Skip to main content

2019 | OriginalPaper | Buchkapitel

Advanced Oxidation Processes: Ozonation and Fenton Processes Applied to the Removal of Pharmaceuticals

verfasst von : Santana-Martínez Germán, Roa-Morales Gabriela, Solís-Casados Dora, Romero Rubí, Natividad Reyna

Erschienen in: Ecopharmacovigilance

Verlag: Springer International Publishing

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This chapter aims to present the fundamentals, important variables, and pharmaceuticals removed by ozonation and Fenton, which are only two of the current existing advanced oxidation processes. Some toxicological information regarding pharmaceuticals oxidized by ozonation is also included. Some strategies to improve such processes, like adding a catalyst, light, or electrical current, are also analyzed. Thus, this chapter intends to present general but fundamental aspects of the aforementioned processes.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Brillas E, Huitle CAM (2011) Synthetic diamond films: preparation, electrochemistry, characterization and applications. Wiley, HobokenCrossRef Brillas E, Huitle CAM (2011) Synthetic diamond films: preparation, electrochemistry, characterization and applications. Wiley, HobokenCrossRef
2.
Zurück zum Zitat Gottschalk C, Libra JA, Saupe A (2009) Ozonation of water and waste water: a practical guide to understanding ozone and its applications. Wiley, HobokenCrossRef Gottschalk C, Libra JA, Saupe A (2009) Ozonation of water and waste water: a practical guide to understanding ozone and its applications. Wiley, HobokenCrossRef
3.
Zurück zum Zitat Alpatova AL, Davies SH, Masten SJ (2013) Hybrid ozonation-ceramic membrane filtration of surface waters: the effect of water characteristics on permeate flux and the removal of DBP precursors, dicloxacillin and ceftazidime. Sep Purif Technol 107:179–186CrossRef Alpatova AL, Davies SH, Masten SJ (2013) Hybrid ozonation-ceramic membrane filtration of surface waters: the effect of water characteristics on permeate flux and the removal of DBP precursors, dicloxacillin and ceftazidime. Sep Purif Technol 107:179–186CrossRef
4.
Zurück zum Zitat Borowska E, Bourgin M, Hollender J et al (2016) Oxidation of cetirizine, fexofenadine and hydrochlorothiazide during ozonation: kinetics and formation of transformation products. Water Res 94:350–362CrossRef Borowska E, Bourgin M, Hollender J et al (2016) Oxidation of cetirizine, fexofenadine and hydrochlorothiazide during ozonation: kinetics and formation of transformation products. Water Res 94:350–362CrossRef
5.
Zurück zum Zitat Tay KS, Madehi N (2015) Ozonation of ofloxacin in water: by-products, degradation pathway and ecotoxicity assessment. Sci Total Environ 520:23–31CrossRef Tay KS, Madehi N (2015) Ozonation of ofloxacin in water: by-products, degradation pathway and ecotoxicity assessment. Sci Total Environ 520:23–31CrossRef
6.
Zurück zum Zitat Huang G, Pan F, Fan G, Liu G (2016) Application of heterogeneous catalytic ozonation as a tertiary treatment of effluent of biologically treated tannery wastewater. J Environ Sci Health Toxicol Hazard Subst Environ Eng 51:626–633 Huang G, Pan F, Fan G, Liu G (2016) Application of heterogeneous catalytic ozonation as a tertiary treatment of effluent of biologically treated tannery wastewater. J Environ Sci Health Toxicol Hazard Subst Environ Eng 51:626–633
7.
Zurück zum Zitat Martins RC, Cardoso M, Dantas RF et al (2015) Catalytic studies for the abatement of emerging contaminants by ozonation. J Chem Technol Biotechnol 90:1611–1618CrossRef Martins RC, Cardoso M, Dantas RF et al (2015) Catalytic studies for the abatement of emerging contaminants by ozonation. J Chem Technol Biotechnol 90:1611–1618CrossRef
8.
Zurück zum Zitat Polat D, Balci I, Özbelge TA (2015) Catalytic ozonation of an industrial textile wastewater in a heterogeneous continuous reactor. J Environ Chem Eng 3:1860–1871CrossRef Polat D, Balci I, Özbelge TA (2015) Catalytic ozonation of an industrial textile wastewater in a heterogeneous continuous reactor. J Environ Chem Eng 3:1860–1871CrossRef
9.
Zurück zum Zitat Crousier C, Pic J-S, Albet J et al (2016) Urban wastewater treatment by catalytic ozonation. Ozone Sci Eng 38:3–13CrossRef Crousier C, Pic J-S, Albet J et al (2016) Urban wastewater treatment by catalytic ozonation. Ozone Sci Eng 38:3–13CrossRef
10.
Zurück zum Zitat Chen S-Y, Li Y-M, Lei L-R (2015) Tertiary treatment of paper-making tobacco sheet wastewater via catalytic ozonation with Ti(IV) ions. Huanan Ligong Daxue Xuebao J South China Univ Technol Nat Sci 43:131–139 Chen S-Y, Li Y-M, Lei L-R (2015) Tertiary treatment of paper-making tobacco sheet wastewater via catalytic ozonation with Ti(IV) ions. Huanan Ligong Daxue Xuebao J South China Univ Technol Nat Sci 43:131–139
11.
