nach oben

Erschienen in:

2017 | OriginalPaper | Buchkapitel

8. Catalytic Pyrolysis of Biomass

verfasst von : Samira Bagheri

Erschienen in: Catalysis for Green Energy and Technology

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A process which involved thermochemical conversion for the in situ upgrading the quality of the bio-oil (pyrolysis oil) in the pyrolysis reactor with the used of heterogeneous catalyst as a heat carrier is called as catalytic pyrolysis of biomass. The upgrading of bio-oil was carried out to minimize the undesirable properties such as high viscosity, high oxygen and water content, instability, corrosivity and low heating value of the bio-oil. In the industry of petrochemical that was utilised to convert heavy oil fractions into chemicals and also lighter fuels, heterogeneous catalysis is used widely.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Catalytic Upgrading of Glycerol, Conversion of Biomass Derived Carbohydrates to Fuels and Catalysis in Depolymerization of Lignin

Nächstes Kapitel Catalytic Upgrading of Bio-oil: Biomass Gasification in the Presence of Catalysts

Adam J, Blazso M, Meszaros E, Stöcker M, Nilsen MH, Bouzga A, Hustad JE, Grønli M, Øye G (2005) Pyrolysis of biomass in the presence of Al-MCM-41 type catalysts. Fuel 84(12):1494–1502

Adam J, Antonakou E, Lappas A, Stöcker M, Nilsen MH, Bouzga A, Hustad JE, Øye G (2006) In situ catalytic upgrading of biomass derived fast pyrolysis vapours in a fixed bed reactor using mesoporous materials. Microporous Mesoporous Mater 96(1):93–101CrossRef

Adjaye JD, Bakhshi N (1995) Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: conversion over various catalysts. Fuel Process Technol 45(3):161–183CrossRef

Adjaye JD, Katikaneni SP, Bakhshi NN (1996) Catalytic conversion of a biofuel to hydrocarbons: effect of mixtures of HZSM-5 and silica-alumina catalysts on product distribution. Fuel Process Technol 48(2):115–143CrossRef

Aho A, Kumar N, Eränen K, Salmi T, Hupa M, Murzin DY (2007) Catalytic pyrolysis of biomass in a fluidized bed reactor: influence of the acidity of H-beta zeolite. Process Saf Environ Prot 85(5):473–480CrossRef

Aho A, Kumar N, Eränen K, Salmi T, Hupa M, Murzin DY (2008) Catalytic pyrolysis of woody biomass in a fluidized bed reactor: influence of the zeolite structure. Fuel 87(12):2493–2501CrossRef

Aho A, Kumar N, Lashkul A, Eränen K, Ziolek M, Decyk P, Salmi T, Holmbom B, Hupa M, Murzin DY (2010) Catalytic upgrading of woody biomass derived pyrolysis vapours over iron modified zeolites in a dual-fluidized bed reactor. Fuel 89(8):1992–2000CrossRef

Antonakou E, Lappas A, Nilsen MH, Bouzga A, Stöcker M (2006) Evaluation of various types of Al-MCM-41 materials as catalysts in biomass pyrolysis for the production of bio-fuels and chemicals. Fuel 85(14):2202–2212CrossRef

Atutxa A, Aguado R, Gayubo AG, Olazar M, Bilbao J (2005) Kinetic description of the catalytic pyrolysis of biomass in a conical spouted bed reactor. Energy Fuels 19(3):765–774CrossRef

Babich I, Van der Hulst M, Lefferts L, Moulijn J, O’Connor P, Seshan K (2011) Catalytic pyrolysis of microalgae to high-quality liquid bio-fuels. Biomass Bioenerg 35(7):3199–3207CrossRef

Bridgwater A (1994) Catalysis in thermal biomass conversion. Appl Catal A 116(1–2):5–47CrossRef

Carlson TR, Vispute TP, Huber GW (2008) Green gasoline by catalytic fast pyrolysis of solid biomass derived compounds. Chemsuschem 1(5):397–400CrossRef

Carlson TR, Tompsett GA, Conner WC, Huber GW (2009) Aromatic production from catalytic fast pyrolysis of biomass-derived feedstocks. Top Catal 52(3):241CrossRef

Chen M-q, Wang J, Zhang M-x, Chen M-g, Zhu X-f, Min F-f, Tan Z-c (2008) Catalytic effects of eight inorganic additives on pyrolysis of pine wood sawdust by microwave heating. J Anal Appl Pyrol 82(1):145–150CrossRef

