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Biomass Conversion and Biorefinery

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18.03.2023 | Original Article

Carbon quantum dots derived from pomegranate peel: highly effective Fe(III) sensor

verfasst von: Hasan Eskalen, Serhan Uruş, Mustafa Kavgacı, Hacı Veli Kalmış, Beyhan Tahta

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 1/2024

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Abstract

Carbon quantum dots (CQDs), which have excellent photoluminescence properties, have been synthesized from pomegranate peel and sucrose as carbon sources by a hydrothermal method in this study. The reaction temperature and the synthesis time were optimized for obtaining CQDs with unique physical and chemical properties that can easily be soluble in water and show luminescence properties. The obtained CQDs were characterized by using thermogravimetric analysis (TGA), UV–Vis spectroscopy, fluorescence spectroscopy, X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FT-IR), and X-ray diffractometry. The quantum yield (QY) of the synthesized CQDs was calculated as 7.02%. The obtained CQDs exhibited highly selective sensor properties and detected Fe³⁺ ions in Co²⁺, Al³⁺, Hg²⁺, Cu²⁺, Zn²⁺, Ni²⁺, Ba²⁺, Mn²⁺, Li⁺, K⁺, and Fe²⁺ cations at the same concentration. Fe(III) ions can be detected at 7.488 μM concentration with R² = 0.952 value. The sensitivity performance of the obtained CQDs was also evaluated in different types of real water samples. It was also determined the synthesized carbon quantum dots were very sensitive to Fe³⁺ in well water (CQDs-W), seawater (CQDs-Sea), dam water (CQDs-D), tap water (CQDs-T), snow water (CQDs-Snow), and ultrapure water (CQDs-U) as nearly the same in the pure water samples under ideal environments that quenched the fluorescence intensity of CQDs.

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Vorheriger Artikel Olive mill wastewater biodegradation for bacterial lipase production using a response surface methodology

Nächster Artikel Optimization of pretreatment and enzymatic hydrolysis coupled with ultrasonication for the production of xylooligosaccharides from corn cob

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Titel: Carbon quantum dots derived from pomegranate peel: highly effective Fe(III) sensor
verfasst von: Hasan Eskalen
Serhan Uruş
Mustafa Kavgacı
Hacı Veli Kalmış
Beyhan Tahta
Publikationsdatum: 18.03.2023
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 1/2024
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-023-04048-5

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