Zurück zum Zitat Wang T, Xue L, Brimblecombe P et al (2017) Ozone pollution in China: a review of concentrations, meteorological influences, chemical precursors, and effects. Sci Total Environ 575:1582–1596CrossRef Wang T, Xue L, Brimblecombe P et al (2017) Ozone pollution in China: a review of concentrations, meteorological influences, chemical precursors, and effects. Sci Total Environ 575:1582–1596CrossRef
12.
Zurück zum Zitat Lucas MS, Reis NM, Li Puma G (2016) Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column. Chem Eng J 296:335–339CrossRef Lucas MS, Reis NM, Li Puma G (2016) Intensification of ozonation processes in a novel, compact, multi-orifice oscillatory baffled column. Chem Eng J 296:335–339CrossRef
13.
Zurück zum Zitat Hewgill MR, Mackley MR, Pandit AB, Pannu SS (1993) Enhancement of gas-liquid mass transfer using oscillatory flow in a baffled tube. Chem Eng Sci 48:799–809CrossRef Hewgill MR, Mackley MR, Pandit AB, Pannu SS (1993) Enhancement of gas-liquid mass transfer using oscillatory flow in a baffled tube. Chem Eng Sci 48:799–809CrossRef
14.
Zurück zum Zitat Martín del Campo E, Valente JS, Pavón T et al (2011) 4-chlorophenol oxidation photocatalyzed by a calcined Mg–Al–Zn layered double hydroxide in a co-current downflow bubble column. Ind Eng Chem Res 50:11544–11552CrossRef Martín del Campo E, Valente JS, Pavón T et al (2011) 4-chlorophenol oxidation photocatalyzed by a calcined Mg–Al–Zn layered double hydroxide in a co-current downflow bubble column. Ind Eng Chem Res 50:11544–11552CrossRef
15.
Zurück zum Zitat Ochuma IJ, Fishwick RP, Wood J, Winterbottom JM (2007) Optimisation of degradation conditions of 1,8-diazabicyclo 5.4.0 undec-7-ene in water and reaction kinetics analysis using a cocurrent downflow contactor photocatalytic reactor. Appl Catal B Environ 73(3–4):259–268CrossRef Ochuma IJ, Fishwick RP, Wood J, Winterbottom JM (2007) Optimisation of degradation conditions of 1,8-diazabicyclo 5.4.0 undec-7-ene in water and reaction kinetics analysis using a cocurrent downflow contactor photocatalytic reactor. Appl Catal B Environ 73(3–4):259–268CrossRef
16.
Zurück zum Zitat Ochuma IJ, Fishwick RP, Wood J, Winterbottoom JM (2007) Photocatalytic oxidation of 2,4,6-trichlorophenol in water using a cocurrent downflow contactor reactor (CDCR). J Hazard Mater 144:627–633CrossRef Ochuma IJ, Fishwick RP, Wood J, Winterbottoom JM (2007) Photocatalytic oxidation of 2,4,6-trichlorophenol in water using a cocurrent downflow contactor reactor (CDCR). J Hazard Mater 144:627–633CrossRef
17.
Zurück zum Zitat Alharbi SK, Price WE, Kang J et al (2016) Ozonation of carbamazepine, diclofenac, sulfamethoxazole and trimethoprim and formation of major oxidation products. Desalin Water Treat 57:29340–29351CrossRef Alharbi SK, Price WE, Kang J et al (2016) Ozonation of carbamazepine, diclofenac, sulfamethoxazole and trimethoprim and formation of major oxidation products. Desalin Water Treat 57:29340–29351CrossRef
18.
Zurück zum Zitat Zhao Y, Kuang J, Zhang S et al (2017) Ozonation of indomethacin: kinetics, mechanisms and toxicity. J Hazard Mater 323:460–470CrossRef Zhao Y, Kuang J, Zhang S et al (2017) Ozonation of indomethacin: kinetics, mechanisms and toxicity. J Hazard Mater 323:460–470CrossRef
19.
Zurück zum Zitat Rodríguez EM, Márquez G, León EA et al (2013) Mechanism considerations for photocatalytic oxidation, ozonation and photocatalytic ozonation of some pharmaceutical compounds in water. J Environ Manag 127:114–124CrossRef Rodríguez EM, Márquez G, León EA et al (2013) Mechanism considerations for photocatalytic oxidation, ozonation and photocatalytic ozonation of some pharmaceutical compounds in water. J Environ Manag 127:114–124CrossRef
20.
Zurück zum Zitat Gimeno O, García-Araya JF, Beltrán FJ et al (2016) Removal of emerging contaminants from a primary effluent of municipal wastewater by means of sequential biological degradation-solar photocatalytic oxidation processes. Chem Eng J 290:12–20CrossRef Gimeno O, García-Araya JF, Beltrán FJ et al (2016) Removal of emerging contaminants from a primary effluent of municipal wastewater by means of sequential biological degradation-solar photocatalytic oxidation processes. Chem Eng J 290:12–20CrossRef
22.
