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Polymer Bulletin

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04.03.2020 | Original Paper

Cassava starch: structural modification for development of a bio-adsorber for aqueous pollutants. Characterization and adsorption studies on methylene blue

verfasst von: Nancy Alvarado, Romina L. Abarca, José Urdaneta, Julio Romero, María José Galotto, Abel Guarda

Erschienen in: Polymer Bulletin | Ausgabe 2/2021

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Abstract

A potential bio-adsorber of contaminants in aqueous medium was developed in this work through modified starches using organic acids. Methylene blue (MB) was used as example of a pollutant agent. For this purpose, firstly three types of modified starches were prepared using malonic, glutaric, and valeric acids in aqueous solution at different concentrations. The characterization of modified starches showed concordance with the chemical structure of the acid incorporated in starch. Pseudo-second-order model explains the rate of adsorption of the cationic dye MB. The adsorption of MB was carried out through intraparticle diffusion mechanism mainly. Physical and chemical interactions between modified starch and MB are involved.

Vorheriger Artikel Preparation and characterization of novel antibacterial blended films based on modified carboxymethyl cellulose/phenolic compounds

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Niedergall K, Bach M, Hirth T, Tovar G, Schiestel T (2014) Removal of micropollutants from water by nanocomposite membrane adsorbers. Sep Purif Technol 131:60–68. https://doi.org/10.1016/j.seppur.2014.04.032CrossRef

Amode J, Santos J, Alam Z, Mirza A, Mei C (2016) Adsorption of methylene blue from aqueous solution using untreated and treated (Metroxylon spp.) waste adsorbent: equilibrium and kinetics studies. Int J Ind Chem 7:333–345. https://doi.org/10.1007/s40090-016-0085-9CrossRef

Oladipo A, Ifebajo A (2018) Highly efficient magnetic chicken bone biochar for removal of tetracycline and fluorescent dye from wastewater: two-stage adsorber analysis. J Environ Manag 209:9–16. https://doi.org/10.1016/j.jenvman.2017.12.030CrossRef

Sophia C, Lima E (2018) Removal of emerging contaminants from the environment by adsorption. Ecotoxicol Environ Saf 150:1–17. https://doi.org/10.1016/j.ecoenv.2017.12.026CrossRef

Baig N, Ihsanullah SM, Saleh T (2019) Graphene-based adsorbents for the removal of toxic organic pollutants: a review. J Environ Manag 244:370–382. https://doi.org/10.1016/j.jenvman.2019.05.047CrossRef

Ayangbenro A, Babalola O (2017) Review a new strategy for heavy metal polluted environments: a review of microbial bio-sorbents. Int J Environ Res Public Health 14:94. https://doi.org/10.3390/ijerph14010094CrossRefPubMedCentral

Bhattacharyya A, Banerjee B, Ghorai S, Rana D, Roy I, Sarkar G, Saha N, De S, Ghosh T, Sadhukhan S, Chattopadhy D (2018) Development of an auto-phase separable and reusable graphene oxidepotato starch based cross-linked bio-composite adsorbent for removal of methylene blue dye. Int J Biol Macromol 116:1037–1048. https://doi.org/10.1016/j.ijbiomac.2018.05.069CrossRefPubMed

Aljeboree A, Alshirifi A, Alkaim A (2017) Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon. Arab J Chem 10:S3381–S3393. https://doi.org/10.1016/j.arabjc.2014.01.020CrossRef

Bello O, Adegoke K, Akinyunni O (2017) Preparation and characterization of a novel adsorbent from Moringa oleifera leaf. Appl Water Sci 7:1295–1305. https://doi.org/10.1007/s13201-015-0345-4CrossRef

10.

Aichour A, Zaghouane-Boudiaf H (2019) Highly brilliant green removal from wastewater by mesoporous adsorbents: kinetics, thermodynamics and equilibrium isotherm studies. Microchem J 146:1255–1262. https://doi.org/10.1016/j.microc.2019.02.040CrossRef

11.

Geissen V, Mol H, Klumpp E, Umlauf G, Nadal M, van der Ploeg M, van de Zee S, Ritsema C (2015) Emerging pollutants in the environment: a challenge for water resource management. Int Soil Water Conserv Res 3:57–65. https://doi.org/10.1016/j.iswcr.2015.03.002CrossRef

12.

