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Erschienen in: Colloid and Polymer Science 8/2015

01.08.2015 | Original Contribution

Adsorption behaviors for oleuropein from olive leaves extracts by porous materials with carbon nanotubes

verfasst von: Yi Liu, Yongfeng Liu, Junhan Zhang, Xiaoyu Wu, Jianteng Wei, Dong Pei, Duolong Di

Erschienen in: Colloid and Polymer Science | Ausgabe 8/2015

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Abstract

Porous materials with carboxyl-modified multi-walled carbon nanotube (C-CNT) were prepared and applied to enrich oleuropein. Surface area, pore volume, and average pore diameter increased with increasing C-CNT content, and adsorption capacity was greatly enhanced. The results indicated that pseudo-second-order kinetics could describe the whole adsorption process, while intraparticle diffusion model fit the experimental data for the second stage (10–300 min). It suggested Freundlich isotherm model could describe the adsorption process. It showed that the porous materials exhibited excellent reusability and during six adsorption-desorption cycles, adsorption capacities showed no obvious loss. The high adsorption capacities, easy desorption, and remarkable reusability made the prepared porous materials as novel adsorbents for the enrichment of oleuropein. This study indicates porous materials with carboxyl group, large surface area, pore volume, and average pore diameter are favorable for oleuropein enrichment, providing an idea to design porous materials with carboxyl groups for oleuropein enrichment.