Zurück zum Zitat Kermani M, Farzadkia M, Esrafili A et al (2016) Removal of catechol from aqueous solutions using catalytic ozonation by magnetic nanoparticles of iron oxide doped with silica and titanium dioxide: a kinetic study. J Mazandaran Univ Med Sci 26:139–154 Kermani M, Farzadkia M, Esrafili A et al (2016) Removal of catechol from aqueous solutions using catalytic ozonation by magnetic nanoparticles of iron oxide doped with silica and titanium dioxide: a kinetic study. J Mazandaran Univ Med Sci 26:139–154
23.
Zurück zum Zitat Oropesa AL, Novais SC, Lemos MFL et al (2017) Oxidative stress responses of Daphnia magna exposed to effluents spiked with emerging contaminants under ozonation and advanced oxidation processes. Environ Sci Pollut Res 24:1735–1747CrossRef Oropesa AL, Novais SC, Lemos MFL et al (2017) Oxidative stress responses of Daphnia magna exposed to effluents spiked with emerging contaminants under ozonation and advanced oxidation processes. Environ Sci Pollut Res 24:1735–1747CrossRef
24.
Zurück zum Zitat Prado M, Borea L, Cesaro A et al (2017) Removal of emerging contaminant and fouling control in membrane bioreactors by combined ozonation and sonolysis. Int Biodeterior Biodegrad 119:577–586CrossRef Prado M, Borea L, Cesaro A et al (2017) Removal of emerging contaminant and fouling control in membrane bioreactors by combined ozonation and sonolysis. Int Biodeterior Biodegrad 119:577–586CrossRef
25.
Zurück zum Zitat Salimi M, Esrafili A, Gholami M et al (2017) Contaminants of emerging concern: a review of new approach in AOP technologies. Environ Monit Assess 189(8):414CrossRef Salimi M, Esrafili A, Gholami M et al (2017) Contaminants of emerging concern: a review of new approach in AOP technologies. Environ Monit Assess 189(8):414CrossRef
26.
Zurück zum Zitat Nawrocki J (2013) Catalytic ozonation in water: controversies and questions. Discussion paper. Appl Catal B Environ 142–143:465–471CrossRef Nawrocki J (2013) Catalytic ozonation in water: controversies and questions. Discussion paper. Appl Catal B Environ 142–143:465–471CrossRef
27.
Zurück zum Zitat Nawrocki J, Kasprzyk-Hordern B (2010) The efficiency and mechanisms of catalytic ozonation. Appl Catal B Environ 99:27–42CrossRef Nawrocki J, Kasprzyk-Hordern B (2010) The efficiency and mechanisms of catalytic ozonation. Appl Catal B Environ 99:27–42CrossRef
28.
Zurück zum Zitat Martínez-Huitle CA, Rodrigo MA, Sirés I, Scialdone O (2015) Single and coupled electrochemical processes and reactors for the abatement of organic water pollutants: a critical review. Chem Rev 115:13362–13407CrossRef Martínez-Huitle CA, Rodrigo MA, Sirés I, Scialdone O (2015) Single and coupled electrochemical processes and reactors for the abatement of organic water pollutants: a critical review. Chem Rev 115:13362–13407CrossRef
29.
Zurück zum Zitat Liu Z-Q, Ma J, Cui Y-H et al (2011) Factors affecting the catalytic activity of multi-walled carbon nanotube for ozonation of oxalic acid. Sep Purif Technol 78:147–153CrossRef Liu Z-Q, Ma J, Cui Y-H et al (2011) Factors affecting the catalytic activity of multi-walled carbon nanotube for ozonation of oxalic acid. Sep Purif Technol 78:147–153CrossRef
30.
Zurück zum Zitat Dai Q, Wang J, Yu J et al (2014) Catalytic ozonation for the degradation of acetylsalicylic acid in aqueous solution by magnetic CeO2 nanometer catalyst particles. Appl Catal B Environ 144:686–693CrossRef Dai Q, Wang J, Yu J et al (2014) Catalytic ozonation for the degradation of acetylsalicylic acid in aqueous solution by magnetic CeO2 nanometer catalyst particles. Appl Catal B Environ 144:686–693CrossRef
31.
Zurück zum Zitat Qin H, Chen H, Zhang X et al (2014) Efficient degradation of fulvic acids in water by catalytic ozonation with CeO2/AC. J Chem Technol Biotechnol 89:1402–1409CrossRef Qin H, Chen H, Zhang X et al (2014) Efficient degradation of fulvic acids in water by catalytic ozonation with CeO2/AC. J Chem Technol Biotechnol 89:1402–1409CrossRef
32.
Zurück zum Zitat Faria PCC, Órfão JJM, Pereira MFR (2009) Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents. Appl Catal B Environ 88:341–350CrossRef Faria PCC, Órfão JJM, Pereira MFR (2009) Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents. Appl Catal B Environ 88:341–350CrossRef
33.
