nach oben

Adsorption

Erschienen in:

20.10.2018

Calibration and uncertainty analysis of a fixed-bed adsorption model for CO₂ separation

verfasst von: Karen N. Son, Justin A. Weibel, James C. Knox, Suresh V. Garimella

Erschienen in: Adsorption | Ausgabe 8/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Fixed-bed adsorption is widely used in industrial gas separation and is the primary method for atmosphere revitalization in space. This paper analyzes the uncertainty of a one-dimensional, fixed-bed adsorption model due to uncertainty in several model inputs, namely, the linear-driving-force (LDF) mass transfer coefficient, axial dispersion, heat transfer coefficients, and adsorbent properties. The input parameter uncertainties are determined from a comprehensive survey of experimental data in the literature. The model is first calibrated against experimental data from intra-bed centerline concentration measurements to find the LDF coefficient. We then use this LDF coefficient to extract axial dispersion coefficients from mixed, downstream concentration measurements for both a small-diameter bed (dominated by wall-channeling) and a large-diameter bed (dominated by pellet-driven dispersion). The predicted effluent concentration and temperature profiles are most strongly affected by uncertainty in LDF coefficient, adsorbent density, and void fraction. The uncertainty analysis further reveals that ignoring the effect of wall-channeling on apparent axial dispersion can cause significant error in the predicted breakthrough times of small-diameter beds.

Vorheriger Artikel On the computer simulations of carbon nanoparticles porosity: statistical mechanics model for CO2 and N2 adsorption isotherms

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

See references Lo and Alok (1996), Farhadpour and Bono (1996), Abdel-Jabbar et al. (2001), Ko et al. (2001), Gomez-Salazar et al. (2003), Worch (2004), Chakraborty et al. (2005), Glover and LeVan (2008), Lv et al. (2008), Richard et al. (2010), Abu-Lail et al. (2012), Likozar et al. (2013), Nur et al. (2014), Gupta et al. (2015), Davila-Guzman et al. (2016), and Shao and Chen (2016).

See references Hartzog and Sircar (1995), Ratto et al. (1996), Yu et al. (2009), Reijers et al. (2009a), Lu et al. (2016), Aguilera and Gutiérrez Ortiz (2016), and Zheng et al. (2016).

See references Lo and Alok (1996), Farhadpour and Bono (1996), Ko et al. (2001), Hartzog and Sircar (1995), Reijers et al. (2009a, b), and Zheng et al. (2016).

See references Abdel-Jabbar et al. (2001), Nur et al. (2014), Hartzog and Sircar (1995), Ratto et al. (1996), Yu et al. (2009), Naja and Volesky (2008), Maring and Webley (2013), and Kalyanaraman et al. (2014).

See references Glover and LeVan (2008), Ratto et al. (1996), Reijers et al. (2009a), Maring and Webley (2013), Sircar et al. (1983), Delage et al. (2000), Sircar (2005), and Walton and LeVan (2005).

See references Lo and Alok (1996), Farhadpour and Bono (1996), Abdel-Jabbar et al. (2001), Ko et al. (2001), Gomez-Salazar et al. (2003), Worch (2004), Chakraborty et al. (2005), Lv et al. (2008), Richard et al. (2010), Abu-Lail et al. (2012), Likozar et al. (2013), Nur et al. (2014), Gupta et al. (2015), Davila-Guzman et al. (2016), Shao and Chen (2016), Lu et al. (2016), Aguilera and Gutiérrez Ortiz (2016), Zheng et al. (2016), Naja and Volesky (2008), Kalyanaraman et al. (2014), and Borina and Pavko (2009).

See references Lo and Alok (1996), Farhadpour and Bono (1996), Abdel-Jabbar et al. (2001), Ko et al. (2001), Likozar et al. (2013), Hartzog and Sircar (1995), Ratto et al. (1996), Yu et al. (2009), Reijers et al. (2009a), Zheng et al. (2016), Naja and Volesky (2008), Maring and Webley (2013), and Kalyanaraman et al. (2014).