Deng L, Fu Y, Guo Q-X (2008) Upgraded acidic components of bio-oil through catalytic ketonic condensation. Energy Fuels 23(1):564–568CrossRef

Ernst S, Hartmann M, Sauerbeck S, Bongers T (2000) A novel family of solid basic catalysts obtained by nitridation of crystalline microporous aluminosilicates and aluminophosphates. Appl Catal A 200(1):117–123CrossRef

Fabbri D, Torri C, Baravelli V (2007) Effect of zeolites and nanopowder metal oxides on the distribution of chiral anhydrosugars evolved from pyrolysis of cellulose: an analytical study. J Anal Appl Pyrol 80(1):24–29CrossRef

French R, Czernik S (2010) Catalytic pyrolysis of biomass for biofuels production. Fuel Process Technol 91(1):25–32CrossRef

Gaertner CA, Serrano-Ruiz JC, Braden DJ, Dumesic JA (2009) Catalytic coupling of carboxylic acids by ketonization as a processing step in biomass conversion. J Catal 266(1):71–78CrossRef

Gayubo AG, Aguayo AT, Atutxa A, Aguado R, Olazar M, Bilbao J (2004a) Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. II. Aldehydes, ketones, and acids. Ind Eng Chem Res 43(11):2619–2626CrossRef

Gayubo AG, Aguayo AT, Atutxa A, Prieto R, Bilbao J (2004b) Deactivation of a HZSM-5 zeolite catalyst in the transformation of the aqueous fraction of biomass pyrolysis oil into hydrocarbons. Energy Fuels 18(6):1640–1647CrossRef

Gayubo AG, Aguayo AT, Atutxa A, Valle B, Bilbao J (2005) Undesired components in the transformation of biomass pyrolysis oil into hydrocarbons on an HZSM-5 zeolite catalyst. J Chem Technol Biotechnol 80(11):1244–1251CrossRef

Horne PA, Williams PT (1994) Premium quality fuels and chemicals from the fluidised bed pyrolysis of biomass with zeolite catalyst upgrading. Renew Energy 5(5–8):810–812CrossRef

Horne PA, Williams PT (1996a) Reaction of oxygenated biomass pyrolysis model compounds over a ZSM-5 catalyst. Renew Energy 7(2):131–144CrossRef

Horne PA, Williams PT (1996b) Upgrading of biomass-derived pyrolytic vapours over zeolite ZSM-5 catalyst: effect of catalyst dilution on product yields. Fuel 75(9):1043–1050CrossRef

Iliopoulou E, Antonakou E, Karakoulia S, Vasalos I, Lappas A, Triantafyllidis K (2007) Catalytic conversion of biomass pyrolysis products by mesoporous materials: effect of steam stability and acidity of Al-MCM-41 catalysts. Chem Eng J 134(1):51–57CrossRef

Jackson MA, Compton DL, Boateng AA (2009) Screening heterogeneous catalysts for the pyrolysis of lignin. J Anal Appl Pyrol 85(1):226–230CrossRef

Lappas A, Samolada M, Iatridis D, Voutetakis S, Vasalos I (2002) Biomass pyrolysis in a circulating fluid bed reactor for the production of fuels and chemicals. Fuel 81(16):2087–2095CrossRef

Lee HI, Park HJ, Park Y-K, Hur JY, Jeon J-K, Kim JM (2008) Synthesis of highly stable mesoporous aluminosilicates from commercially available zeolites and their application to the pyrolysis of woody biomass. Catal Today 132(1):68–74CrossRef

Lu Q, Zhu X, Li W, Zhang Y, Chen D (2009) On-line catalytic upgrading of biomass fast pyrolysis products. Chin Sci Bull 54(11):1941–1948

Lu Q, Zhang Z-F, Dong C-Q, Zhu X-F (2010) Catalytic upgrading of biomass fast pyrolysis vapors with nano metal oxides: an analytical Py-GC/MS study. Energies 3(11):1805–1820CrossRef

Mullen CA, Boateng AA (2010) Catalytic pyrolysis-GC/MS of lignin from several sources. Fuel Process Technol 91(11):1446–1458CrossRef

Nilsen MH, Antonakou E, Bouzga A, Lappas A, Mathisen K, Stöcker M (2007) Investigation of the effect of metal sites in Me–Al-MCM-41 (Me = Fe, Cu or Zn) on the catalytic behavior during the pyrolysis of wooden based biomass. Microporous Mesoporous Mater 105(1):189–203CrossRef

Nokkosmäki M, Kuoppala E, Leppämäki E, Krause A (2000) Catalytic conversion of biomass pyrolysis vapours with zinc oxide. J Anal Appl Pyrol 55(1):119–131CrossRef

