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2015 | OriginalPaper | Buchkapitel

3. Adsorbents for CO2 Capture

verfasst von : Anne Elise Creamer, Bin Gao

Erschienen in: Carbon Dioxide Capture: An Effective Way to Combat Global Warming

Verlag: Springer International Publishing

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Abstract

Solid adsorbents are promising for applications in post-combustion CO2 capture scenarios. Some adsorbents include zeolites, activated carbon, carbon nanotubes, zeolites, and silicon-based adsorbents. The materials are characterized by their surface functional groups, porosity, surface area, pore size, metal ligands, and electrostatic interactions to determine their potential as adsorbents for CO2. Organic adsorbents are promising for low temperature CO2 adsorption because of their surface properties, such as high surface area, which enables it to be modified by adding additional metals and functional groups. Carbonaceous materials can be physically or chemically activated in order to enhance capture. Biochar, a material known for its benefits to agriculture, can also be used to capture CO2. Modified Organic Frameworks (MOFs) combine metal ions and organic ligands to produce a crystalline porous network that is capable of selectively binding molecules at high capacity. Other solid adsorbents include zeolites, clays, silica-based adsorbents, and metal oxide-based adsorbents.

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Literatur
Zurück zum Zitat Bae YS, Hauser BG, Farha OK, Hupp JT, Snurr RQ (2011) Enhancement of CO2/CH4 selectivity in metal-organic frameworks containing lithium cations. Microporous Mesoporous Mater 141(1–3):231–235CrossRef Bae YS, Hauser BG, Farha OK, Hupp JT, Snurr RQ (2011) Enhancement of CO2/CH4 selectivity in metal-organic frameworks containing lithium cations. Microporous Mesoporous Mater 141(1–3):231–235CrossRef
Zurück zum Zitat Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM (2008) High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science 319(5865):939–943CrossRef Banerjee R, Phan A, Wang B, Knobler C, Furukawa H, O’Keeffe M, Yaghi OM (2008) High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science 319(5865):939–943CrossRef
Zurück zum Zitat Barrow CJ (2012) Biochar: potential for countering land degradation and for improving agriculture. Appl Geogr 34:21–28CrossRef Barrow CJ (2012) Biochar: potential for countering land degradation and for improving agriculture. Appl Geogr 34:21–28CrossRef
Zurück zum Zitat Bastin L, Barcia PS, Hurtado EJ, Silva JAC, Rodrigues AE, Chen BL (2008) A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. J Phys Chem C 112(5):1575–1581CrossRef Bastin L, Barcia PS, Hurtado EJ, Silva JAC, Rodrigues AE, Chen BL (2008) A microporous metal-organic framework for separation of CO2/N-2 and CO2/CH4 by fixed-bed adsorption. J Phys Chem C 112(5):1575–1581CrossRef
Zurück zum Zitat Brasquet C, Rousseau B, Estrade-Szwarckopf H, Le Cloirec P (2000) Observation of activated carbon fibers with SEM and AFM correlation with adsorption data in aqueous solution. Carbon 38(3):407–422CrossRef Brasquet C, Rousseau B, Estrade-Szwarckopf H, Le Cloirec P (2000) Observation of activated carbon fibers with SEM and AFM correlation with adsorption data in aqueous solution. Carbon 38(3):407–422CrossRef
Zurück zum Zitat Casco ME, Martinez-Escandell M, Silvestre-Albero J, Rodriguez-Reinoso F (2014) Effect of the porous structure in carbon materials for CO2 capture at atmospheric and high-pressure. Carbon 67:230–235CrossRef Casco ME, Martinez-Escandell M, Silvestre-Albero J, Rodriguez-Reinoso F (2014) Effect of the porous structure in carbon materials for CO2 capture at atmospheric and high-pressure. Carbon 67:230–235CrossRef
