nach oben

Polymer Bulletin

Erschienen in:

15.03.2018 | Original Paper

Characterization and swelling–deswelling properties of porous superabsorbent hydrogel membranes made of PVA and Ziziphus spina-christi fibers reinforced with nanosilica manufactured by compression moulding process

verfasst von: E. M. Abdel Bary, Ahmed Fekri, Yaser A. Soliman, Ammar N. Harmal

Erschienen in: Polymer Bulletin | Ausgabe 11/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Novel superabsorbent membranes consisting of polyvinyl alcohol (PVA), cellulose nanocrystals originated from Ziziphus spina-christi fibers, nanosilica, glutaraldehyde, and glycerin (G) were manufactured by compression moulding process. Ziziphus spina-christi fibers are a new source to isolate pure cellulose nanocrystals via mechanical and chemical treatment. Ziziphus spina-christi fibers were used to improve water-saving irrigation systems. Glycerin was used to increase the elasticity of superabsorbent membranes. These membranes were characterized by FTIR, XRD, SEM, mechanical testing, and thermal analysis. Superabsorbent membranes showed greater equilibrium swelling capacity compared with neat cross-linked PVA. Moreover, water transport mechanism of all superabsorbent membranes followed Fickian diffusion type. Superabsorbent membranes exhibited good pH-dependent swelling reversibility and high-water retention capacity, making it more efficient water-saving material. The superabsorbent membranes were also investigated for antimicrobial activities against pathogenic bacteria like Candida albicans (fungus), Bacillus subtilis (G+ve), Staphylococcus aureus (G+ve), Proteus vulgaris (G−ve), and Erwinia carotovora (G−ve). The results showed that design of innovative bioactive superabsorbent membranes is promising for the water reservoir, which might be most profitable in agricultural applications.

Vorheriger Artikel High flame retardancy of amorphous sodium silicate on poly(ethylene-co-vinyl acetate) (EVA)

Nächster Artikel Interfacial interactions in PTT–PTMO/polyhedral oligomeric silsesquioxane (POSS) nanocomposites and their impact on mechanical, thermal, and dielectric properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Abdel Bary EA, Fekri A, Soliman Y, Harmal AN (2017) Novel superabsorbent membranes made of PVA and Ziziphus spina-christi cellulose for agricultural and horticultural applications. New J Chem 41:9688–9700. https://doi.org/10.1039/C7NJ01676J CrossRef

Montesano FF, Parente A, Santamaria P et al (2015) Biodegradable superabsorbent hydrogel increases water retention properties of growing media and plant growth. Agric Agric Sci Procedia 4:451–458. https://doi.org/10.1016/j.aaspro.2015.03.052 CrossRef

Kabiri K, Omidian H, Zohuriaan-Mehr MJ, Doroudiani S (2008) Superabsorbent hydrogel composites and nanocomposites: a review. Polym Compos 16:101–113. https://doi.org/10.1002/pc.21046 CrossRef

Puoci F, Iemma F, Spizzirri UG et al (2008) Polymer in agriculture: a review. Am J Agric Biol Sci 3:299–314. https://doi.org/10.3844/ajabssp.2008.299.314 CrossRef

Kasgoz H, Durmus A (2006) Nanostructured polyolefins/clay composites: role of the molecular interaction at the interface. Polym Adv Technol 17:395–418. https://doi.org/10.1002/pat CrossRef

Kosemund K, Schlatter H, Ochsenhirt JL et al (2009) Safety evaluation of superabsorbent baby diapers. Regul Toxicol Pharmacol 53:81–89. https://doi.org/10.1016/j.yrtph.2008.10.005 CrossRefPubMed

Kostarelos K, Prato M, Vázquez E et al (2015) Nanocomposite hydrogels: 3D polymer-nanoparticle synergies for on-demand drug delivery. ACS Nano 9:4686–4697CrossRefPubMed

Pina S, Oliveira JM, Reis RL (2015) Natural-based nanocomposites for bone tissue engineering and regenerative medicine: a review. Adv Mater 27:1143–1169. https://doi.org/10.1002/adma.201403354 CrossRefPubMed

Kiatkamjornwong S (2007) Superabsorbent polymers and superabsorbent polymer composites. ScienceAsia 33(s1):39. https://doi.org/10.2306/scienceasia1513-1874.2007.33(s1).039 CrossRef

10.

