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Biomass Conversion and Biorefinery

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21.03.2022 | Original Article

Biodiesel production using a novel surface functionalized biomass residue solid green catalyst

verfasst von: Siyi Tang, Xiaoling Duan, Qingyu Zhang, Cunwen Wang, Weiguo Wang, Weiliang Feng, Tielin Wang

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 2/2024

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Abstract

This paper focuses on the preparation of environmentally friendly biomass carbon-based solid acid catalysts from black soldier fly larvae (BSFL) shells. The effective catalysts were prepared by incomplete carbonization of BSFL shells and then the p-toluenesulfonic acid (PTSA) groups were introduced to obtain catalysts. The synthesized composite catalysts were characterized by XPS, FT-IR, SEM, XRD, and BET analysis to reveal the physiochemical properties. Meanwhile, the effects of various reaction conditions on the yield of biodiesel with oleic acid (OA) and methanol were studied in detail. The results showed that the conversion rate reached 93.2% under the optimal conditions in this paper: carbonization temperature = 400 °C, carbonization time = 2 h, sulfonation temperature = 100 °C, and reaction time = 4 h, respectively. Furthermore, the stability and reusability of the prepared catalysts were also demonstrated. At last, the possible catalytic mechanism of the prepared catalyst was comprehensively described. Moreover, the results showed that the synthesized biomass-based solid acid catalyst under these conditions had good catalytic activity.

Vorheriger Artikel Hardwood spent mushroom substrate–based activated biochar as a sustainable bioresource for removal of emerging pollutants from wastewater

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Titel: Biodiesel production using a novel surface functionalized biomass residue solid green catalyst
verfasst von: Siyi Tang
Xiaoling Duan
Qingyu Zhang
Cunwen Wang
Weiguo Wang
Weiliang Feng
Tielin Wang
Publikationsdatum: 21.03.2022
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 2/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-022-02576-0

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