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Metallurgical and Materials Transactions A
Erschienen in: Metallurgical and Materials Transactions A 10/2014

01.09.2014

Anticorrosive Activity of Kigelia pinnata Leaves Extract on Mild Steel in Acidic Media

verfasst von: P. Muthukrishnan, K. Saravana Kumar, B. Jeyaprabha, P. Prakash

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 10/2014

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Abstract

The corrosion inhibition of mild steel in 1 M H2SO4 and 1 M HCl solution with different concentrations of Kigelia pinnata leaves extract (KPLE) was investigated using mass loss, Tafel polarization, and electrochemical impedance spectroscopy. Inhibition efficiency of KPLE is found to increase with increasing concentration but to decrease with temperature. Polarization measurements reveal that KPLE acts as a mixed type inhibitor in both acids. Impedance curves show that increasing KPLE concentration increases charge transfer resistance and decreases double layer capacitance. The adsorption of KPLE on the mild steel surface obeys the Langmuir adsorption isotherm. The experimental results reveal that KPLE inhibits the corrosion reaction in both acid environments, and inhibition efficiency follows the order H2SO4 > HCl. The kinetic and adsorption parameters for mild steel in acid in the presence and absence of KPLE were evaluated and discussed. The negative value of the standard free energy of adsorption in the presence of inhibitor suggests spontaneous adsorption of inhibitor on the mild steel surface. Protective film formation against corrosion was confirmed by ultraviolet-visible (UV-visible), X-ray diffraction, scanning electron microscopy, and Fourier transform–infrared spectroscopy techniques.
Vorheriger Artikel Microstructural Evolution of the 55 Wt Pct Al-Zn Coating During Press Hardening
Nächster Artikel Effect of Treatment Time on the Microstructure of Austenitic Stainless Steel During Low-Temperature Liquid Nitrocarburizing

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Metadaten
Titel
Anticorrosive Activity of Kigelia pinnata Leaves Extract on Mild Steel in Acidic Media
verfasst von
P. Muthukrishnan
K. Saravana Kumar
B. Jeyaprabha
P. Prakash
Publikationsdatum
01.09.2014
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 10/2014
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-014-2366-2

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