Tang P, Sun Q, Zhao L, Tang Y, Liu Y, Pu H, Gan N, Liu Y, Li H (2019) A simple and green method to construct cyclodextrin polymer for the effective and simultaneous estrogen pollutant and metal removal. Chem Eng J 366:598–607. https://doi.org/10.1016/j.cej.2019.02.117CrossRef

13.

Ali I, Basheer A, Mbianda X, Burakov A, Galunin E, Burakova I, Mkrtchyan E, Tkachev A, Grachev V (2019) Graphene based adsorbents for remediation of noxious pollutants from wastewater. Environ Int 127:160–180. https://doi.org/10.1016/j.envint.2019.03.029CrossRefPubMed

14.

Hu F, Wang Z, Zhu B, Zhu L, Xu Y (2018) Poly (N-vinyl imidazole) gel-filled membrane adsorbers for highly efficient removal of dyes from water. J Chromatogr A 1563:198–206. https://doi.org/10.1016/j.chroma.2018.05.075CrossRefPubMed

15.

Arsh A (2018) New generation nano-adsorbents for the removal of emerging contaminants in water. J Mol Liq 261:583–593CrossRef

16.

Kennedy K, Maseka K, Mbulo M (2018) Selected adsorbents for removal of contaminants from wastewater: towards engineering clay minerals. Open J Appl Sci 8:355–369. https://doi.org/10.4236/ojapps.2018.88027CrossRef

17.

Anjum H, Johari K, Arunagiri A, Gnanasundaram N, Thanabalan M (2019) Surface modification and characterization of carbonaceous adsorbents for the efficient removal of oil pollutants. J Hazard Mater 379:127603. https://doi.org/10.1016/j.jhazmat.2019.05.066CrossRef

18.

Gisi S, Lofrano G, Grassi M, Notarnicola M (2016) Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: a review. Sustain Mater Technol 9:10–40. https://doi.org/10.1016/j.susmat.2016.06.002CrossRef

19.

Benhachem F, Attar T, Bouabdallah F (2019) Kinetic study of adsorption methylene blue dye from aqueous solutions using activated carbon from starch. Che Rev Lett 2:33–39. https://doi.org/10.1016/j.cej.2005.12.012CrossRef

20.

Bello M, Raman A (2018) Adsorption and oxidation techniques to remove organic pollutants from water. In: Crini G, Lichtfouse E (eds) Green adsorbents for pollutant removal environmental chemistry for a sustainable world, vol 18. Springer, Cham

21.

Khulbe KC, Matsuura T (2018) Removal of heavy metals and pollutants by membrane adsorption techniques Appl Water Sci 8:19. https://doi.org/10.1007/s13201-018-0661-6CrossRef

22.

Sivashankar R, Sathya A, Vasantharaj K, Sivasubramanian V (2014) Magnetic composite an environmental super adsorbent for dye sequestration. Environ Nanotechnol Monit Manag 1–2:36–49. https://doi.org/10.1016/j.enmm.2014.06.001CrossRef

23.

Sadegh H, Ali GAM, Gupta VK, Hamdy A, Shahryari-ghoshekandi R, Nadagouda M, Sillanpaa M, Megiel E (2017) The role of nanomaterials as effective adsorbents and their applications in wastewater treatment. J Nanostruct Chem 7:1–14. https://doi.org/10.1007/s40097-017-0219-4CrossRef

24.

Lawal I, Klink M, Ndungu P, Moodley B (2019) Brief bibliometric analysis of “ionic liquid” applications and its review as a substitute for common adsorbent modifier for the adsorption of organic pollutants. Environ Res 175:34–51. https://doi.org/10.1016/j.envres.2019.05.005CrossRefPubMed

25.

Naidu M, Sean P, Jye W, Fauzi A (2019) The roles of nanomaterials in conventional and emerging technologies for heavy metal removal: a state of the art review. Nanomaterials 9:625. https://doi.org/10.3390/nano9040625CrossRef

26.

Adeniyi A, Ighalo J (2019) Biosorption of pollutants by plant leaves: an empirical review. J Environ Chem Eng 7:103100. https://doi.org/10.1016/j.jece.2019.103100CrossRef

27.

