nach oben

Cellulose

Erschienen in:

14.10.2022 | Original Research

Cellulose-ceramic composite flexible paper separator with improved wettability and flame retardant properties for lithium-ion batteries

verfasst von: Mononita Das, Pradip Sekhar Das, Rajendra Nath Basu, Mir Wasim Raja

Erschienen in: Cellulose | Ausgabe 18/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In quest of developing sustainable separator for lithium-ion batteries (LIBs), this research focuses on functionalization of low cost cellulose based commercial paper using duo-polymer and nano-SiO₂ by designing a facile aqueous based industry friendly wet-coating process. Unlike commercial plastic based polyolefin separators (polypropylene/polyethylene), the developed paper separator shows superior thermal stability > 200 °C without dimensional shrinkage, excellent electrolyte wettability (147%) with zero contact angle, quicker electrolyte saturation and satisfactory mechanical strength (34.86–38.31 MPa). The electrochemical performance carried out in 2032 coin cells using fabricated paper separators shows comparable performance to that of commercial polypropylene (PP) based separator at different current densities of 0.05–0.4 mA/cm² with excellent columbic efficiency (> 96%) and good capacity retention on cycling. The developed separator is found to be compatible with most of the commercial electrodes (MCMB, LiCoO₂, LiFePO₄) used in today’s LIBs. The functionalized cellulose-ceramic composite paper separator shows excellent flame retardant properties by offering an added safety features for its successful use in lithium-ion batteries.

Graphical abstract

Vorheriger Artikel Cellulose nanofiber-reinforced dissolving microneedles for transdermal delivery of a water-soluble compound

Nächster Artikel Optical 3D crepe reconstruction for industrial base tissue paper characterization

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Alongi J, Camino G, Malucelli G (2013) Heating rate effect on char yield from cotton, poly(ethylene terephthalate) and blend fabrics. Carbohydr Polym 92(2):1327–1334. https://doi.org/10.1016/j.carbpol.2012.10.029CrossRef

Asadpoordarvish A, Sandström A, Larsen C, Bollström R, Toivakka M, Österbacka R, Edman L (2015) Light-emitting paper. Adv Funct Mater 25(21):3238–3245. https://doi.org/10.1002/adfm.201500528CrossRef

Chena W, Shib L, Wang Z, Zhu J, Yang H, Mao X, Chib M, Sun L, Yuan S (2016) Porous cellulose diacetate-SiO₂ composite coating on polyethylene separator for high-performance lithium-ion battery. Carbohydr Polym 147:517–524. https://doi.org/10.1016/j.carbpol.2016.04.046CrossRef

Chetouani A, Elkolli M, Bounekhel M, Benachour D (2017) Chitosan/oxidized pectin/PVA blend film: mechanical and biological properties. Polym Bull 74:4297–4310. https://doi.org/10.1007/s00289-017-1953-yCrossRef

Chun SJ, Choi ES, Lee EH, Kim JH, Lee SY, Lee SY (2012) Eco-friendly cellulose nanofiber paper-derived separator membranes featuring tunable nanoporous network channels for lithium-ion batteries. J Mater Chem 22(32):16618–16626. https://doi.org/10.1039/C2JM32415FCrossRef

Deimede V, Elmasides C (2015) Separators for lithium-ion batteries: a review on the production processes and recent developments. Energ Technol 3(5):453–468. https://doi.org/10.1002/ente.201402215CrossRef

Fang Z, Zhu H, Yuan Y, Ha D, Zhu S, Preston C, Chen Q, Li Y, Han X, Lee S, Chen G, Li T, Munday J, Huang J, Hu L (2014) Novel nanostructured paper with ultrahigh transparency and ultrahigh haze for solar cells. Nano Letter 14(2):765–773. https://doi.org/10.1021/nl404101pCrossRef

Gogia A, Wang Y, Rai AK, Bhattacharya R, Subramanyam G, Kumar J (2021) Thin-film ceramic-coated separators for improved safety of lithium-ion batteries. ACS Omega 6(6):4204–4211. https://doi.org/10.1021/acsomega.0c05037CrossRefPubMedPubMedCentral

Ha D, Fang Z, Zhitenev NB (2018) Paper in electronic and optoelectronic devices. Adv Electron Mater 4(5):1700593–1700613. https://doi.org/10.1002/aelm.201700593CrossRef

