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Erschienen in: Colloid and Polymer Science 14-15/2010

01.10.2010 | Original Contribution

Chemical hybridization of imidized waterborne polyurethane with silica particle

verfasst von: Dong H. Jung, Min A. Jeong, Han M. Jeong, Byung K. Kim

Erschienen in: Colloid and Polymer Science | Ausgabe 14-15/2010

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Abstract

Chemical hybrids of imidized waterborne polyurethane (WPU) with silica nanoparticle were synthesized by UV cure. Imide groups were introduced into the hard segment of UV curable WPU by extending the NCO-terminated prepolymers with pyromellitic dianhydride where chemical hybridization by UV cure was made between the acrylate-terminated polyurethane prepolymer and vinyltrimethoxysilane-silica oligomer. It was found that imidization of WPU and imidized WPU-silica hybrids showed remarkably high mechanical and dynamic mechanical properties at room and elevated temperatures as well as thermal stability.

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Literatur
1.
Zurück zum Zitat Madbouly SA, Otaigbe JU (2009) Recent advances in synthesis, characterization and rheological properties of polyurethanes and POSS/polyurethane nanocomposites dispersions and films. Prog Polym Sci 34:1283–1332CrossRef Madbouly SA, Otaigbe JU (2009) Recent advances in synthesis, characterization and rheological properties of polyurethanes and POSS/polyurethane nanocomposites dispersions and films. Prog Polym Sci 34:1283–1332CrossRef
2.
Zurück zum Zitat Dong AJ, Sun DX (2003) Properties of amphoteric polyurethane waterborne dispersions: II. Macromolecular self-assembly behavior. J Colloid Interface Sci 266:276–281CrossRef Dong AJ, Sun DX (2003) Properties of amphoteric polyurethane waterborne dispersions: II. Macromolecular self-assembly behavior. J Colloid Interface Sci 266:276–281CrossRef
3.
Zurück zum Zitat Yang CH, Liu FJ (2006) Hybrids of colloidal silica and waterborne polyurethane. J Colloid Interface Sci 302:123–132CrossRef Yang CH, Liu FJ (2006) Hybrids of colloidal silica and waterborne polyurethane. J Colloid Interface Sci 302:123–132CrossRef
4.
Zurück zum Zitat Asif A, Hu LH, Shi WF (2009) Synthesis, rheological, and thermal properties of waterborne hyperbranched polyurethane acrylate dispersions for UV curable coatings. Colloid Polym Sci 287:1041–1049CrossRef Asif A, Hu LH, Shi WF (2009) Synthesis, rheological, and thermal properties of waterborne hyperbranched polyurethane acrylate dispersions for UV curable coatings. Colloid Polym Sci 287:1041–1049CrossRef
5.
Zurück zum Zitat Noh SH, Choi HS, Noh ST (2000) Synthesis and application of water-based urethane acrylate crosslinking agent containing unsaturated group. J Appl Polym Sci 78:1216–1223CrossRef Noh SH, Choi HS, Noh ST (2000) Synthesis and application of water-based urethane acrylate crosslinking agent containing unsaturated group. J Appl Polym Sci 78:1216–1223CrossRef
6.
Zurück zum Zitat Schwalm R, Häußling L, Reich W, Beak E, Enenkel P, Mensel K (1997) Tuning the mechanical properties of UV coatings towards hard and flexible systems. Prog Org Coat 32:191–196CrossRef Schwalm R, Häußling L, Reich W, Beak E, Enenkel P, Mensel K (1997) Tuning the mechanical properties of UV coatings towards hard and flexible systems. Prog Org Coat 32:191–196CrossRef
7.
Zurück zum Zitat Kim BK, Shin JH (2002) Modification of waterborne polyurethane by forming latex interpenetrating polymer networks with acrylate rubber. Colloid Polym Sci 280:716–724CrossRef Kim BK, Shin JH (2002) Modification of waterborne polyurethane by forming latex interpenetrating polymer networks with acrylate rubber. Colloid Polym Sci 280:716–724CrossRef
8.