Zurück zum Zitat Buxton GV, Greenstock CL, Helman WP, Ross AB (1988) Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (•OH/•O−) in aqueous solution. J Phys Chem Ref Data 17:513–886CrossRef Buxton GV, Greenstock CL, Helman WP, Ross AB (1988) Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (OH/O) in aqueous solution. J Phys Chem Ref Data 17:513–886CrossRef
34.
Zurück zum Zitat Yin R, Guo W, Zhou X et al (2016) Enhanced sulfamethoxazole ozonation by noble metal-free catalysis based on magnetic Fe3 O4 nanoparticles: catalytic performance and degradation mechanism. RSC Adv 6:19265–19270CrossRef Yin R, Guo W, Zhou X et al (2016) Enhanced sulfamethoxazole ozonation by noble metal-free catalysis based on magnetic Fe3 O4 nanoparticles: catalytic performance and degradation mechanism. RSC Adv 6:19265–19270CrossRef
35.
Zurück zum Zitat Qi F, Chu W, Xu B (2016) Comparison of phenacetin degradation in aqueous solutions by catalytic ozonation with CuFe2O4 and its precursor: surface properties, intermediates and reaction mechanisms. Chem Eng J 284:28–36CrossRef Qi F, Chu W, Xu B (2016) Comparison of phenacetin degradation in aqueous solutions by catalytic ozonation with CuFe2O4 and its precursor: surface properties, intermediates and reaction mechanisms. Chem Eng J 284:28–36CrossRef
37.
Zurück zum Zitat Bing J, Hu C, Nie Y et al (2015) Mechanism of catalytic ozonation in Fe2O3/Al2O3@ SBA-15 aqueous suspension for destruction of ibuprofen. Environ Sci Technol 49:1690–1697CrossRef Bing J, Hu C, Nie Y et al (2015) Mechanism of catalytic ozonation in Fe2O3/Al2O3@ SBA-15 aqueous suspension for destruction of ibuprofen. Environ Sci Technol 49:1690–1697CrossRef
38.
Zurück zum Zitat Aghaeinejad-Meybodi A, Ebadi A, Shafiei S et al (2015) Degradation of antidepressant drug fluoxetine in aqueous media by ozone/H2O2 system: process optimization using central composite design. Environ Technol 36:1477–1488CrossRef Aghaeinejad-Meybodi A, Ebadi A, Shafiei S et al (2015) Degradation of antidepressant drug fluoxetine in aqueous media by ozone/H2O2 system: process optimization using central composite design. Environ Technol 36:1477–1488CrossRef
39.
Zurück zum Zitat Li H, Xu B, Qi F et al (2014) Degradation of bezafibrate in wastewater by catalytic ozonation with cobalt doped red mud: efficiency, intermediates and toxicity. Appl Catal B Environ 152–153:342–351CrossRef Li H, Xu B, Qi F et al (2014) Degradation of bezafibrate in wastewater by catalytic ozonation with cobalt doped red mud: efficiency, intermediates and toxicity. Appl Catal B Environ 152–153:342–351CrossRef
40.
Zurück zum Zitat Hollender J, Zimmermann SG, Koepke S et al (2009) Elimination of organic micropollutants in a municipal wastewater treatment plant upgraded with a full-scale post-ozonation followed by sand filtration. Environ Sci Technol 43:7862–7869CrossRef Hollender J, Zimmermann SG, Koepke S et al (2009) Elimination of organic micropollutants in a municipal wastewater treatment plant upgraded with a full-scale post-ozonation followed by sand filtration. Environ Sci Technol 43:7862–7869CrossRef
41.
Zurück zum Zitat Mashayekh-Salehi A, Moussavi G, Yaghmaeian K (2017) Preparation, characterization and catalytic activity of a novel mesoporous nanocrystalline MgO nanoparticle for ozonation of acetaminophen as an emerging water contaminant. Chem Eng J 310:157–169CrossRef Mashayekh-Salehi A, Moussavi G, Yaghmaeian K (2017) Preparation, characterization and catalytic activity of a novel mesoporous nanocrystalline MgO nanoparticle for ozonation of acetaminophen as an emerging water contaminant. Chem Eng J 310:157–169CrossRef
42.
Zurück zum Zitat Jin X, Peldszus S, Huck PM (2012) Reaction kinetics of selected micropollutants in ozonation and advanced oxidation processes. Water Res 46:6519–6530CrossRef Jin X, Peldszus S, Huck PM (2012) Reaction kinetics of selected micropollutants in ozonation and advanced oxidation processes. Water Res 46:6519–6530CrossRef
43.
Zurück zum Zitat Amado-Piña D, Roa-Morales G, Barrera-Díaz C et al (2017) Synergic effect of ozonation and electrochemical methods on oxidation and toxicity reduction: phenol degradation. Int Mex Congr Chem React Eng 198:82–90 Amado-Piña D, Roa-Morales G, Barrera-Díaz C et al (2017) Synergic effect of ozonation and electrochemical methods on oxidation and toxicity reduction: phenol degradation. Int Mex Congr Chem React Eng 198:82–90
44.