Jang ES, Kang CW, Jang SS (2018) Comparison of the mercury intrusion porosimerty, capillary flow porometry and gas permeability of eleven species of Korean wood. J Korean Wood Sci Technol 46(4):681–691. https://doi.org/10.5658/WOOD.2018.46.6.681CrossRef

Laura V, Marianna L, Inse S, Linda R, Uldis G, Juris Z, Raphael P, Evelyn M (2017) Effect of chitosan on properties of paper for packagaing. Cellul Chem Technol 51(12):67–73. Corpus ID: 115142608

Lien DH, Kao ZK, Huang TH, Liao YC, Lee SC, He JH (2014) All-printed paper memory. ACS Nano 8(8):7613–7619. https://doi.org/10.1021/nn501231zCrossRefPubMed

Liu C, Shao Z, Wang J, Lu C, Wang Z (2016) Eco-friendly polyvinyl alcohol/cellulose nanofiber-Li+ composite separator for high-performance lithium-ion battery. RSC Adv 6(100):97912–97920. https://doi.org/10.1039/C6RA18471ECrossRef

Mirzaeian M, Abbas Q, Ogwu A, Hall P, Goldin M (2017) Electrode and electrolyte materials for electrochemical capacitors. Int J Hydrogen Energy 42(40):25565–25587. https://doi.org/10.1016/j.ijhydene.2017.04.241CrossRef

Oliveira FC, Timmons AB, Lopes-da-Silva JA (2010) Preparation and characterization of chitosan/SiO2 composite films. J Nanosci Nanotechnol 10(4):2816–2825. https://doi.org/10.1166/jnn.2010.1442CrossRefPubMed

Orendorff CJ (2012) The role of separators in lithium-ion cell safety. Interface-Electrochem Soc 21(2):61–65. https://doi.org/10.1149/2.F07122ifCrossRef

Osińska M, Walkowiak M, Zalewska A, Jesionowski T (2009) Study of the role of ceramic filler in composite gel electrolytes based on microporous polymer membranes. J Membr Sci 326(2):582–588. https://doi.org/10.1016/j.memsci.2008.10.036CrossRef

Pingan H, Mengjun J, Yanyan Z, Ling H (2017) A silica/PVA adhesive hybrid material with high transparency, thermostability and mechanical strength. RSC Adv 7(5):2450–2459. https://doi.org/10.1039/C6RA25579ECrossRef

Qolby S, Christin RR, Andri H, Titik L, Achmad S, Abdulloh R, Rike Y, Hiroshi U (2021) Preparation and characterization of nanofibrous cellulose as solid polymer electrolyte for lithium-ion battery applications. RSC Adv 11:22929–22936. https://doi.org/10.1039/D1RA03480DCrossRef

Raja MW, Basu RN, Pramanik NC, Das PS, Das M (2022) Paperator: the paper-based ceramic separator for lithium-ion batteries and the process scale-up strategy. ACS Appl Energy Mater 5(5):5841–5854. https://doi.org/10.1021/acsaem.2c00188CrossRef

Roberts JC (1996) The chemistry of paper. Royal Soc Chem-UK. https://doi.org/10.1039/9781847552068CrossRef

Sugantha VK, Khaleel SB, Sudha PN (2012) Physicochemical and morphological evaluation of chitosan/poly(vinyl alcohol)/methylcellulose chemically cross-linked ternary blends. Polym Bull 68(5):1387–1393. https://doi.org/10.1007/s00289-011-0645-2CrossRef

Sun C, Goharpey AH, Rai A, Zhang T, Ko DK (2016) Paper thermoelectrics: merging nanotechnology with naturally abundant fibrous material. ACS Appl Mater Interfaces 8(34):22182–22189. https://doi.org/10.1021/acsami.6b05843CrossRefPubMed

Visakh PM, Yoshihiko A (2015) Flame retardants: polymer blends. Springer International Publishing-Switzerland, Composites and nanocomposites. https://doi.org/10.1007/978-3-319-03467-6CrossRef

Wang Y, Jow J, Su K, Zhang J (2012) Development of the unsteady upward fire model to simulate polymer burning under UL94 vertical test conditions. Fire Saf J 54(1):1–13. https://doi.org/10.1016/j.firesaf.2012.08.001CrossRef

Wang Z, Xiang H, Wang L, Xia R, Nie S, Chen C, Wang H (2018) A paper-supported inorganic composite separator for high-safety lithium-ion batteries. J Membr Sci 553(1):10–16. https://doi.org/10.1016/j.memsci.2018.02.040CrossRef

