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Adsorption

Erschienen in:

29.01.2020

Aqueous miscible organic-layered double hydroxides with improved CO₂ adsorption capacity

verfasst von: Xuancan Zhu, Chunping Chen, Yixiang Shi, Dermot O’Hare, Ningsheng Cai

Erschienen in: Adsorption | Ausgabe 7/2020

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Abstract

Potassium-promoted layered double hydroxide (LDH)-derived materials are suitable elevated temperature CO₂ adsorbents for pre-combustion CO₂ capture. A challenge for the commercialization of LDHs as efficient CO₂ adsorbents is their low capacities (ca. 0.5–0.6 mmol/g@400 °C) due to their hydrogen-bonded stacked structure. In this study, the aqueous miscible organic solvent treatment (AMOST) was used to exfoliate Mg₃Al–CO₃ LDH into nanosheets with a flower-like morphology, resulting in high surface areas of 287 and 212 m²/g for CC1 (washed with ethanol) and CC2 (washed with acetone), respectively. The exfoliated LDH structure exposed more interlayered CO₂ active sites and promoters for alkali metal modification. Six impregnation solvents, water, acetone, ethanediol, ethanol, DMAC, and methanol were screened to optimize the CO₂ uptake of 20 wt% K₂CO₃-promoted CC1. K₂CO₃/CC1(ed) using ethanediol as the impregnation solvent reached a CO₂ working capacity of 1.46 mmol/g at 400 °C in the first cycle and 1.23 mmol/g after 10 cycles, twice the capacity of the commercial K₂CO₃/MG70. Material characterization indicated that the unexpectedly high performance of K₂CO₃/CC1(ed) could be attributed to the uniform K⁺ dispersion on the surface of K₂CO₃/CC1(ed) rather than bulk phase formation and the release of the residual solvent during calcination that could generate more paths for CO₂ diffusion.

Vorheriger Artikel Value added utilization of ferronickel slags as raw materials of 4A zeolite for CO2 reduction

Nächster Artikel Coupled gravimetric, manometric and calorimetric study of CO2, N2 and CH4 adsorption on zeolites for the assessment of classical equilibrium models

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Titel: Aqueous miscible organic-layered double hydroxides with improved CO2 adsorption capacity
verfasst von: Xuancan Zhu
Chunping Chen
Yixiang Shi
Dermot O’Hare
Ningsheng Cai
Publikationsdatum: 29.01.2020
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 7/2020
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-020-00209-4

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