Zurück zum Zitat Chang YC, Chen DH (2006) Recovery of gold(III) ions by a chitosan-coated magnetic nano-adsorbent. Gold Bull 39(3):98–102CrossRef Chang YC, Chen DH (2006) Recovery of gold(III) ions by a chitosan-coated magnetic nano-adsorbent. Gold Bull 39(3):98–102CrossRef
Zurück zum Zitat Che SN, Lund K, Tatsumi T, Iijima S, Joo SH, Ryoo R, Terasaki O (2003) Direct observation of 3D mesoporous structure by scanning electron microscopy (SEM): SBA-15 silica and CMK-5 carbon. Angew Chem Int Ed 42(19):2182–2185CrossRef Che SN, Lund K, Tatsumi T, Iijima S, Joo SH, Ryoo R, Terasaki O (2003) Direct observation of 3D mesoporous structure by scanning electron microscopy (SEM): SBA-15 silica and CMK-5 carbon. Angew Chem Int Ed 42(19):2182–2185CrossRef
Zurück zum Zitat Creamer AE, Gao B, Zhang M (2014) Carbon dioxide capture using biochar produced from sugarcane bagasse and hickory wood. Chem Eng J 249:174–179CrossRef Creamer AE, Gao B, Zhang M (2014) Carbon dioxide capture using biochar produced from sugarcane bagasse and hickory wood. Chem Eng J 249:174–179CrossRef
Zurück zum Zitat D’alessandro DM, Smit B, Long JR (2010) Carbon dioxide capture: prospects for new materials. Angew Chem Int Ed 49(35):6058–6082CrossRef D’alessandro DM, Smit B, Long JR (2010) Carbon dioxide capture: prospects for new materials. Angew Chem Int Ed 49(35):6058–6082CrossRef
Zurück zum Zitat Dogan AU, Dogan M, Onal M, Sarikaya Y, Aburub A, Wurster DE (2006) Baseline studies of the clay minerals society source clays: specific surface area by the brunauer emmett teller (BET) method. Clays Clay Miner 54(1):62–66CrossRef Dogan AU, Dogan M, Onal M, Sarikaya Y, Aburub A, Wurster DE (2006) Baseline studies of the clay minerals society source clays: specific surface area by the brunauer emmett teller (BET) method. Clays Clay Miner 54(1):62–66CrossRef
Zurück zum Zitat Drage TC, Blackman JM, Pevida C, Snape CE (2009) Evaluation of activated carbon adsorbents for CO2 capture in gasification. Energy Fuels 23:2790–2796CrossRef Drage TC, Blackman JM, Pevida C, Snape CE (2009) Evaluation of activated carbon adsorbents for CO2 capture in gasification. Energy Fuels 23:2790–2796CrossRef
Zurück zum Zitat Glaser B, Parr M, Braun C, Kopolo G (2009) Biochar is carbon negative. Nat Geosci 2(1):2–2CrossRef Glaser B, Parr M, Braun C, Kopolo G (2009) Biochar is carbon negative. Nat Geosci 2(1):2–2CrossRef
Zurück zum Zitat Goh KH, Lim TT, Dong Z (2008) Application of layered double hydroxides for removal of oxyanions: a review. Water Res 42(6–7):1343–1368CrossRef Goh KH, Lim TT, Dong Z (2008) Application of layered double hydroxides for removal of oxyanions: a review. Water Res 42(6–7):1343–1368CrossRef
Zurück zum Zitat Hicks JC, Drese JH, Fauth DJ, Gray ML, Qi GG, Jones CW (2008) Designing adsorbents for CO(2) capture from flue gas-hyperbranched aminosilicas capable of capturing CO(2) reversibly. J Am Chem Soc 130(10):2902–2903CrossRef Hicks JC, Drese JH, Fauth DJ, Gray ML, Qi GG, Jones CW (2008) Designing adsorbents for CO(2) capture from flue gas-hyperbranched aminosilicas capable of capturing CO(2) reversibly. J Am Chem Soc 130(10):2902–2903CrossRef
Zurück zum Zitat Jeffery S, Verheijen FGA, van der Velde M, Bastos AC (2011) A quantitative review of the effects of biochar application to soils on crop productivity using meta-analysis. Agric Ecosyst Environ 144(1):175–187CrossRef Jeffery S, Verheijen FGA, van der Velde M, Bastos AC (2011) A quantitative review of the effects of biochar application to soils on crop productivity using meta-analysis. Agric Ecosyst Environ 144(1):175–187CrossRef