Zurück zum Zitat Xu B, Qi F, Sun D et al (2016) Cerium doped red mud catalytic ozonation for bezafibrate degradation in wastewater: efficiency, intermediates, and toxicity. Chemosphere 146:22–31CrossRef Xu B, Qi F, Sun D et al (2016) Cerium doped red mud catalytic ozonation for bezafibrate degradation in wastewater: efficiency, intermediates, and toxicity. Chemosphere 146:22–31CrossRef
45.
Zurück zum Zitat Brillas E, Sirés I, Oturan MA (2009) Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem Rev 109:6570–6631CrossRef Brillas E, Sirés I, Oturan MA (2009) Electro-Fenton process and related electrochemical technologies based on Fenton’s reaction chemistry. Chem Rev 109:6570–6631CrossRef
46.
Zurück zum Zitat Oturan MA, Aaron J-J (2014) Advanced oxidation processes in water/wastewater treatment: principles and applications. A review. Crit Rev Environ Sci Technol 44:2577–2641CrossRef Oturan MA, Aaron J-J (2014) Advanced oxidation processes in water/wastewater treatment: principles and applications. A review. Crit Rev Environ Sci Technol 44:2577–2641CrossRef
47.
Zurück zum Zitat Bokare AD, Choi W (2014) Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes. J Hazard Mater 275:121–135CrossRef Bokare AD, Choi W (2014) Review of iron-free Fenton-like systems for activating H2O2 in advanced oxidation processes. J Hazard Mater 275:121–135CrossRef
48.
Zurück zum Zitat Pang S-Y, Jiang J, Ma J (2011) Oxidation of sulfoxides and arsenic(III) in corrosion of nanoscale zero valent iron by oxygen: evidence against ferryl ions (Fe(IV)) as active intermediates in fenton reaction. Environ Sci Technol 45:3179–3180CrossRef Pang S-Y, Jiang J, Ma J (2011) Oxidation of sulfoxides and arsenic(III) in corrosion of nanoscale zero valent iron by oxygen: evidence against ferryl ions (Fe(IV)) as active intermediates in fenton reaction. Environ Sci Technol 45:3179–3180CrossRef
49.
Zurück zum Zitat De Laat HJG (1999) Catalytic decomposition of hydrogen peroxide by Fe(III) in homogeneous aqueous solution: mechanism and kinetic modeling. Environ Sci Technol 33:2726–2732CrossRef De Laat HJG (1999) Catalytic decomposition of hydrogen peroxide by Fe(III) in homogeneous aqueous solution: mechanism and kinetic modeling. Environ Sci Technol 33:2726–2732CrossRef
50.
Zurück zum Zitat Novoa-Luna KA, Mendoza-Zepeda A, Natividad R et al (2016) Biological hazard evaluation of a pharmaceutical effluent before and after a photo-Fenton treatment. Sci Total Environ 569:830–840CrossRef Novoa-Luna KA, Mendoza-Zepeda A, Natividad R et al (2016) Biological hazard evaluation of a pharmaceutical effluent before and after a photo-Fenton treatment. Sci Total Environ 569:830–840CrossRef
51.
Zurück zum Zitat Bernal M, Romero R, Roa G et al (2013) Ozonation of indigo carmine catalyzed with Fe-pillared clay. Int J Photoenergy 2013:7CrossRef Bernal M, Romero R, Roa G et al (2013) Ozonation of indigo carmine catalyzed with Fe-pillared clay. Int J Photoenergy 2013:7CrossRef
52.
Zurück zum Zitat Santana-Martínez G, Roa-Morales G, Martin del Campo E et al (2016) Electro-Fenton and electro-Fenton-like with in situ electrogeneration of H2O2 and catalyst applied to 4-chlorophenol mineralization. Electrochim Acta 195:246–256CrossRef Santana-Martínez G, Roa-Morales G, Martin del Campo E et al (2016) Electro-Fenton and electro-Fenton-like with in situ electrogeneration of H2O2 and catalyst applied to 4-chlorophenol mineralization. Electrochim Acta 195:246–256CrossRef
53.
Zurück zum Zitat Campos-Martin JM, Blanco-Brieva G, Fierro JL (2006) Hydrogen peroxide synthesis: an outlook beyond the anthraquinone process. Angew Chem Int Ed 45:6962–6984CrossRef Campos-Martin JM, Blanco-Brieva G, Fierro JL (2006) Hydrogen peroxide synthesis: an outlook beyond the anthraquinone process. Angew Chem Int Ed 45:6962–6984CrossRef
54.
Zurück zum Zitat Wernimont E, Ventura M, Garboden G, Mullens P (1999) Past and present uses of rocket grade hydrogen peroxide. General Kinetics, LLC Aliso Viejo, CA 92656 Wernimont E, Ventura M, Garboden G, Mullens P (1999) Past and present uses of rocket grade hydrogen peroxide. General Kinetics, LLC Aliso Viejo, CA 92656
55.
