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Journal of Materials Science
Erschienen in: Journal of Materials Science 22/2021

29.04.2021 | Energy materials

Biomass wood-derived efficient Fe–N–C catalysts for oxygen reduction reaction

verfasst von: Dingding Li, Zheng Han, Kunyue Leng, Shenghua Ma, Yi Wang, Jinbo Bai

Erschienen in: Journal of Materials Science | Ausgabe 22/2021

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Abstract

Efficient and low-cost electrocatalysts for oxygen reduction reaction (ORR) were the key for scalable application of metal–air batteries and fuel cells. Herein, iron-based nitrogen-doped carbon catalysts (Fe–N–Cwood) were prepared, using hydrothermal-pyrolysis-treated wood-derived nitrogen-doped carbon as the support. This support possessed large specific surface area and macro–meso–micro hierarchical porous networks, ensuring fluent mass transfer of electrolyte and oxygen species. In the ORR electrochemical test, Fe–N–Cwood catalyst showed an excellent activity, with a half-wave potential of 0.90 V in 0.1 M KOH, and a half-wave potential of 0.70 V in 0.1 M HClO4. Moreover, durability tests illustrated that Fe–N–Cwood possessed high stability and methanol tolerance. The Fe–N–Cwood-based Zn–air battery delivered a peak power density of 231 mW cm−2, suggesting its potential applications in sustainable energy conversion systems.

Graphical abstract

A highly efficient ORR electrocatalyst was obtained by embedding iron nanoparticles with hydrothermal-pyrolysis-treated wood-derived carbon.
Vorheriger Artikel Enhancing the mechanical–electrical property simultaneously in pure copper composites by using carbonized polymer dots
Nächster Artikel Ni/NiO hybrid nanostructure supported on biomass carbon for visible-light photocatalytic hydrogen evolution

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Metadaten
Titel
Biomass wood-derived efficient Fe–N–C catalysts for oxygen reduction reaction
verfasst von
Dingding Li
Zheng Han
Kunyue Leng
Shenghua Ma
Yi Wang
Jinbo Bai
Publikationsdatum
29.04.2021
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 22/2021
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-021-06122-7

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