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Literatur
1.
Zurück zum Zitat Briante R, Patumi M, Terenziani S, Bismuto E, Febbraio F, Nucci R (2002) Olea europaea L. leaf extract and derivatives: antioxidant properties. J Agric Food Chem 17:4934–4940CrossRef Briante R, Patumi M, Terenziani S, Bismuto E, Febbraio F, Nucci R (2002) Olea europaea L. leaf extract and derivatives: antioxidant properties. J Agric Food Chem 17:4934–4940CrossRef
2.
Zurück zum Zitat Jemai H, El Feki A, Sayadi S (2009) Antidiabetic and antioxidant effects of hydroxytyrosol and oleuropein from olive leaves in alloxan-diabetic rats. J Agric Food Chem 57:8798–8804CrossRef Jemai H, El Feki A, Sayadi S (2009) Antidiabetic and antioxidant effects of hydroxytyrosol and oleuropein from olive leaves in alloxan-diabetic rats. J Agric Food Chem 57:8798–8804CrossRef
3.
Zurück zum Zitat Andrikopoulos NK, Antonopoulou S, Kaliora AC (2002) Oleuropein inhibits LDL oxidation induced by cooking oil frying by-products and platelet aggregation induced by platelet-activating factor. LWT-Food Sci Technol 35:479–484CrossRef Andrikopoulos NK, Antonopoulou S, Kaliora AC (2002) Oleuropein inhibits LDL oxidation induced by cooking oil frying by-products and platelet aggregation induced by platelet-activating factor. LWT-Food Sci Technol 35:479–484CrossRef
4.
Zurück zum Zitat Visioli F, Bellasta S, Galli C (1998) Oleuropein, the bitter principle of olives, enhances nitric oxide production by mouse macrophages. Life Sci 62:541–546CrossRef Visioli F, Bellasta S, Galli C (1998) Oleuropein, the bitter principle of olives, enhances nitric oxide production by mouse macrophages. Life Sci 62:541–546CrossRef
5.
Zurück zum Zitat Visioli F, Poli A, Galli C (2002) Antioxidant and other biological activities of phenols from olives and olive oil. Med Res Rev 22:65–75CrossRef Visioli F, Poli A, Galli C (2002) Antioxidant and other biological activities of phenols from olives and olive oil. Med Res Rev 22:65–75CrossRef
6.
Zurück zum Zitat Martins FP, Pinto M (2008) Isolation and characterization of a new hydroxytyrosol derivative from olive (Olea europaea) leaves. J Agric Food Chem 56:5582–5588CrossRef Martins FP, Pinto M (2008) Isolation and characterization of a new hydroxytyrosol derivative from olive (Olea europaea) leaves. J Agric Food Chem 56:5582–5588CrossRef
7.
Zurück zum Zitat Japón-Luján R, Luque de Castro MD (2006) Superheated liquid extraction of oleuropein and related biophenols from olive leaves. J Chromatogr A 1136:185–191CrossRef Japón-Luján R, Luque de Castro MD (2006) Superheated liquid extraction of oleuropein and related biophenols from olive leaves. J Chromatogr A 1136:185–191CrossRef
8.
Zurück zum Zitat Japón-Luján R, Luque-Rodríguez JM, Luque de Castro MD (2006) Dynamic ultrasound-assisted extraction of oleuropein and related biophenols from olive leaves. J Chromatogr A 1108:76–82CrossRef Japón-Luján R, Luque-Rodríguez JM, Luque de Castro MD (2006) Dynamic ultrasound-assisted extraction of oleuropein and related biophenols from olive leaves. J Chromatogr A 1108:76–82CrossRef
9.
Zurück zum Zitat Sun R, Fu K, Fu Y, Zu Y, Wang Y, Luo M, Li S, Luo H, Li Z (2009) Preparative separation and enrichment of four taxoids from Taxus chinensis needles extracts by macroporous resin column chromatography. J Sep Sci 32:1284–1293CrossRef Sun R, Fu K, Fu Y, Zu Y, Wang Y, Luo M, Li S, Luo H, Li Z (2009) Preparative separation and enrichment of four taxoids from Taxus chinensis needles extracts by macroporous resin column chromatography. J Sep Sci 32:1284–1293CrossRef
10.
Zurück zum Zitat Li C, Zheng Y, Wang X, Feng S, Di D (2011) Simultaneous separation and purification of flavonoids and oleuropein from Olea europaea L. (olive) leaves using macroporous resin. J Sci Food Agric 91:2826–2834CrossRef Li C, Zheng Y, Wang X, Feng S, Di D (2011) Simultaneous separation and purification of flavonoids and oleuropein from Olea europaea L. (olive) leaves using macroporous resin. J Sci Food Agric 91:2826–2834CrossRef
11.
Zurück zum Zitat Yang SY, Lin WN, Huang YL, Tien HW, Wang JY, Ma CCM, Li SM, Wang YS (2011) Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites. Carbon 49:793–803CrossRef Yang SY, Lin WN, Huang YL, Tien HW, Wang JY, Ma CCM, Li SM, Wang YS (2011) Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites. Carbon 49:793–803CrossRef
12.