Zurück zum Zitat Moreira FC, Boaventura RAR, Brillas E, Vilar VJP (2017) Electrochemical advanced oxidation processes: a review on their application to synthetic and real wastewaters. Appl Catal B Environ 202:217–261CrossRef Moreira FC, Boaventura RAR, Brillas E, Vilar VJP (2017) Electrochemical advanced oxidation processes: a review on their application to synthetic and real wastewaters. Appl Catal B Environ 202:217–261CrossRef
56.
Zurück zum Zitat Yang L, Dong G, Jacobs DL et al (2017) Two-channel photocatalytic production of H2O2 over g-C3N4 nanosheets modified with perylene imides. J Catal 352:274–281CrossRef Yang L, Dong G, Jacobs DL et al (2017) Two-channel photocatalytic production of H2O2 over g-C3N4 nanosheets modified with perylene imides. J Catal 352:274–281CrossRef
57.
Zurück zum Zitat Isarain-Chávez E, Martínez-Huitle CA, Peralta-Hernández JM, De la Rosa C (2013) On-site hydrogen peroxide production at pilot flow plant: application to electro-Fenton process. Int J Electrochem Sci 8:3084–3094 Isarain-Chávez E, Martínez-Huitle CA, Peralta-Hernández JM, De la Rosa C (2013) On-site hydrogen peroxide production at pilot flow plant: application to electro-Fenton process. Int J Electrochem Sci 8:3084–3094
58.
Zurück zum Zitat Yu F, Zhou M, Zhou L, Peng R (2014) A novel electro-Fenton process with H2O2 generation in a rotating disk reactor for organic pollutant degradation. Environ Sci Technol Lett 1:320–324CrossRef Yu F, Zhou M, Zhou L, Peng R (2014) A novel electro-Fenton process with H2O2 generation in a rotating disk reactor for organic pollutant degradation. Environ Sci Technol Lett 1:320–324CrossRef
59.
Zurück zum Zitat Yu F, Zhou M, Yu X (2015) Cost-effective electro-Fenton using modified graphite felt that dramatically enhanced on H2O2 electro-generation without external aeration. Electrochim Acta 163:182–189CrossRef Yu F, Zhou M, Yu X (2015) Cost-effective electro-Fenton using modified graphite felt that dramatically enhanced on H2O2 electro-generation without external aeration. Electrochim Acta 163:182–189CrossRef
60.
Zurück zum Zitat Pérez JF, Llanos J, Sáez C et al (2016) Electrochemical jet-cell for the in-situ generation of hydrogen peroxide. Electrochem Commun 71:65–68CrossRef Pérez JF, Llanos J, Sáez C et al (2016) Electrochemical jet-cell for the in-situ generation of hydrogen peroxide. Electrochem Commun 71:65–68CrossRef
61.
Zurück zum Zitat Assumpção M, Moraes A, De Souza R et al (2012) Low content cerium oxide nanoparticles on carbon for hydrogen peroxide electrosynthesis. Appl Catal A Gen 411:1–6CrossRef Assumpção M, Moraes A, De Souza R et al (2012) Low content cerium oxide nanoparticles on carbon for hydrogen peroxide electrosynthesis. Appl Catal A Gen 411:1–6CrossRef
62.
Zurück zum Zitat Silva FL, Reis RM, Barros WRP et al (2014) Electrogeneration of hydrogen peroxide in gas diffusion electrodes: application of iron (II) phthalocyanine as a modifier of carbon black. J Electroanal Chem 722–723:32–37CrossRef Silva FL, Reis RM, Barros WRP et al (2014) Electrogeneration of hydrogen peroxide in gas diffusion electrodes: application of iron (II) phthalocyanine as a modifier of carbon black. J Electroanal Chem 722–723:32–37CrossRef
63.
Zurück zum Zitat Peralta E, Natividad R, Roa G et al (2013) A comparative study on the electrochemical production of H2O2 between BDD and graphite cathodes. Sustain Environ Res 23:259–266 Peralta E, Natividad R, Roa G et al (2013) A comparative study on the electrochemical production of H2O2 between BDD and graphite cathodes. Sustain Environ Res 23:259–266
64.
Zurück zum Zitat Olvera-Vargas H, Oturan N, Oturan MA, Brillas E (2015) Electro-Fenton and solar photoelectro-Fenton treatments of the pharmaceutical ranitidine in pre-pilot flow plant scale. Sep Purif Technol 146:127–135CrossRef Olvera-Vargas H, Oturan N, Oturan MA, Brillas E (2015) Electro-Fenton and solar photoelectro-Fenton treatments of the pharmaceutical ranitidine in pre-pilot flow plant scale. Sep Purif Technol 146:127–135CrossRef
65.
Zurück zum Zitat Pérez T, Garcia-Segura S, El-Ghenymy A et al (2015) Solar photoelectro-Fenton degradation of the antibiotic metronidazole using a flow plant with a Pt/air-diffusion cell and a CPC photoreactor. Electrochim Acta 165:173–181CrossRef Pérez T, Garcia-Segura S, El-Ghenymy A et al (2015) Solar photoelectro-Fenton degradation of the antibiotic metronidazole using a flow plant with a Pt/air-diffusion cell and a CPC photoreactor. Electrochim Acta 165:173–181CrossRef
66.