Park HJ, Dong J, Jeon J, Yoo K, Yim J, Sohn JM, Park Y (2007) Conversion of the pyrolytic vapor of radiata pine over zeolites. J Ind Eng Chem-Seoul 13(2):182

Park HJ, Heo HS, Jeon J-K, Kim J, Ryoo R, Jeong K-E, Park Y-K (2010) Highly valuable chemicals production from catalytic upgrading of radiata pine sawdust-derived pyrolytic vapors over mesoporous MFI zeolites. Appl Catal B 95(3):365–373CrossRef

Pattiya A, Titiloye JO, Bridgwater AV (2008) Fast pyrolysis of cassava rhizome in the presence of catalysts. J Anal Appl Pyrol 81(1):72–79CrossRef

Peralta MA, Sooknoi T, Danuthai T, Resasco DE (2009) Deoxygenation of benzaldehyde over CsNaX zeolites. J Mol Catal A Chem 312(1):78–86CrossRef

Qi W, Hu C, Li G, Guo L, Yang Y, Luo J, Miao X, Du Y (2006) Catalytic pyrolysis of several kinds of bamboos over zeolite NaY. Green Chem 8(2):183–190CrossRef

Samolada M, Papafotica A, Vasalos I (2000) Catalyst evaluation for catalytic biomass pyrolysis. Energy Fuels 14(6):1161–1167CrossRef

Stefanidis S, Kalogiannis K, Iliopoulou E, Lappas A, Pilavachi P (2011) In-situ upgrading of biomass pyrolysis vapors: catalyst screening on a fixed bed reactor. Biores Technol 102(17):8261–8267CrossRef

Thring RW, Katikaneni SP, Bakhshi NN (2000) The production of gasoline range hydrocarbons from Alcell® lignin using HZSM-5 catalyst. Fuel Process Technol 62(1):17–30CrossRef

Torri C, Reinikainen M, Lindfors C, Fabbri D, Oasmaa A, Kuoppala E (2010) Investigation on catalytic pyrolysis of pine sawdust: catalyst screening by Py-GC-MIP-AED. J Anal Appl Pyrol 88(1):7–13CrossRef

Triantafyllidis KS, Iliopoulou EF, Antonakou EV, Lappas AA, Wang H, Pinnavaia TJ (2007) Hydrothermally stable mesoporous aluminosilicates (MSU-S) assembled from zeolite seeds as catalysts for biomass pyrolysis. Microporous Mesoporous Mater 99(1):132–139CrossRef

Uzun BB, Sarioğlu N (2009) Rapid and catalytic pyrolysis of corn stalks. Fuel Process Technol 90(5):705–716CrossRef

Vitolo S, Bresci B, Seggiani M, Gallo M (2001) Catalytic upgrading of pyrolytic oils over HZSM-5 zeolite: behaviour of the catalyst when used in repeated upgrading–regenerating cycles. Fuel 80(1):17–26CrossRef

Wang D, Xiao R, Zhang H, He G (2010) Comparison of catalytic pyrolysis of biomass with MCM-41 and CaO catalysts by using TGA–FTIR analysis. J Anal Appl Pyrol 89(2):171–177CrossRef

Williams PT, Horne PA (1994) Characterisation of oils from the fluidised bed pyrolysis of biomass with zeolite catalyst upgrading. Biomass Bioenerg 7(1–6):223–236CrossRef

Williams PT, Horne PA (1995a) Analysis of aromatic hydrocarbons in pyrolytic oil derived from biomass. J Anal Appl Pyrol 31:15–37CrossRef

Williams PT, Horne PA (1995b) The influence of catalyst type on the composition of upgraded biomass pyrolysis oils. J Anal Appl Pyrol 31:39–61CrossRef

Zhang H, Xiao R, Huang H, Xiao G (2009) Comparison of non-catalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor. Biores Technol 100(3):1428–1434CrossRef

Zhu X, Lu Q, Li W, Zhang D (2010) Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M = Fe, Zn) catalysts on pyrolytic products. Front Energy Power Eng Chin 4(3):424–429CrossRef

Titel: Catalytic Pyrolysis of Biomass
verfasst von: Samira Bagheri
Verlag: Springer International Publishing
Buch: Catalysis for Green Energy and Technology
Print ISBN: 978-3-319-43103-1

Electronic ISBN: 978-3-319-43104-8

Copyright-Jahr: 2017
DOI: https://doi.org/10.1007/978-3-319-43104-8_8