El-Azazy M, Kalla R, Issa A, Al-Sulaiti M, El-Shafie A, Shomar B, Al-Saad K (2019) Pomegranate peels as versatile adsorbents for water purification: application of Box–Behnken design as a methodological optimization approach. Environ Prog Sustain Energy. https://doi.org/10.1002/ep.13223CrossRef

28.

Haq F, Yu H, Wang L, Teng L, Haroon M, Khan R, Mehmood S, Amin B, Ullah R, Khan A, Nazir A (2019) Advances in chemical modifications of starches and their applications. Carbohydr Res 476:12–35. https://doi.org/10.1016/j.carres.2019.02.007CrossRefPubMed

29.

Cheng R, Ou S (2011) Application of modified starches in wastewater treatment. In: Méndez-Vilas A, Solano A (eds) Polymer science: research advances, practical applications and educational aspects. ISBN-10: 8494213482

30.

Schwantes D, Goncalves A, Miola A, Ferreira G, Goncalves Dos Santos M, Volz Lismann E (2015) Removal of Cu (II) and Zn (II) from water with natural adsorbents from cassava agroindustry residues. Act Scientiarum Technol 37:409–417. https://doi.org/10.4025/actascitechnol.v37i3.26809CrossRef

31.

Zhu F (2019) Recent advances in modifications and applications of sago starch. Food Hydrocoll 96:412–423. https://doi.org/10.1016/j.foodhyd.2019.05.035CrossRef

32.

Kaveh Z, Azadmard-Damirchi S, Yousefi G, Hosseini SMH (2019) Effect of different alcoholic-alkaline treatments on physical and mucoadhesive properties of tapioca starch. Int J Biol Macromol. https://doi.org/10.1016/j.ijbiomac.2019.10.230CrossRefPubMed

33.

Qian SY, Tang MQ, Gao Q, Wang XW, Zhang JW, Tanokura M, Xue YL (2019) Effects of different modification methods on the physicochemical and rheological properties of Chinese yam (Dioscorea opposita Thunb.) starch. LWT 116:108513–108521. https://doi.org/10.1016/j.lwt.2019.108513CrossRef

34.

Haroon M, Wang L, Yu H, Abbasi N, Abdin Z, Saleem M, Khan R, Ullah R, Chen Q, Wu J (2016) Chemical modification of starch and its application as an adsorbent material. Royal Soc Chem Adv 6:78264–78285. https://doi.org/10.1039/C6RA16795KCrossRef

35.

Charles J, Bradu C, Morin-Crini N, Sancey B, Winterton P, Torri G, Badot P-M, Crini G (2016) Pollutant removal from industrial discharge water using individual and combined effects of adsorption and ion-exchange processes: Chemical abatement. J Saudi Chem Soc 20:185–194. https://doi.org/10.1016/j.jscs.2013.03.007CrossRef

36.

Bai W, Fan L, Zhou Y, Zhang Y, Shi J, Lv G, Wu Y, Liu Q, Song J (2017) Removal of Cd²⁺ ions from aqueous solution using cassava starch-based superabsorbent polymers. J Appl Polym Sci 44758:1–12. https://doi.org/10.1002/app.44758CrossRef

37.

Hosseinzadeh H, Ramin S (2018) Fabrication of starch-graft-poly(acrylamide)/graphene oxide/hydroxyapatite nanocomposite hydrogel adsorbent for removal of malachite green dye from aqueous solution. Int J Biol Macromol 106:101–115. https://doi.org/10.1016/j.ijbiomac.2017.07.182CrossRefPubMed

38.

Takeda C, Takeda Y, Hizukuri S (1893) Physicochemical properties of lily starch. Cereal Chem 60:212–216

39.

Kweon DK, Choi JKEK, Kim S, Lim T (2001) Adsorption of divalent metal ions by succinylated and oxidized corn starches. Carbohydr Polym 46:171–177. https://doi.org/10.1016/S0144-8617(00)00300-3CrossRef

40.

Wurburg OB (1964) Acetylation. In: Whistler RL, Smith RJ, Wolfram ML (eds) Methods in carbohydrate chemistry, vol IV. Academic Press, New York, pp 240–241

41.

