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Erschienen in: Adsorption 7/2020

08.02.2020

Adsorption equilibrium isotherms and thermodynamic analysis of CH4, CO2, CO, N2 and H2 on NaY Zeolite

verfasst von: Li Feng, Yuanhui Shen, Tongbo Wu, Bing Liu, Donghui Zhang, Zhongli Tang

Erschienen in: Adsorption | Ausgabe 7/2020

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Abstract

Adsorption capacities of CH4, CO2, CO, N2 and H2 on NaY zeolite were measured at 298 K, 318 K, 338 K and 358 K with pressure ranged from 0 to 10 bar. The order of adsorption capacity was CO2 ≫ CH4 > CO > N2 ≫ H2. The experiment data were fitted by the Langmuir, Toth and Sips equations. The fitting relativity of above models were also compared. Moreover, the isosteric heat of adsorption were calculated by the Clausius–Clapeyron equation, the results showed that the adsorption heat of CO2 is the largest (41.89764 kJ/mol with adsorption loading of 5.8 mmol/g) and that of H2 is the smallest. Finally, the selectivity of binary mixture was predicted according to the IAS theory.

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Metadaten
Titel
Adsorption equilibrium isotherms and thermodynamic analysis of CH4, CO2, CO, N2 and H2 on NaY Zeolite
verfasst von
Li Feng
Yuanhui Shen
Tongbo Wu
Bing Liu
Donghui Zhang
Zhongli Tang
Publikationsdatum
08.02.2020
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 7/2020
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-020-00205-8

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