Rodrigues FHA, Fajardo AR (2012) Chitosan-graft-poly (acrylic acid)/rice husk ash based superabsorbent hydrogel composite: preparation and characterization. J Polym Res. https://doi.org/10.1007/s10965-012-0001-8 CrossRef

11.

Abdel Bary EM, Fekri A, Soliman Y, Harmal AN (2016) Biodegradable polymer nanocomposites based on polyvinyl alcohol and nano-rice straw. Indian J Appl Res 6:713–721. https://doi.org/10.15373/2249555X CrossRef

12.

Hassan CM, Peppas NA (2000) Structure and applications of poly (vinyl alcohol) hydrogels produced by conventional crosslinking or by freezing/thawing methods. Adv Polym Sci 153:37–65. https://doi.org/10.1007/3-540-46414-X_2 CrossRef

13.

Oliveira RN, Rouzé R, Quilty B et al (2014) Mechanical properties and in vitro characterization of polyvinyl alcohol-nano-silver hydrogel wound dressings. Interface Focus 4:20130049. https://doi.org/10.1098/rsfs.2013.0049 CrossRefPubMedPubMedCentral

14.

Hassan CM, Ward JH, Peppas NA (2000) Modeling of crystal dissolution of poly(vinyl alcohol) gels produced by freezing/thawing processes. Polymer (Guildf) 41:6729–6739. https://doi.org/10.1016/S0032-3861(00)00031-8 CrossRef

15.

Nghiep TD, Minh DTN, Cong NT (2010) Formation and characterization of a hydrophilic polymer hydrogel under gamma irradiation. J Radioanal Nucl Chem 285:719–721. https://doi.org/10.1007/s10967-010-0618-1 CrossRef

16.

Hosseinzadeh H, Sadeghi M (2012) Preparation and swelling behaviour of carboxymethylcellulose-g-poly (sodium acrylate)/kaolin super absorbent hydrogel composites. Asian J Chem 24:85–88

17.

Bal A, Çepni FE, Çakir Ö et al (2015) Synthesis and characterization of copolymeric and terpolymeric hydrogel-silver nanocomposites based on acrylic acid, acrylamide and itaconic acid: investigation of their antibacterial activity against Gram-negative bacteria. Braz J Chem Eng 32:509–518CrossRef

18.

Zhang W, Yang X, Li C et al (2011) Mechanochemical activation of cellulose and its thermoplastic polyvinyl alcohol ecocomposites with enhanced physicochemical properties. Carbohydr Polym 83:257–263. https://doi.org/10.1016/j.carbpol.2010.07.062 CrossRef

19.

Panaitescu DM, Frone AN, Ghiurea M et al (2010) Properties of polymer composites with cellulose microfibrils. Adv Compos Mater Ecodesign Anal 484:103–122

20.

Bana R, Banthia AK (2011) Mechanical and thermal analysis of poly (vinyl-alcohol) and modified wood dust composites. J Wood Chem Technol 31:218–232. https://doi.org/10.1080/02773813.2010.523160 CrossRef

21.

Qiu K, Netravali AN (2012) Fabrication and characterization of biodegradable composites based on microfibrillated cellulose and polyvinyl alcohol. Compos Sci Technol 72:1588–1594. https://doi.org/10.1016/j.compscitech.2012.06.010 CrossRef

22.

Metwally MA, Gouda MA, Harmal AN, Khalil AM (2012) Synthesis, antitumor, cytotoxic and antioxidant evaluation of some new pyrazolotriazines attached to antipyrine moiety. Eur J Med Chem 56:254–262. https://doi.org/10.1016/j.ejmech.2012.08.034 CrossRefPubMed

23.

Metwally MA, Gouda MA, Harmal AN, Khalil AM (2012) 3-Iminobutanenitrile as building block for the synthesis of substituted pyrazolo[1,5-a]pyrimidines with antitumor and antioxidant activities. Int J Mod Org Chem Int J Mod Org Chem J 1:96–114

24.

Metwally MA, Soliman YA, Gouda MA, Harmal AN, Khalil AM (2012) Synthesis, antitumor and antioxidant evaluation of some new antipyrine based azo dyes incorporating pyrazolone moiety. Int J Mod Org Chem J 1:213–225. https://doi.org/10.1016/j.ejmech.2012.08.034 CrossRef

25.