Zurück zum Zitat Lee JW, Kidder M, Evans BR, Paik S, Buchanan AC, Garten CT, Brown RC (2010) Characterization of biochars produced from cornstovers for soil amendment. Environ Sci Technol 44(20):7970–7974CrossRef Lee JW, Kidder M, Evans BR, Paik S, Buchanan AC, Garten CT, Brown RC (2010) Characterization of biochars produced from cornstovers for soil amendment. Environ Sci Technol 44(20):7970–7974CrossRef
Zurück zum Zitat Li J (2011) Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord Chem Rev 255:1791–1823 Li J (2011) Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord Chem Rev 255:1791–1823
Zurück zum Zitat Li JR, Ma YG, McCarthy MC, Sculley J, Yu JM, Jeong HK, Balbuena PB, Zhou HC (2011) Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord Chem Rev 255(15–16):1791–1823CrossRef Li JR, Ma YG, McCarthy MC, Sculley J, Yu JM, Jeong HK, Balbuena PB, Zhou HC (2011) Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks. Coord Chem Rev 255(15–16):1791–1823CrossRef
Zurück zum Zitat Li ZS, Cai NS, Huang YY, Han HJ (2005) Synthesis, experimental studies, and analysis of a new calcium-based carbon dioxide absorbent. Energy Fuels 19(4):1447–1452CrossRef Li ZS, Cai NS, Huang YY, Han HJ (2005) Synthesis, experimental studies, and analysis of a new calcium-based carbon dioxide absorbent. Energy Fuels 19(4):1447–1452CrossRef
Zurück zum Zitat Liu J (2012) Progress in adsorption-based CO2 capture by metal-organic frameworks. Chem Soc Rev 41:2308–2322 Liu J (2012) Progress in adsorption-based CO2 capture by metal-organic frameworks. Chem Soc Rev 41:2308–2322
Zurück zum Zitat Lowell S, Shields JE (1991) Powder surface area and porosity, 3rd edn. Chapman & Hall, LondonCrossRef Lowell S, Shields JE (1991) Powder surface area and porosity, 3rd edn. Chapman & Hall, LondonCrossRef
Zurück zum Zitat Lu CY, Bai HL, Wu BL, Su FS, Fen-Hwang J (2008) Comparative study of CO2 capture by carbon nanotubes, activated carbons, and zeolites. Energy Fuels 22(5):3050–3056CrossRef Lu CY, Bai HL, Wu BL, Su FS, Fen-Hwang J (2008) Comparative study of CO2 capture by carbon nanotubes, activated carbons, and zeolites. Energy Fuels 22(5):3050–3056CrossRef
Zurück zum Zitat Lu H, Reddy EP, Smirniotis PG (2006) Calcium oxide based sorbents for capture of carbon dioxide at high temperatures. Ind Eng Chem Res 45(11):3944–3949CrossRef Lu H, Reddy EP, Smirniotis PG (2006) Calcium oxide based sorbents for capture of carbon dioxide at high temperatures. Ind Eng Chem Res 45(11):3944–3949CrossRef
Zurück zum Zitat Matovic D (2011) Biochar as a viable carbon sequestration option: global and Canadian perspective. Energy 36(4):2011–2016CrossRef Matovic D (2011) Biochar as a viable carbon sequestration option: global and Canadian perspective. Energy 36(4):2011–2016CrossRef
Zurück zum Zitat Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O’Keeffe M, Yaghi OM (2010) Synthesis, structure, and carbon dioxide capture properties of zeolitic imidazolate frameworks. Acc Chem Res 43(1):58–67CrossRef Phan A, Doonan CJ, Uribe-Romo FJ, Knobler CB, O’Keeffe M, Yaghi OM (2010) Synthesis, structure, and carbon dioxide capture properties of zeolitic imidazolate frameworks. Acc Chem Res 43(1):58–67CrossRef
Zurück zum Zitat Pires J, de Carvalho MB, Carvalho AP, Guil JM, Perdigon-Melon JA (2000) Heats of adsorption of N-hexane by thermal gravimetry with differential scanning calorimetry (TG-DSC): a tool for textural characterization of pillared clays. Clays Clay Miner 48(3):385–391CrossRef Pires J, de Carvalho MB, Carvalho AP, Guil JM, Perdigon-Melon JA (2000) Heats of adsorption of N-hexane by thermal gravimetry with differential scanning calorimetry (TG-DSC): a tool for textural characterization of pillared clays. Clays Clay Miner 48(3):385–391CrossRef