Zurück zum Zitat Aschberger K, Johnston HJ, Stone V, Aitken RJ, Hankin SM, Peters SAK, Tran CL, Christensen FM (2010) Review of carbon nanotubes toxicity and exposure—appraisal of human health risk assessment based on open literature. Crit Rev Toxicol 40:759–790CrossRef Aschberger K, Johnston HJ, Stone V, Aitken RJ, Hankin SM, Peters SAK, Tran CL, Christensen FM (2010) Review of carbon nanotubes toxicity and exposure—appraisal of human health risk assessment based on open literature. Crit Rev Toxicol 40:759–790CrossRef
13.
Zurück zum Zitat Lee J, Mahendra S, Alvarez PJJ (2010) Nanomaterials in the construction industry: a review of their applications and environmental health and safety considerations. ACS Nano 4:3580–3590CrossRef Lee J, Mahendra S, Alvarez PJJ (2010) Nanomaterials in the construction industry: a review of their applications and environmental health and safety considerations. ACS Nano 4:3580–3590CrossRef
14.
Zurück zum Zitat Nismy NA, Adikaari AADT, Silva SRP (2010) Functionalized multiwall carbon nanotubes incorporated polymer/fullerene hybrid photovoltaics. Appl Phys Lett 97, 033105-033105-3CrossRef Nismy NA, Adikaari AADT, Silva SRP (2010) Functionalized multiwall carbon nanotubes incorporated polymer/fullerene hybrid photovoltaics. Appl Phys Lett 97, 033105-033105-3CrossRef
15.
Zurück zum Zitat Nish A, Hwang J-Y, Doig J, Nicholas RJ (2007) Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers. Nat Nanotechnol 2:640–646CrossRef Nish A, Hwang J-Y, Doig J, Nicholas RJ (2007) Highly selective dispersion of single-walled carbon nanotubes using aromatic polymers. Nat Nanotechnol 2:640–646CrossRef
16.
Zurück zum Zitat Huang D, Wang A (2013) Non-covalently functionalized multiwalled carbon nanotubes by chitosan and their synergistic reinforcing effects in PVA films. RSC Adv 3:1210–1216CrossRef Huang D, Wang A (2013) Non-covalently functionalized multiwalled carbon nanotubes by chitosan and their synergistic reinforcing effects in PVA films. RSC Adv 3:1210–1216CrossRef
17.
Zurück zum Zitat Huang SW, Chiang PN, Liu JC, Hung JT, Kuan WH, Tzou YM, Wang SL, Huang JH, Chen CC, Wang MK, Loeppert RH (2012) Chromate reduction on humic acid derived from a peat soil—exploration of the activated sites on HAs for chromate removal. Chemosphere 87:587–594CrossRef Huang SW, Chiang PN, Liu JC, Hung JT, Kuan WH, Tzou YM, Wang SL, Huang JH, Chen CC, Wang MK, Loeppert RH (2012) Chromate reduction on humic acid derived from a peat soil—exploration of the activated sites on HAs for chromate removal. Chemosphere 87:587–594CrossRef
18.
Zurück zum Zitat Fu HB, Quan X (2006) Complexes of fulvic acid on the surface of hematite, goethite, and akaganeite: FTIR observation. Chemosphere 63:403–410CrossRef Fu HB, Quan X (2006) Complexes of fulvic acid on the surface of hematite, goethite, and akaganeite: FTIR observation. Chemosphere 63:403–410CrossRef
19.
Zurück zum Zitat Lu XQ, Vassallo AM, Johnson WD (1997) Thermal stability of humic substances and their metal forms: an investigation using FTIR emission spectroscopy. J Anal Appl Pyrolysis 43:103–113CrossRef Lu XQ, Vassallo AM, Johnson WD (1997) Thermal stability of humic substances and their metal forms: an investigation using FTIR emission spectroscopy. J Anal Appl Pyrolysis 43:103–113CrossRef
20.
Zurück zum Zitat Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619CrossRef Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, Siemieniewska T (1985) Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 57:603–619CrossRef
21.
Zurück zum Zitat Li B, Gong R, Luo Y, Tan BT (2011) Tailoring the pore size of hypercrosslinked polymers. Soft Matter 7:10910–10916CrossRef Li B, Gong R, Luo Y, Tan BT (2011) Tailoring the pore size of hypercrosslinked polymers. Soft Matter 7:10910–10916CrossRef
22.
Zurück zum Zitat Avnir D, Jaroniec M (1989) An isotherm equation for adsorption on fractal surfaces of heterogeneous porous materials. Langmuir 5:1431–1433CrossRef Avnir D, Jaroniec M (1989) An isotherm equation for adsorption on fractal surfaces of heterogeneous porous materials. Langmuir 5:1431–1433CrossRef
23.
Zurück zum Zitat Sahouli B, Blacher S, Brouers F (1997) Applicability of the fractal FHH equation. Langmuir 13:4391–4394CrossRef Sahouli B, Blacher S, Brouers F (1997) Applicability of the fractal FHH equation. Langmuir 13:4391–4394CrossRef
24.