Zurück zum Zitat Bustos YA, Rangel-Peraza JG, Rojas-Valencia MN et al (2016) Treatment of industrial effluents by electrochemical generation of H2O2 using an RVC cathode in a parallel plate reactor. Environ Technol 37:815–827CrossRef Bustos YA, Rangel-Peraza JG, Rojas-Valencia MN et al (2016) Treatment of industrial effluents by electrochemical generation of H2O2 using an RVC cathode in a parallel plate reactor. Environ Technol 37:815–827CrossRef
67.
Zurück zum Zitat Luo H, Li C, Wu C et al (2015) Electrochemical degradation of phenol by in situ electro-generated and electro-activated hydrogen peroxide using an improved gas diffusion cathode. Electrochim Acta 186:486–493CrossRef Luo H, Li C, Wu C et al (2015) Electrochemical degradation of phenol by in situ electro-generated and electro-activated hydrogen peroxide using an improved gas diffusion cathode. Electrochim Acta 186:486–493CrossRef
68.
Zurück zum Zitat Kato S, Jung J, Suenobu T, Fukuzumi S (2013) Production of hydrogen peroxide as a sustainable solar fuel from water and dioxygen. Energy Environ Sci 6:3756–3764CrossRef Kato S, Jung J, Suenobu T, Fukuzumi S (2013) Production of hydrogen peroxide as a sustainable solar fuel from water and dioxygen. Energy Environ Sci 6:3756–3764CrossRef
69.
Zurück zum Zitat Tsukamoto D, Shiro A, Shiraishi Y et al (2012) Photocatalytic H2O2 production from ethanol/O2 system using TiO2 loaded with Au-Ag bimetallic alloy nanoparticles. ACS Catal 2:599–603CrossRef Tsukamoto D, Shiro A, Shiraishi Y et al (2012) Photocatalytic H2O2 production from ethanol/O2 system using TiO2 loaded with Au-Ag bimetallic alloy nanoparticles. ACS Catal 2:599–603CrossRef
70.
Zurück zum Zitat Zhuang H, Yang L, Xu J et al (2015) Robust photocatalytic H2O2 production by octahedral Cd3(C3N3S3)2 coordination polymer under visible light. Sci Rep 5:16947CrossRef Zhuang H, Yang L, Xu J et al (2015) Robust photocatalytic H2O2 production by octahedral Cd3(C3N3S3)2 coordination polymer under visible light. Sci Rep 5:16947CrossRef
71.
Zurück zum Zitat Wang R, Pan K, Han D et al (2016) Solar-driven H2O2 generation from H2O and O2 using earth-abundant mixed-metal oxide@carbon nitride photocatalysts. ChemSusChem 9:2470–2479CrossRef Wang R, Pan K, Han D et al (2016) Solar-driven H2O2 generation from H2O and O2 using earth-abundant mixed-metal oxide@carbon nitride photocatalysts. ChemSusChem 9:2470–2479CrossRef
72.
Zurück zum Zitat Shiraishi Y, Kanazawa S, Sugano Y et al (2014) Highly selective production of hydrogen peroxide on graphitic carbon nitride (g-C3N4) photocatalyst activated by visible light. ACS Catal 4:774–780CrossRef Shiraishi Y, Kanazawa S, Sugano Y et al (2014) Highly selective production of hydrogen peroxide on graphitic carbon nitride (g-C3N4) photocatalyst activated by visible light. ACS Catal 4:774–780CrossRef
73.
Zurück zum Zitat Li W, Nanaboina V, Zhou Q, Korshin GV (2012) Effects of Fenton treatment on the properties of effluent organic matter and their relationships with the degradation of pharmaceuticals and personal care products. Water Res 46:403–412CrossRef Li W, Nanaboina V, Zhou Q, Korshin GV (2012) Effects of Fenton treatment on the properties of effluent organic matter and their relationships with the degradation of pharmaceuticals and personal care products. Water Res 46:403–412CrossRef
74.
Zurück zum Zitat Aguinaco A, Beltrán FJ, Sagasti JJP, Gimeno O (2014) In situ generation of hydrogen peroxide from pharmaceuticals single ozonation: a comparative study of its application on Fenton like systems. Chem Eng J 235:46–51CrossRef Aguinaco A, Beltrán FJ, Sagasti JJP, Gimeno O (2014) In situ generation of hydrogen peroxide from pharmaceuticals single ozonation: a comparative study of its application on Fenton like systems. Chem Eng J 235:46–51CrossRef
75.
Zurück zum Zitat Cui X, Zeng P, Qiu G et al (2015) Pilot-scale treatment of pharmaceutical berberine wastewater by Fenton oxidation. Environ Earth Sci 73:4967–4977CrossRef Cui X, Zeng P, Qiu G et al (2015) Pilot-scale treatment of pharmaceutical berberine wastewater by Fenton oxidation. Environ Earth Sci 73:4967–4977CrossRef
76.
