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29.03.2022 | Original Article

Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study

verfasst von: Pramod Kumbhar, Suryakant Patil, Dattatray Narale, Ashish Sartape, Chitra Jambhale, Jin-Hyeok Kim, Sanjay Kolekar

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 3/2024

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Abstract

We synthesized waste biomass-based partly graphitized activated carbon from Samanea saman waste pods (SSWPAC) and used it to remove hazardous dye rhodamine B (Rh B) and metal Cr(VI) from aqueous solution. The prepared adsorbent showed a remarkable surface area of 546.016 m² g⁻¹. The adsorbent was characterized by applying Fourier transform infrared spectroscopy, field emission scanning electron microscopy, energy-dispersive x-ray analysis, Raman spectroscopy, and X-ray diffraction. Within 50 min, 99.2% elimination of Rh B dye was observed at pH 2 using 1.0 g L⁻¹ of the adsorbent, while Cr(VI) removal was 98.3% at pH 2 using 2.5 g L⁻¹ of the adsorbent within 120 min at room temperature. The correlation coefficient R² favored pseudo-second-order kinetics in kinetic analyses of both adsorption processes. The isotherm experimental values of Rh B and Cr(VI) fits to Freundlich adsorption systems with correlation coefficient R² = 0.998 and 0.999 respectively. The results showed maximum adsorption capacity of SSWPAC for Rh B (101.01 mg g⁻¹) and Cr(VI) (64.52 mg g⁻¹). The phytotoxicity study exhibited successful removal of these pollutants from the solutions under study.

Vorheriger Artikel Application of a biowaste of fish (Labeo rohita) scale for the removal of methyl orange from aqueous solutions: optimization of sorption conditions by response surface method and analysis of adsorption mechanism

Nächster Artikel Commercialization of 2G bioethanol as a transportation fuel for the sustainable energy, environment, and economic growth of India: theoretical and empirical assessment of bioethanol potential from agriculture crop residues

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Titel: Biobased carbon for effective removal of rhodamine B and Cr(VI) from aqueous solution: kinetic, isotherm and thermodynamic study
verfasst von: Pramod Kumbhar
Suryakant Patil
Dattatray Narale
Ashish Sartape
Chitra Jambhale
Jin-Hyeok Kim
Sanjay Kolekar
Publikationsdatum: 29.03.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 3/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-022-02625-8

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