2014 Strategic Plan; NASA, pp 11–15 (2014)

Abdel-Jabbar, N., Al-Asheh, S., Hader, B., Modeling: Parametric estimation, and sensitivity analysis for copper adsorption with moss packed-bed. Sep. Sci. Technol. 36(13), 2811–2833 (2001)CrossRef

Abu-Lail, L., Bergendahl, J.A., Thompson, R.W.: Mathematical modeling of chloroform adsorption onto fixed-bed columns of highly siliceous granular zeolites. Environ. Prog. Sustain. Energy 31(4), 591–596 (2012)CrossRef

Aguilera, P.G., Gutiérrez Ortiz, F.J.: Prediction of fixed-bed breakthrough curves for H₂S adsorption from biogas: importance of axial dispersion for design. Chem. Eng. J. 289, 93–98 (2016)CrossRef

Augier, F., Laroche, C., Brehon, E.: Application of computational fluid dynamics to fixed bed adsorption calculations: effect of hydrodynamics at laboratory and industrial scale. Sep. Purif. Technol. 63(2), 466–474 (2008)CrossRef

Borina, B., Pavko, A.: Adsorption of vancomycin on amberlite XAD-16 in a packed bed column. Chem. Biochem. Eng. Q. 23(4), 479–483 (2009)

Chahbani, M.H., Tondeur, D.: Mass transfer kinetics in pressure swing adsorption. Sep. Purif. Technol. 20(2–3), 185–196 (2000)CrossRef

Chakraborty, S., De, S., DasGupta, S., Basu, J.K.: Adsorption study for the removal of a basic dye: experimental and modeling. Chemosphere 58(8), 1079–1086 (2005)CrossRef

Coker, R., Knox, J. Predictive modeling of the CDRA 4BMS. In Proceedings of the 46th International Conference on Environmental Systems; Vienna, Austria, 2016

COMSOL Multiphysics®; COMSOL AB: Stockholm, SE, 2016

Datasheet Flexible Min-K®; 6-14-120; Morgan advanced materials (2013)

Davila-Guzman, N.E., Cerino-Córdova, F.J., Loredo-Cancino, M., Rangel-Mendez, J.R., Gómez-González, R., Soto-Regalado, E.: Studies of adsorption of heavy metals onto spent coffee ground: equilibrium, regeneration, and dynamic performance in a fixed-bed column. Int. J. Chem. Eng. (2016). https://doi.org/10.1155/2016/9413879 CrossRef

Grace Davidson, Adsorbents for process applications. W. R. Grace & Co, Columbia, MD (2010)

Delage, F., Pré, P., Le Cloirec, P.: Mass transfer and warming during adsorption of high concentrations of VOCs on an activated carbon bed: experimental and theoretical analysis. Environ. Sci. Technol. 34(22), 4816–4821 (2000)CrossRef

Delgado, J.M.P.Q.: A critical review of dispersion in packed beds. Heat Mass Transfer 42(4), 279–310 (2006)CrossRef

Delgado, J.M.P.Q.: Longitudinal and transverse dispersion in porous media. Chem. Eng. Res. Des. 85(9), 1245–1252 (2007)CrossRef

Do, D.D.: Adsorption analysis: equilibria and kinetics; Series on chemical engineering; v, 2. Imperial College Press, London (1998)

Edwards, M.F., Richardson, J.F.: Gas dispersion in packed beds. Chem. Eng. Sci. 23(2), 109–123 (1968)CrossRef

Fairbanks, D.F., Wilke, C.R.: Diffusion coefficients in multicomponent gas mixtures. Ind. Eng. Chem. 42(3), 471–475 (1950)CrossRef

Farhadpour, F.A., Bono, A.: Sorptive separation of ethanol-water mixtures with a Bi-dispersed hydrophobic molecular sieve, silicalite: measurement and theoretical analysis of column dynamics. Chem. Eng. Processing 35(2), 157–168 (1996)CrossRef

Glover, T.G., LeVan, M.D.: Sensitivity analysis of adsorption bed behavior: examination of pulse inputs and layered-bed optimization. Chem. Eng. Sci. 63(8), 2086–2098 (2008)CrossRef

Glueckauf, E., Coates, J.I.: Theory of chromatography; the influence of incomplete equilibrium on the front boundary of chromatograms and on the effectiveness of separation. J. Chem. Soc. 1315–1321, e21 (1947)