Zurück zum Zitat Jaroniec M (1995) Evaluation of the fractal dimension from a single adsorption isotherm. Langmuir 11:2316–2317CrossRef Jaroniec M (1995) Evaluation of the fractal dimension from a single adsorption isotherm. Langmuir 11:2316–2317CrossRef
25.
Zurück zum Zitat Liu Y, Bai Q, Lou S, Di D, Li J, Guo M (2012) Adsorption characteristics of (−)-epigallocatechin gallate and caffeine in the extract of waste tea on macroporous adsorption resins functionalized with chloromethyl, amino, and phenylamino groups. J Agric Food Chem 60:1555–1566CrossRef Liu Y, Bai Q, Lou S, Di D, Li J, Guo M (2012) Adsorption characteristics of (−)-epigallocatechin gallate and caffeine in the extract of waste tea on macroporous adsorption resins functionalized with chloromethyl, amino, and phenylamino groups. J Agric Food Chem 60:1555–1566CrossRef
26.
Zurück zum Zitat Lagergren S, Svenska BK (1898) Zur theorie der sogenannten adsorption geloester stoffe. Kungliga Svenska Vetensk Handl 24:1–39 Lagergren S, Svenska BK (1898) Zur theorie der sogenannten adsorption geloester stoffe. Kungliga Svenska Vetensk Handl 24:1–39
27.
Zurück zum Zitat Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–124CrossRef Ho YS, McKay G (1998) Sorption of dye from aqueous solution by peat. Chem Eng J 70:115–124CrossRef
28.
Zurück zum Zitat Weber WJ, Morris JC (1962) Proceedings of the international conference on water pollution symposium. Pergamon, Oxford: 231 Weber WJ, Morris JC (1962) Proceedings of the international conference on water pollution symposium. Pergamon, Oxford: 231
29.
Zurück zum Zitat Annadurai G, Juang R-S, Lee D-J (2002) Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. J Hazard Mater 92:263–274CrossRef Annadurai G, Juang R-S, Lee D-J (2002) Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. J Hazard Mater 92:263–274CrossRef
30.
Zurück zum Zitat Özacar M (2003) Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite. Adsorption 9:125–132CrossRef Özacar M (2003) Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite. Adsorption 9:125–132CrossRef
31.
Zurück zum Zitat Özacar M, Şengil İA (2004) Application of kinetic models to the sorption of disperse dyes onto alunite. Colloids Surf, A 242:105–113CrossRef Özacar M, Şengil İA (2004) Application of kinetic models to the sorption of disperse dyes onto alunite. Colloids Surf, A 242:105–113CrossRef
32.
Zurück zum Zitat Allen SJ, McKay G, Khader KYH (1989) Intraparticle diffusion of a basic dye during adsorption onto sphagnum peat. Environ Pollut 56:39–50CrossRef Allen SJ, McKay G, Khader KYH (1989) Intraparticle diffusion of a basic dye during adsorption onto sphagnum peat. Environ Pollut 56:39–50CrossRef
33.
Zurück zum Zitat Ismail LFM, Sallam HB, Abo Farha SA, Gamal AM, Mahmoud GEA (2014) Adsorption behaviour of direct yellow 50 onto cotton fiber: equilibrium, kinetic and thermodynamic profile. Spectrochim Acta, Part A 131:657–666CrossRef Ismail LFM, Sallam HB, Abo Farha SA, Gamal AM, Mahmoud GEA (2014) Adsorption behaviour of direct yellow 50 onto cotton fiber: equilibrium, kinetic and thermodynamic profile. Spectrochim Acta, Part A 131:657–666CrossRef
34.
Zurück zum Zitat Chen Z, Zhang A, Dong F, Di D, Wu Y (2010) Study on the adsorption feature of rutin aqueous solution on macroporous adsorption resins. J Phys Chem B 114:4841–4853CrossRef Chen Z, Zhang A, Dong F, Di D, Wu Y (2010) Study on the adsorption feature of rutin aqueous solution on macroporous adsorption resins. J Phys Chem B 114:4841–4853CrossRef
35.
Zurück zum Zitat Aouidia F, Dupuy N, Artaud J, Roussos S, Msallem M, Gaime IP, Hamdi M (2012) Rapid quantitative determination of oleuropein in olive leaves (Olea europaea) using mid-infrared spectroscopy combined with chemometric analyses. Ind Crops Prod 37:292–297CrossRef Aouidia F, Dupuy N, Artaud J, Roussos S, Msallem M, Gaime IP, Hamdi M (2012) Rapid quantitative determination of oleuropein in olive leaves (Olea europaea) using mid-infrared spectroscopy combined with chemometric analyses. Ind Crops Prod 37:292–297CrossRef
Metadaten
Titel
Adsorption behaviors for oleuropein from olive leaves extracts by porous materials with carbon nanotubes
verfasst von
Yi Liu
Yongfeng Liu
Junhan Zhang
Xiaoyu Wu
Jianteng Wei
Dong Pei
Duolong Di
Publikationsdatum
01.08.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 8/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3643-3

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