Leach HW, McCowenm LD, Scoch TJ (1959) Structure of starch granule. Swelling and solubility patterns of various starches. Cereal Chem 36:534–544

42.

Lagergren S (1898) Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens, Handlingar. Band 24:1–39

43.

Ho YS, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ Protect 76:332–340. https://doi.org/10.1205/095758298529696CrossRef

44.

Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div Am Soc Civ Eng 89:31–60

45.

Altuna L, Herrera ML, Foresti ML (2018) Synthesis and characterization of octenyl succinic anhydride modified starches for food applications. A review of recent literature. Food Hydrocoll 80:97–110. https://doi.org/10.1016/j.foodhyd.2018.01.032CrossRef

46.

Kumoro C, Retnowati DS, Budiyati CS, Manurung T, Siswanto. (2012) Water solubility, swelling and gelatinization properties of raw and ginger oil modified gadung (Dioscorea hispida dennst) flour. Res J Appl Sci Eng Technol 4:2854–2860

47.

Todica M, Nagy E, Niculaescu C, Stan O, Cioica N, Pop C (2016) XRD investigation of some thermal degraded starch based materials. J Spectrosc ID 9605312. https://doi.org/10.1155/2016/9605312

48.

Sangian H, Telleng R, Aruan I, Mosey H, Tamintuan G (2018) The structural modification of cassava starch using a saline water pretreatment. Food Sci Technol 38:215–220. https://doi.org/10.1590/1678-457x.18517CrossRef

49.

Garrido L, Schnitzler E, Boff M, de Souza T, Mottin I (2014) Physicochemical properties of cassava starch oxidized by sodium hypochlorite. J Food Sci Technol 51:2640–2647. https://doi.org/10.1007/s13197-012-0794-9CrossRefPubMed

50.

Okazaki M (2018) The structure and characteristics of sago starch. In: Ehara H, Toyoda Y, Johnson D (eds) Sago Palm. Springer, Singapore, pp 247–259CrossRef

51.

Xu A, Guo K, Liu T, Bian X, Zhang L, Wei C (2018) Effects of different isolation media on structural and functional properties of starches from root tubers of purple, yellow and white sweet potatoes. Mol 23:2135–2152. https://doi.org/10.3390/molecules23092135CrossRef

52.

Abarca RL, Rodríguez F, Guarda A, Galotto MJ, Bruna J (2016) Characterization of beta-cyclodextrin inclusion complexes containing an essential oil component. Food Chem 196:968–975. https://doi.org/10.1016/j.foodchem.2015.10.023CrossRefPubMed

53.

Alvarado N, Romero J, Torres A, Lopez de Dicastillo C, Rojas A, Galotto MJ, Guarda A (2018) Supercritical impregnation of thymol in poly(lactic acid) filled with electrospun poly(vinyl alcohol)-cellulose nanocrystals nanofibers: development an active food packaging material. J Food Eng 217:1–10. https://doi.org/10.1016/j.jfoodeng.2017.08.008CrossRef

54.

Alvarado N, Fuentes I, Alegría L, Sandoval C, Kortaberıa G, Eceiza A, Gargallo L, Leiva A, Radic D (2015) Interactions in blends of dendronized polymeric nanocomposites with some common drugs. J Appl Polym Sci 132:42450–42459. https://doi.org/10.1002/app.42450CrossRef

55.

Kizil R, Irudayaraj J, Seetharaman K (2002) Characterization of irradiated starches by using FT-Raman and FTIR spectroscopy. J Agric Food Chem 50:3912–3918. https://doi.org/10.1021/jf011652pCrossRefPubMed

56.

Zhang B, Huang Q, Luo F, Fu X, Jiang H, Jane J (2011) Effects of octenylsuccinylation on the structure and properties of high-amylose maize starch. Carbohydr Polym 84:1276–1281. https://doi.org/10.1016/j.carbpol.2011.01.020CrossRef

57.

Lindeboom N, Chang PR, Tyler RT (2004) Analytical, biochemical and physicochemical aspects of starch granule size, with emphasis on small granule starches: a review. Starch/Stärke 56:89–99. https://doi.org/10.1002/star.200300218CrossRef

58.