Jiang F, Hsieh Y (2015) Cellulose nanocrystal isolation from tomato peels and assembled nanofibers. Carbohydr Polym 122:60–68. https://doi.org/10.1016/j.carbpol.2014.12.064 CrossRefPubMed

26.

Qin L, Qiu J, Liu M et al (2011) Mechanical and thermal properties of poly (lactic acid) composites with rice straw fiber modified by poly (butyl acrylate). Chem Eng J 166:772–778. https://doi.org/10.1016/j.cej.2010.11.039 CrossRef

27.

Feit B, Bar-nun A, Lahav M (1964) Anionic graft polymerization of vinyl monomers cellulose and polyvinyl alcohol. J Appl Polymeh Sci 8:1869–1888. https://doi.org/10.1002/app.1964.070080434 CrossRef

28.

Yazdimamaghani M, Pourvala T, Motamedi E et al (2013) Synthesis and characterization of encapsulated nanosilica particles with an acrylic copolymer by in situ emulsion polymerization using thermoresponsive nonionic surfactant. Materials (Basel) 6:3727–3741. https://doi.org/10.3390/ma6093727 CrossRef

29.

Chopra P, Garg S, Jana AK (2013) Study on the Performance of starch/PVA blend films modified with SiO 2 nanoparticles. Int J Res Mech Eng Technol 5762:36–40

30.

Abdel Bary EM, Fekri A, Soliman YA, Harmal AN (2018) Chemical and biology aging of novel green membranes made of PVA and wood flour fibers reinforced with nanosilica manufactured by compression molding process. Int J Polym Anal Char 23:159–169. https://doi.org/10.1080/1023666X.2017.1404271 CrossRef

31.

Priya B, Kumar V, Pathania D, Singh A (2014) Synthesis, characterization and antibacterial activity of biodegradable starch/PVA composite films reinforced with cellulosic fibre. Carbohydr Polym 109:171–179. https://doi.org/10.1016/j.carbpol.2014.03.044 CrossRefPubMed

32.

Bana R, Banthia AK (2007) Green composites: development of poly(vinyl alcohol)-wood dust composites. Polym Plast Technol Eng 46:821–829. https://doi.org/10.1080/03602550701278079 CrossRef

33.

Qiao J, Hamaya T, Okada T (2005) New highly proton conductive polymer membranes poly(vinyl alcohol)–2-acrylamido-2-methyl-1-propanesulfonic acid (PVA–PAMPS). J Mater Chem 15:4414. https://doi.org/10.1039/b507924a CrossRef

34.

Mansur Herman S, Mansur AAP (2005) Small angle X-Ray scattering, FTIR and SEM characterization of nanostructured PVA/TEOS hybrids by chemical crosslinking. Mater Res Soc 871:1–6. https://doi.org/10.1557/PROC-873-K1.9 CrossRef

35.

Tang H, Xiong H, Tang S, Zou P (2009) A starch-based biodegradable film modified by nano silicon dioxide. J Appl Polym Sci 113:34–40. https://doi.org/10.1002/app.29855 CrossRef

36.

Ma K, Voort FR, Sedman J, Ismail AA (1997) Stoichiometric determination of hydroperoxides in fats and oils by fourier transform infrared spectroscopy. J Am Oil Chem Soc 74:897–906. https://doi.org/10.1007/s11746-997-0001-8 CrossRef

37.

Jia X, Li Y, Cheng Q et al (2007) Preparation and properties of poly(vinyl alcohol)/silica nanocomposites derived from copolymerization of vinyl silica nanoparticles and vinyl acetate. Eur Polym J 43:1123–1131. https://doi.org/10.1016/j.eurpolymj.2007.01.019 CrossRef

38.

Sriupayo J, Supaphol P, Blackwell J, Rujiravanit R (2005) Preparation and characterization of a-chitin whisker-reinforced poly(vinyl alcohol) nanocomposite films with or without heat treatment. Polymer (Guildf) 46:5637–5644. https://doi.org/10.1016/j.polymer.2005.04.069 CrossRef

39.

Shao C, Kim HY, Gong J et al (2003) Fiber mats of poly(vinyl alcohol)/silica composite via electrospinning. Mater Lett 57:1579–1584. https://doi.org/10.1016/S0167-577X(02)01036-4 CrossRef

40.

