquid Pretreatment of Lignocellulosic Biomass for Enhanced Enzymatic Delignification

Nächstes Kapitel Whole-Cell Biocatalysis in Ionic Liquids

[C2mim]+

1-Ethyl-3-methylimidazolium

[C4mim]+

1-Butyl-3-methylimidazolium

[C4dmim]+

1-Butyl-2,3-dimethylimidazolium

[HOPmim]+

1-Methyl-3-(3-hydroxy)propylimidazolium

[3-Ph-C3mim]+

1-Methyl-3(3-phenylpropyl)imidazolium

[C16tam]+

N-Cetyl-N,N,N-trimethylammonium

[Me(OCH2CH2)3-Et-Pip]+

Ethyl (2-(2-methoxyethoxy)ethoxy)ethylpiperidin-1-ium

[Me(OCH2CH2)3-Et3N]+

Triethyl (2-(2-methoxyethoxy)ethoxy)ethylammonium

[Me(OCH2CH2)3eim]+

1-Ethyl-3-(2-(2-methoxyethoxy)ethoxy)ethylimidazolium

L-Pro-Me

(S)-1-Butyl-2-methyl-3-(pyrrolidin-2-ylmethyl)-1H-imidazol-3-ium

L-Pro-H

(S)-1-Butyl-3-(pyrrolidin-2-ylmethyl)-1H-imidazol-3-ium

D-Pro-H

(R)-1-Butyl-3-(pyrrolidin-2-ylmethyl)-1H-imidazol-3-ium

D-Pro-Me

(R)-1-Butyl-2-methyl-3-(pyrrolidin-2-ylmethyl)-1H-imidazol-3-ium

[N221MEM]+

N,N-Diethyl-N-methyl-N-(2-methoxyethoxymethyl)ammonium

[N2222]+

N,N,N-Tetraethylammonium

[P444ME]+

Tributyl(2-methoxyethyl)phosphonium

[P444MEM]+

Tributyl(2-methoxyethoxyethyl)phosphonium

[TAC1]+

Tris(diethylamino)cyclopropenium

[TEA]+

N,N,N,N-Tetraethylammonium

[PP22]+

N,N-Diethylpiperidinium

[Tz1]+

1-Butyl-3-methyltriazolium

[Tz2]+

1-Benzyl-3-methyltriazolium

[Tz3]+

1-Butyl-3-methyl-5-(hydroxymethyl)triazolium

[OAc]−

Acetate

[BF4]−

Tetrafluoroborate

[NO3]–

Nitrate

[OTf]−

Trifluoromethanesulfonate

[Tf2N]−

Bis(trifluoromethylsulfonyl)amide. [Tf₂N] is widely known as “bis(trifluoromethylsulfonyl)imide.” However, “imide” means “an amido compound which is connected with two carbonyl groups,” so [Tf₂N] should be labelled as “bis(trifluoromethylsulfonyl)amide” according to the IUPAC rule

ISCB1

Potassium 3,5-bis(2-(2-(2-ethoxyethoxy)ethoxy)ethoxy)benzoate (ISCB1)

IL1

1-Butyl-2,3-dimethylimidazolium 3,6,9,12,15,18,21,24,27,30-decaoxacetyltriacontyl sulfate (cetyl-PEG10 sulfate)

DES

Deep eutectic solvent

AMMOENG 102™

See Fig. 22

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Titel: Activation of Lipase-Catalyzed Reactions Using Ionic Liquids for Organic Synthesis
verfasst von: Toshiyuki Itoh
Verlag: Springer International Publishing
Buch: Application of Ionic Liquids in Biotechnology
Print ISBN: 978-3-030-23080-7

Electronic ISBN: 978-3-030-23081-4

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/10_2018_62

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