Ayala G, Djabourov M, Amaral P (2016) Water desorption of cassava starch granules: A study based on thermogravimetric analysis of aqueous suspensions and humid powders. Carbohydr Polym 147:533–541. https://doi.org/10.1016/j.carbpol.2016.04.030CrossRef

59.

Lv Y, Zhang L, Li M, He X, Hao L, Dai Y (2019) Physicochemical properties and digestibility of potato starch treated by ball milling with tea polyphenols. Int J Biol Macromol 129:207–213. https://doi.org/10.1016/j.ijbiomac.2019.02.028CrossRefPubMed

60.

Siyamak S, Laycock B, Luckman P (2019) Synthesis of starch graft-copolymers via reactive extrusion: process development and structural analysis. Carbohydr Polym. https://doi.org/10.1016/j.carbpol.2019.115066CrossRefPubMed

61.

Zhang K, Dai Y, Hou H, Li X, Dong H, Wang W, Zhang H (2019) Influences of grinding on structures and properties of mung bean starch and quality of acetylated starch. Food Chem 294:285–292. https://doi.org/10.1016/j.foodchem.2019.05.055CrossRefPubMed

62.

Soto D, Urdaneta J, Pernía K, León O, Muñoz-Bonilla A, Fernandez-García M (2015) Removal of heavy metal ions in water by starch esters. Starch/Stärke 56:89–99. https://doi.org/10.1002/star.201500155CrossRef

63.

Broido A (1969) A simple, sensitive graphical method of treating thermogravimetric analysis data. J Polym Sci Part B: Polym Phys 7:1761–1773. https://doi.org/10.1002/pol.1969.160071012CrossRef

64.

Zohuriaan MJ, Shokrolahi F (2004) Thermal studies on natural and modified gums. Polym Test 23:575–579. https://doi.org/10.1016/j.polymertesting.2003.11.001CrossRef

65.

Zdanowicz M, Spychaj T, Lendzion-Bielun Z (2014) Crosslinked carboxymethyl starch: one step synthesis and sorption characteristics. Int J Biol Macromol 71:87–93. https://doi.org/10.1016/j.ijbiomac.2014.04.043CrossRefPubMed

66.

Delval F, Crini G, Bertini S, Filiatre C, Torri G (2005) Preparation, characterization and sorption properties of crosslinked starch-based exchangers. Carbohydr Polym 60:67–75. https://doi.org/10.1016/j.carbpol.2004.11.025CrossRef

67.

Abdel-Halim ES (2013) Preparation of starch/poly(N, N-Diethylaminoethyl methacrylate) hydrogel and its use in dye removal from aqueous solutions. React Funct Polym 73:1531–1536. https://doi.org/10.1016/j.reactfunctpolym.2013.08.003CrossRef

68.

Xiang B, Fan W, Yi X, Wang Z, Gao F, Li Y, Gu H (2016) Dithiocarbamate-modified starch derivatives with high heavy metal adsorption performance. Carbohydr Polym 136:30–37. https://doi.org/10.1016/j.carbpol.2015.08.065CrossRefPubMed

69.

Sumalinog DAG, Capareda SC, de Luna MDG (2018) Evaluation of the effectiveness and mechanisms of acetaminophen and methylene blue dye adsorption on activated biochar derived from municipal solid wastes. J Environ Manag 210:255–262. https://doi.org/10.1016/j.jenvman.2018.01.010CrossRef

70.

Doğan M, Abak H, Alkan M (2009) Adsorption of methylene blue onto hazelnut shell: kinetics, mechanism and activation parameters. J Hazard Mater 164:172–181. https://doi.org/10.1016/j.jhazmat.2008.07.155CrossRefPubMed

71.

Zhang W, Zhang LY, Zhao XJ, Zhou Z (2016) Citrus pectin derived porous carbons as a superior adsorbent toward removal of methylene blue. J Solid State Chem 243:101–105. https://doi.org/10.1016/j.jssc.2016.08.014CrossRef

Titel: Cassava starch: structural modification for development of a bio-adsorber for aqueous pollutants. Characterization and adsorption studies on methylene blue
verfasst von: Nancy Alvarado
Romina L. Abarca
José Urdaneta
Julio Romero
María José Galotto
Abel Guarda
Publikationsdatum: 04.03.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 2/2021
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-020-03149-9

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