Zurück zum Zitat Reddy MKR, Xu ZP, Lu GQ, da Costa JCD (2006) Layered double hydroxides for CO2 capture: structure evolution and regeneration. Ind Eng Chem Res 45(22):7504–7509CrossRef Reddy MKR, Xu ZP, Lu GQ, da Costa JCD (2006) Layered double hydroxides for CO2 capture: structure evolution and regeneration. Ind Eng Chem Res 45(22):7504–7509CrossRef
Zurück zum Zitat Samanta A, Zhao A, Shimizu GKH, Sarkar P, Gupta R (2012) Post-combustion CO2 capture using solid sorbents: a review. Ind Eng Chem Res 51(4):1438–1463CrossRef Samanta A, Zhao A, Shimizu GKH, Sarkar P, Gupta R (2012) Post-combustion CO2 capture using solid sorbents: a review. Ind Eng Chem Res 51(4):1438–1463CrossRef
Zurück zum Zitat Schneemann A, Bon V, Schwedler I, Senkovska I, Kaskel S, Fischer RA (2014) Flexible metal-organic frameworks. Chem Soc Rev 43(16):6062–6096CrossRef Schneemann A, Bon V, Schwedler I, Senkovska I, Kaskel S, Fischer RA (2014) Flexible metal-organic frameworks. Chem Soc Rev 43(16):6062–6096CrossRef
Zurück zum Zitat Sevilla M (2011) Sustainable porous carbons with a superior performance for CO2 capture. Energy Environ Sci 4:1765–1771 Sevilla M (2011) Sustainable porous carbons with a superior performance for CO2 capture. Energy Environ Sci 4:1765–1771
Zurück zum Zitat Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, Bae TH, Long JR (2012) Carbon dioxide capture in metal-organic frameworks. Chem Rev 112(2):724–781CrossRef Sumida K, Rogow DL, Mason JA, McDonald TM, Bloch ED, Herm ZR, Bae TH, Long JR (2012) Carbon dioxide capture in metal-organic frameworks. Chem Rev 112(2):724–781CrossRef
Zurück zum Zitat Sun YN, Gao B, Yao Y, Fang JN, Zhang M, Zhou YM, Chen H, Yang LY (2014) Effects of feedstock type, production method, and pyrolysis temperature on biochar and hydrochar properties. Chem Eng J 240:574–578CrossRef Sun YN, Gao B, Yao Y, Fang JN, Zhang M, Zhou YM, Chen H, Yang LY (2014) Effects of feedstock type, production method, and pyrolysis temperature on biochar and hydrochar properties. Chem Eng J 240:574–578CrossRef
Zurück zum Zitat Tenenbaum DJ (2009) Biochar: carbon mitigation from the ground up. Environ Health Perspect 117(2):A70–A73CrossRef Tenenbaum DJ (2009) Biochar: carbon mitigation from the ground up. Environ Health Perspect 117(2):A70–A73CrossRef
Zurück zum Zitat Yazaydin AO, Snurr RQ, Park TH, Koh K, Liu J, LeVan MD, Benin AI, Jakubczak P, Lanuza M, Galloway DB, Low JJ, Willis RR (2009) Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach. J Am Chem Soc 131(51):18198 Yazaydin AO, Snurr RQ, Park TH, Koh K, Liu J, LeVan MD, Benin AI, Jakubczak P, Lanuza M, Galloway DB, Low JJ, Willis RR (2009) Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach. J Am Chem Soc 131(51):18198
Zurück zum Zitat Zaman M, Lee JH (2013) Carbon capture from stationary power generation sources: a review of the current status of the technologies. Korean J Chem Eng 30(8):1497–1526CrossRef Zaman M, Lee JH (2013) Carbon capture from stationary power generation sources: a review of the current status of the technologies. Korean J Chem Eng 30(8):1497–1526CrossRef
Zurück zum Zitat Zelenak V, Halamova D, Gaberova L, Bloch E, Llewellyn P (2008) Amine-modified SBA-12 mesoporous silica for carbon dioxide capture: effect of amine basicity on sorption properties. Microporous Mesoporous Mater 116(1–3):358–364CrossRef Zelenak V, Halamova D, Gaberova L, Bloch E, Llewellyn P (2008) Amine-modified SBA-12 mesoporous silica for carbon dioxide capture: effect of amine basicity on sorption properties. Microporous Mesoporous Mater 116(1–3):358–364CrossRef
Metadaten
Titel
Adsorbents for CO2 Capture
verfasst von
Anne Elise Creamer
Bin Gao
Copyright-Jahr
2015
DOI
https://doi.org/10.1007/978-3-319-17010-7_3