Gomez-Salazar, S., Lee, J.S., Heydweiller, J.C., Tavlarides, L.L.: Analysis of cadmium adsorption on novel organo-ceramic adsorbents with a thiol functionality. Ind. Eng. Chem. Res. 42(14), 3403–3412 (2003)CrossRef

Gupta, K.N., Rao, N.J., Agarwal, G.K.: Gaseous phase adsorption of volatile organic compounds on granular activated carbon. Chem. Eng. Commun. 202(3), 384–401 (2015)CrossRef

Hartzog, D.G., Sircar, S.: Sensitivity of PSA process performance to input variables. Adsorption 1(2), 133–151 (1995)CrossRef

Hirschfelder, J.O., Curtiss, C.F., Bird, R.B.: The Molecular Theory of Gases and Liquids. Wiley-Interscience, London (1964)

Human Exploration and Operations (HEO) Mission Directorate; NASA (2012)

Incropera, F.P., DeWitt, D.P., Bergman, T.L., Lavine, A.S.. Fundamentals of Heat and Mass Transfer, 6th ed.. Wiley, Hoboken (2006)

Kalyanaraman, J., Kawajiri, Y., Realff, M.J.: Bayesian estimation, uncertainty propagation and design of experiments for CO₂ adsorption on amine sorbents. In: Eden, M.R., Siirola, J.D., Towler, G.P. (eds.) Proceedings of the 8th International Conference on Foundations of Computer-Aided Process Design, Cle Elum, pp 345–350 (2014)

Kay, R., Pancho, D.: Evaluation of alternative desiccants and adsorbents for the desiccant/adsorbent bed; 12-77742, CAGE 70210; Honeywell (2013)

Knox, J.C.: Predictive simulation of gas adsorption in fixed beds and limitations due to the Ill-posed danckwerts boundary condition. Dissertation, the University of Alabama in Huntsville, Huntsville, AL (2016)

Knox, J.C., Ebner, A.D., LeVan, M.D., Coker, R.F., Ritter, J.A.: Limitations of breakthrough curve analysis in fixed-bed adsorption. Ind. Eng. Chem. Res. 55(16), 4734–4748 (2016a)CrossRef

Knox, J., Coker, R., Howard, D., Peters, W., Watson, D., Cmarik, G., Miller, L. Development of carbon dioxide removal systems for advanced exploration systems 2015–2016. In Proceedings of the 46th International Conference on Environmental Systems, Vienna (2016b)

Ko, D.C.K., Porter, J.F., McKay, G.: Film-pore diffusion model for the fixed-bed sorption of copper and cadmium ions onto bone char. Water Res. 35(16), 3876–3886 (2001)CrossRef

Krupiczka, R.: Analysis of thermal conductivity in granular materials. Int. Chem. Eng. 7(1), 122–144 (1967)

Kunii, D., Suzuki, M., Ono, N.: Heat transfer from wall surface to packed beds at high Reynolds number. J. Chem. Eng. Jpn. 1(1), 21–26 (1968)CrossRef

Langer, G., Roethe, A., Roethe, K.-P., Gelbin, D.: Heat and mass transfer in packed beds—III. Axial mass dispersion. Int. J. Heat Mass Transf. 21(6), 751–759 (1978)CrossRef

Li, C.-H., Finlayson, B.A.: Heat transfer in packed beds—a reevaluation. Chem. Eng. Sci. 32(9), 1055–1066 (1976)CrossRef

Likozar, B., Senica, D., Pavko, A.: Interpretation of experimental results for vancomycin adsorption on polymeric resins in a fixed bed column by mathematical modeling with independently estimated parameters. Ind. Eng. Chem. Res. 52(26), 9247–9258 (2013)CrossRef

Lo, I.M.C., Alok, P.A.: Computer simulation of activated carbon adsorption for multi-component systems. Environ. Int. 22(2), 239–252 (1996)CrossRef

Lu, Y., He, J., Wu, L., Luo, G.: Relationship between breakthrough curve and adsorption isotherm of Ca(II) imprinted Chitosan microspheres for metal adsorption. Chin. J. Chem. Eng. 24(2), 323–329 (2016)CrossRef