Mandal A, Chakrabarty D (2014) Studies on the mechanical, thermal, morphological and barrier properties of nanocomposites based on poly(vinyl alcohol) and nanocellulose from sugarcane bagasse. J Ind Eng Chem 20:462–473. https://doi.org/10.1016/j.jiec.2013.05.003 CrossRef

41.

Hassan AF, Abdelghny AM, Elhadidy H, Youssef AM (2014) Synthesis and characterization of high surface area nanosilica from rice husk ash by surfactant-free sol–gel method. J Sol Gel Sci Technol 69:465–472. https://doi.org/10.1007/s10971-013-3245-9 CrossRef

42.

Li GC, Chen J, Li Q, Yang T (2011) Biodegradable composites from pinewood sawdust and polyvinyl alcohol adhesives. Adv Mater Res 281:59–63. https://doi.org/10.4028/www.scientific.net/AMR.281.59 CrossRef

43.

Cândido JDS, Pereira AGB, Fajardo AR et al (2013) Poly(acrylamide-co-acrylate)/rice husk ash hydrogel composites. II. Temperature effect on rice husk ash obtention. Compos Part B Eng 51:246–253. https://doi.org/10.1016/j.compositesb.2013.03.027 CrossRef

44.

Awasthi S, Singhal R (2013) A study on interaction and solubility of acetaminophen with poly(AM-co-HEA-co-AA) hydrogels by DSC: effect on drug diffusion behavior. J Macromol Sci Part A 50:72–89. https://doi.org/10.1080/10601325.2012.736266 CrossRef

45.

Kasgoz H, Durmus A (2008) Dye removal by a novel hydrogel-clay nanocomposite with enhanced swelling properties. Polym Adv Technol 19:838–845. https://doi.org/10.1002/pat CrossRef

46.

Gharekhani H, Olad A, Mirmohseni A, Bybordi A (2017) Superabsorbent hydrogel made of NaAlg-g-poly(AA-co-AAm) and rice husk ash: synthesis, characterization, and swelling kinetic studies. Carbohydr Polym 168:1–13. https://doi.org/10.1016/j.carbpol.2017.03.047 CrossRefPubMed

47.

Spagnol C, Rodrigues FHA, Pereira AGB et al (2012) Superabsorbent hydrogel composite made of cellulose nanofibrils and chitosan-graft-poly(acrylic acid). Carbohydr Polym 87:2038–2045. https://doi.org/10.1016/j.carbpol.2011.10.017 CrossRef

48.

Rowbotham JS, Dyer PW, Greenwell HC et al (2013) Copper (II) -mediated thermolysis of alginates: a model kinetic study on the influence of metal ions in the thermochemical processing of macroalgae. Interface Focus 3:1–16

49.

Shi XN, Wang WB, Wang AQ (2011) Synthesis, characterization and swelling behaviors of guar gum-g-poly(sodium acrylate-co-styrene)/vermiculite superabsorbent composites. J Compos Mater 45:2189–2198. https://doi.org/10.1177/0021998311401071 CrossRef

50.

Hu D, Wang L (2016) Physical and antibacterial properties of polyvinyl alcohol films reinforced with quaternized cellulose. J Appl Polym Sci 133:1–8. https://doi.org/10.1002/app.43552 CrossRef

Titel: Characterization and swelling–deswelling properties of porous superabsorbent hydrogel membranes made of PVA and Ziziphus spina-christi fibers reinforced with nanosilica manufactured by compression moulding process
verfasst von: E. M. Abdel Bary
Ahmed Fekri
Yaser A. Soliman
Ammar N. Harmal
Publikationsdatum: 15.03.2018
Verlag: Springer Berlin Heidelberg
Erschienen in: Polymer Bulletin / Ausgabe 11/2018
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-018-2315-0

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2018

Environmental functional photo-cross-linked hydrogel bilayer thin films from vanillin (part 2): temperature-responsive layer A, functional, temperature and pH layer B

Preparation, characterization, and bioactivity of the polyester and tea waste green composites

Preparation of novel marine antifouling polyurethane coating materials

Understanding the effect of functionalized carbon nanotubes on the properties of tamarind gum hydrogels

In situ preparation of thermoset/clay nanocomposites via thiol-epoxy click chemistry

High flame retardancy of amorphous sodium silicate on poly(ethylene-co-vinyl acetate) (EVA)

Premium Partner

Marktübersichten