Xu Q, Kong Q, Liu Z, Wang X, Liu R, Zhang J, Yue L, Duan Y, Cui G (2014) Cellulose/Polysulfonamide composite separator as a high performance lithium-ion battery separator. ACS Sustain Chem Eng 2(2):194–199. https://doi.org/10.1021/sc400370hCrossRef

Xu G, Ding L, Wu T, Xiang M, Yang F (2019) Effect of PPR on the pore formation behavior and pore performances of β-iPP microporous membrane used for lithium-ion battery separator. J Polym Res 26:27. https://doi.org/10.1007/s10965-018-1689-xCrossRef

Yang B, Wang L, Zhang M, Li W, Zhou Q, Zhong L (2021) Advanced separators based on aramid nanofiber (ANF) membranes for lithium-ion batteries: a review of recent progress. J Mater Chem A 9(22):12923–12946. https://doi.org/10.1039/D1TA03125BCrossRef

Yao Y, Tao J, Zou J, Zhang B, Li T, Dai J, Zhu M, Wang S, Fu KK, Henderson D, Hitz E, Peng J, Hu L (2016) Light management in plastic-paper hybrid substrate towards high-performance optoelectronics. Energy Environ Sci 9(7):2278–2285. https://doi.org/10.1039/C6EE01011CCrossRef

Yousaf J, Almajali E, Najjar ME, Amir A, Altaf A, Elahi M, Alja’afreh S S, Rmili H, (2022) Flexible, fully printable, and inexpensive paper-based chipless arabic alphabet-based rfid tags. Sensors 22(2):564–586. https://doi.org/10.3390/s22020564CrossRefPubMedPubMedCentral

Yuan B, Wen K, Chen D, Liu Y, Dong Y, Feng C, Han Y, Han J, Zhang Y, Xia C, Sun A, He W (2021) Composite separators for robust high rate lithium ion batteries. Adv Funct Mater 31(32):2101420. https://doi.org/10.1002/adfm.202101420CrossRef

Zeng X, Liu Y, He R, Li T, Hu Y, Wang C, Xu J, Wang L, Wang H (2022) Tissue paper-based composite separator using nano-SiO2 hybrid crosslinked polymer electrolyte as coating layer for lithium ion battery with superior security and cycle stability. Cellulose 29:3985–4000. https://doi.org/10.1007/s10570-022-04499-5CrossRef

Zhang SS (2007) A review on the separators of liquid electrolyte Li-ion batteries. J Power Sources 164(1):351–364. https://doi.org/10.1016/j.jpowsour.2006.10.065CrossRef

Zhang Z, Zhou M, Yu J, Cai J, Yang Z (2021) Poly(vinylidene fluoride) modified commercial paper as a separator with enhanced thermal stability and electrolyte affinity for lithium-ion battery. Energy Environ Mater 4(4):664–670. https://doi.org/10.1002/eem2.12153CrossRef

Zheng C, Xiang L, Jin W, Shen H, Zhao W, Zhang F, Di C, Zhu D (2019) A flexible self-powered sensing element with integrated organic thermoelectric generator. Adv Mater Technol 4(8):1900247–1900254. https://doi.org/10.1002/admt.201900247CrossRef

Zhou ML, Zhang Z, Xu J, Wei J, Yu J, Yang ZY (2020) PDA modified commercial paper separator engineering with excellent lithiophilicity and mechanical strength for lithium metal batteries. J Electroanal Chem 868(1):114195. https://doi.org/10.1016/j.jelechem.2020.114195CrossRef

Titel: Cellulose-ceramic composite flexible paper separator with improved wettability and flame retardant properties for lithium-ion batteries
verfasst von: Mononita Das
Pradip Sekhar Das
Rajendra Nath Basu
Mir Wasim Raja
Publikationsdatum: 14.10.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 18/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04873-3

Springer Professional

Abstract

Graphical abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 18/2022

Nanoparticle release from anionic nanocellulose hydrogel matrix

Graphene oxide modified with carboxymethyl cellulose for high adsorption capacities towards Nd(III) and Ce(III) from aqueous solutions

Cellulose nanocrystal-based enhancement of ultrasound microbubbles for increased tolerance of mechanical index values

Effect of cellulose nanocrystals on rheology, liquid crystal, and delivery behavior of metronidazole poloxamer-based in-situ dental medication

Preparation of efficient heavy metal adsorbent based on walnut shell and adsorption for Pb(II) ions from aqueous solution

Mild, rapid and efficient etherification of cellulose