Lv, L., Zhang, Y., Wang, K., Ray, A.K., Zhao, X.S.: Modeling of the adsorption breakthrough behaviors of Pb²⁺ in a fixed bed of ETS-10 adsorbent. J. Colloid Interface Sci. 325(1), 57–63 (2008)CrossRef

Maring, B.J., Webley, P.A.: A New simplified pressure/vacuum swing adsorption model for rapid adsorbent screening for CO₂ capture applications. Int. J. Greenh. Gas Control 15, 16–31 (2013)CrossRef

Material Library User’s Guide; COMSOL Multiphysics®, ver. 5.2a; COMSOL AB: Stockholm, SE

Naja, G., Volesky, B.: Optimization of a biosorption column performance. Environ. Sci. Technol. 42(15), 5622–5629 (2008)CrossRef

Nur, T., Shim, W.G., Johir, M.A.H., Vigneswaran, S., Kandasamy, J.: Modelling of phosphorus removal by ion-exchange resin (Purolite FerrIX A33E) in fixed-bed column experiments. Desalin. Water Treat. 52(4–6), 784–790 (2014)CrossRef

Onyestyák, G., Shen, D., Rees, L.V.C.: Frequency-response studies of CO₂ diffusion in commercial 5A powders and pellets. Microporous Mater. 5(5), 279–288 (1996)CrossRef

Özgümüş, T., Mobedi, M., Özkol, Ü, Nakayama, A.: Thermal dispersion in porous media—a review on the experimental studies for packed beds. Appl. Mech. Rev. 65(3), 031001 (2013)CrossRef

Physical Properties of Pyropel® Insulation. Albany International, Rochester, NH

Q-Fiber® Felt Data Sheet; HPI-25 4-08; Johns Manville, Denver, CO (2008)

Ratto, M., Lodi, G., Costa, P.: Sensitivity analysis of a fixed-bed gas-solid TSA: the problem of design with uncertain models. Sep. Technol. 6(4), 235–245 (1996)CrossRef

Reijers, H.T.J., Boon, J., Elzinga, G.D., Cobden, P.D., Haije, W.G., van den Brink, R.W.: Modeling study of the sorption-enhanced reaction process for CO₂ capture. I. Model development and validation. Ind. Eng. Chem. Res. 48(15), 6966–6974 (2009a)CrossRef

Reijers, H.T.J., Boon, J., Elzinga, G.D., Cobden, P.D., Haije, W.G., van den Brink, R.W.: Modeling study of the sorption-enhanced reaction process for CO₂ capture. II. Application to steam-methane reforming. Ind. Eng. Chem. Res. 48(15), 6975–6982 (2009b)CrossRef

Richard, D., Delgado, N., Schweich, D.: Adsorption of complex phenolic compounds on active charcoal: breakthrough curves. Chem. Eng. J. 158(2), 213–219 (2010)CrossRef

Scott, D.S., Lee, W., Papa, J.: The measurement of transport coefficients in gas-solid heterogeneous reactions. Chem. Eng. Sci. 29(11), 2155–2167 (1974)CrossRef

Shafeeyan, M.S., Wan Daud, W.M.A., Shamiri, A.A.: Review of mathematical modeling of fixed-bed columns for carbon dioxide adsorption. Chem. Eng. Res. Des. 92(5), 961–988 (2014)CrossRef

Shao, Y., Chen, H.: Adsorption kinetics of P-nitrophenol (PNP) on coal-based activated carbon: experimental and simulation. Desalin. Water Treat. 57(31), 14496–14505 (2016)CrossRef

Sircar, S.: Influence of gas-solid heat transfer on rapid PSA. Adsorption 11(1), 509–513 (2005)CrossRef

Sircar, S., Hufton, J.R.: Why does the linear driving force model for adsorption kinetics work? Adsorption 6(2), 137–147 (2000)CrossRef

Sircar, S., Kumar, R., Anselmo, K.J.: Effects of column nonisothermality or nonadiabaticity on the adsorption breakthrough curves. Ind. Eng. Chem. Proc. Des. Dev. 22(1), 10–15 (1983)CrossRef

Son, K.N., Gomez, C., Paragon, M., Knox, J.C.: Experimental validation of vacuum desorption in 1-D model of CO₂ removal. In Proceedings of the 46th International Conference on Environmental Systems, Vienna (2016)