Zurück zum Zitat Dwivedi K, Morone A, Chakrabarti T, Pandey RA (2016) Evaluation and optimization of Fenton pretreatment integrated with granulated activated carbon (GAC) filtration for carbamazepine removal from complex wastewater of pharmaceutical industry. J Environ Chem Eng. https://doi.org/10.1016/j.jece.2016.12.054 Dwivedi K, Morone A, Chakrabarti T, Pandey RA (2016) Evaluation and optimization of Fenton pretreatment integrated with granulated activated carbon (GAC) filtration for carbamazepine removal from complex wastewater of pharmaceutical industry. J Environ Chem Eng. https://​doi.​org/​10.​1016/​j.​jece.​2016.​12.​054
77.
Zurück zum Zitat Chi GT, Churchley J, Huddersman KD (2013) Pilot-scale removal of trace steroid hormones and pharmaceuticals and personal care products from municipal wastewater using a heterogeneous fenton’s catalytic process. Int J Chem Eng. https://doi.org/10.1155/2013/760915 Chi GT, Churchley J, Huddersman KD (2013) Pilot-scale removal of trace steroid hormones and pharmaceuticals and personal care products from municipal wastewater using a heterogeneous fenton’s catalytic process. Int J Chem Eng. https://​doi.​org/​10.​1155/​2013/​760915
78.
Zurück zum Zitat Chong S, Zhang G, Zhang N et al (2016) Preparation of FeCeOx by ultrasonic impregnation method for heterogeneous Fenton degradation of diclofenac. Ultrason Sonochem 32:231–240CrossRef Chong S, Zhang G, Zhang N et al (2016) Preparation of FeCeOx by ultrasonic impregnation method for heterogeneous Fenton degradation of diclofenac. Ultrason Sonochem 32:231–240CrossRef
79.
Zurück zum Zitat Velichkova F, Julcour-Lebigue C, Koumanova B, Delmas H (2013) Heterogeneous Fenton oxidation of paracetamol using iron oxide (nano)particles. J Environ Chem Eng 1:1214–1222CrossRef Velichkova F, Julcour-Lebigue C, Koumanova B, Delmas H (2013) Heterogeneous Fenton oxidation of paracetamol using iron oxide (nano)particles. J Environ Chem Eng 1:1214–1222CrossRef
80.
Zurück zum Zitat Titouhi H, Belgaied J-E (2016) Heterogeneous Fenton oxidation of ofloxacin drug by iron alginate support. Environ Technol 37:2003–2015CrossRef Titouhi H, Belgaied J-E (2016) Heterogeneous Fenton oxidation of ofloxacin drug by iron alginate support. Environ Technol 37:2003–2015CrossRef
81.
Zurück zum Zitat Mirzaei A, Chen Z, Haghighat F, Yerushalmi L (2017) Removal of pharmaceuticals from water by homo/heterogonous Fenton-type processes – a review. Chemosphere 174:665–688CrossRef Mirzaei A, Chen Z, Haghighat F, Yerushalmi L (2017) Removal of pharmaceuticals from water by homo/heterogonous Fenton-type processes – a review. Chemosphere 174:665–688CrossRef
82.
Zurück zum Zitat Arzate-Salgado S-Y, Morales-Pérez A-A, Solís-López M, Ramírez-Zamora R-M (2016) Evaluation of metallurgical slag as a Fenton-type photocatalyst for the degradation of an emerging pollutant: diclofenac. Catal Today 266:126–135CrossRef Arzate-Salgado S-Y, Morales-Pérez A-A, Solís-López M, Ramírez-Zamora R-M (2016) Evaluation of metallurgical slag as a Fenton-type photocatalyst for the degradation of an emerging pollutant: diclofenac. Catal Today 266:126–135CrossRef
83.
Zurück zum Zitat Bautitz IR, Nogueira RFP (2007) Degradation of tetracycline by photo-Fenton process-solar irradiation and matrix effects. J Photochem Photobiol Chem 187:33–39CrossRef Bautitz IR, Nogueira RFP (2007) Degradation of tetracycline by photo-Fenton process-solar irradiation and matrix effects. J Photochem Photobiol Chem 187:33–39CrossRef
84.
Zurück zum Zitat Sun S-P, Lemley AT (2011) P-nitrophenol degradation by a heterogeneous Fenton-like reaction on nano-magnetite: process optimization, kinetics, and degradation pathways. J Mol Catal Chem 349:71–79CrossRef Sun S-P, Lemley AT (2011) P-nitrophenol degradation by a heterogeneous Fenton-like reaction on nano-magnetite: process optimization, kinetics, and degradation pathways. J Mol Catal Chem 349:71–79CrossRef
Metadaten
Titel
Advanced Oxidation Processes: Ozonation and Fenton Processes Applied to the Removal of Pharmaceuticals
verfasst von
Santana-Martínez Germán
Roa-Morales Gabriela
Solís-Casados Dora
Romero Rubí
Natividad Reyna
Copyright-Jahr
2019
DOI
https://doi.org/10.1007/698_2017_166