Son, K.N., Weibel, J.A., Garimella, S.V., Knox, J.C.: Calibration and sensitivity of a fixed-bed adsorption model for atmosphere revitalization in space. In Proceedings of the 47th International Conference on Environmental Systems, Charleston, p 173 (2017)

Toth, J.: State equations of the solid gas interface layer. Acta Chim. Acad. Sci. Hung. 69(3), 311–317 (1971)

Vortmeyer, D., Michael, K.: The effect of non-uniform flow distribution on concentration profiles and breakthrough curves of fixed bed adsorbers. Chem. Eng. Sci. 40(11), 2135–2138 (1985)CrossRef

Vortmeyer, D., Winter, R.P.: Die Bedeutung Der Strömungsverteilung Für Die Modellierung von Chemischen Festbettreaktoren Bei Höheren Reynolds-Zahlen Und Ausgedehnten Reaktionszonen. Chemie Ingenieur Technik 55(12), 950–951 (1983)CrossRef

Wakao, N., Kaguei, S.: Heat and Mass Transfer in Packed Beds. Taylor & Francis, New York (1982)

Wakao, N., Kaguei, S., Funazkri, T.: Effect of fluid dispersion coefficients on particle-to-fluid heat transfer coefficients in packed beds. Chem. Eng. Sci. 34(3), 325–336 (1979)CrossRef

Walton, K.S., LeVan, M.D.: Effect of energy balance approximations on simulation of fixed-bed adsorption. Ind. Eng. Chem. Res. 44(19), 7474–7480 (2005)CrossRef

Wang, Y., LeVan, M.D.: Adsorption equilibrium of carbon dioxide and water vapor on Zeolites 5A and 13X and silica gel: pure components. J. Chem. Eng. Data 54(10), 2839–2844 (2009)CrossRef

Wicke, E.: Significance of molecular diffusion for chromatographic procedures. Ber. Bunsen-Ges. Phys. Chem. Chem. Phys. 77(3), 160–171 (1973)

Worch, E.: Modelling the solute transport under nonequilibrium conditions on the basis of mass transfer equations. J. Contam. Hydrol. 68(1–2), 97–120 (2004)CrossRef

Yagi, S., Wakao, N.: Heat and mass transfer from wall to fluid in packed beds. AIChE J. 5(1), 79–85 (1959)CrossRef

Yagi, S., Kunii, D., Wakao, N.: Studies on axial effective thermal conductivities in packed beds. AIChE J. 6(4), 543–546 (1960)CrossRef

Yu, Z., Peldszus, S., Huck, P.M.: Adsorption of selected pharmaceuticals and an endocrine disrupting compound by granular activated carbon. 2. Model prediction. Environ. Sci. Technol. 43(5), 1474–1479 (2009)CrossRef

Zheng, M., Xu, C., Hu, H., Ye, Z., Chen, X.A.: Modified homogeneous surface diffusion model for the fixed-bed adsorption of 4,6-DMDBT on Ag–CeOx/TiO₂–SiO₂. RSC Adv. 6(114), 112899–112907 (2016)CrossRef

Titel: Calibration and uncertainty analysis of a fixed-bed adsorption model for CO2 separation
verfasst von: Karen N. Son
Justin A. Weibel
James C. Knox
Suresh V. Garimella
Publikationsdatum: 20.10.2018
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 8/2018
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-018-9982-x

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 8/2018

NBO, AIM, HOMO–LUMO and thermodynamic investigation of the nitrate ion adsorption on the surface of pristine, Al and Ga doped BNNTs: A DFT study

Amine functionalized activated carbon fibers as effective structured adsorbents for formaldehyde removal

Efficient adsorption toward precious metal from aqueous solution by zeolitic imidazolate framework-8

On the computer simulations of carbon nanoparticles porosity: statistical mechanics model for CO2 and N2 adsorption isotherms

Adsorption and diffusion of alkylbenzene in microspherical ZSM-5 zeolite assembled with nanocrystals

Co-adsorption of Albumin and Immunoglobulin G from Human Serum onto a cation exchanger mixed mode adsorbent

Premium Partner

Marktübersichten