Zurück zum Zitat Petrović ZS, Savargo Z, Flynn JH, Macknight WJ (1994) Thermal degradation of segmented polyurethanes. J Appl Polym Sci 51:1087–1095CrossRef Petrović ZS, Savargo Z, Flynn JH, Macknight WJ (1994) Thermal degradation of segmented polyurethanes. J Appl Polym Sci 51:1087–1095CrossRef
9.
Zurück zum Zitat Lin MF, Shu YC, Tsen WC, Chuang FS (1999) Synthesis of polyurethane-imide (PU-imide) copolymers with different dianhydrides and their properties. Polym Int 48:433–445CrossRef Lin MF, Shu YC, Tsen WC, Chuang FS (1999) Synthesis of polyurethane-imide (PU-imide) copolymers with different dianhydrides and their properties. Polym Int 48:433–445CrossRef
10.
Zurück zum Zitat Liu J, Ma D (2002) Study on synthesis and thermal properties of polyurethane-imide copolymers with multiple hard segments. J Appl Polym Sci 84:2206–2215CrossRef Liu J, Ma D (2002) Study on synthesis and thermal properties of polyurethane-imide copolymers with multiple hard segments. J Appl Polym Sci 84:2206–2215CrossRef
11.
Zurück zum Zitat Qin X, Yang X, Wang X, Wang M (2005) Synthesis and characterization of poly(imide-urethane) based on novel chain-extender containing both imide and sulphone functions. J Polym Sci Part A: Polym Chem 43:4469–4477CrossRef Qin X, Yang X, Wang X, Wang M (2005) Synthesis and characterization of poly(imide-urethane) based on novel chain-extender containing both imide and sulphone functions. J Polym Sci Part A: Polym Chem 43:4469–4477CrossRef
12.
Zurück zum Zitat Lee MH, Choi HY, Jeong KY, Lee JW, Huang TW, Kim BK (2007) High performance UV cured polyurethane dispersion. Polym Degrad Stab 92:1677–1681CrossRef Lee MH, Choi HY, Jeong KY, Lee JW, Huang TW, Kim BK (2007) High performance UV cured polyurethane dispersion. Polym Degrad Stab 92:1677–1681CrossRef
13.
Zurück zum Zitat Jang MK, Hartwig A, Kim BK (2009) Shape memory polyurethanes cross-linked by surface modified silica particles. J Mater Chem 19:1166–1172CrossRef Jang MK, Hartwig A, Kim BK (2009) Shape memory polyurethanes cross-linked by surface modified silica particles. J Mater Chem 19:1166–1172CrossRef
14.
Zurück zum Zitat Chen B, Evans JRG (2006) Poly(ε-caprolactone) − Clay nanocomposites: structure and mechanical properties. Macromolecules 39:747–754CrossRef Chen B, Evans JRG (2006) Poly(ε-caprolactone) − Clay nanocomposites: structure and mechanical properties. Macromolecules 39:747–754CrossRef
15.
Zurück zum Zitat Zhang H, Zhang Z, Friedrich K, Eger C (2006) Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content. Acta Mater 54:1833–1842CrossRef Zhang H, Zhang Z, Friedrich K, Eger C (2006) Property improvements of in situ epoxy nanocomposites with reduced interparticle distance at high nanosilica content. Acta Mater 54:1833–1842CrossRef
16.
Zurück zum Zitat Cho JW, Lee SH (2004) Influence of silica on shape memory effect and mechanical properties of polyurethane–silica hybrids. Eur Polym J 40:1343–1348CrossRef Cho JW, Lee SH (2004) Influence of silica on shape memory effect and mechanical properties of polyurethane–silica hybrids. Eur Polym J 40:1343–1348CrossRef
17.
Zurück zum Zitat Gall K, Dunn ML, Liu Y, Stefanic G, Balzar D (2004) Internal stress storage in shape memory polymer nanocomposites. Appl Phys Lett 85:290–292CrossRef Gall K, Dunn ML, Liu Y, Stefanic G, Balzar D (2004) Internal stress storage in shape memory polymer nanocomposites. Appl Phys Lett 85:290–292CrossRef
18.
Zurück zum Zitat Iyer NP, Gnanarajan TP, Radhakrishnan G (2001) Catalysis of poly(urethane imidine) copolymer formation from amine-blocked isocyanate and bisphthalide. J Polym Sci Part A: Polym Chem 39:4236–4242CrossRef Iyer NP, Gnanarajan TP, Radhakrishnan G (2001) Catalysis of poly(urethane imidine) copolymer formation from amine-blocked isocyanate and bisphthalide. J Polym Sci Part A: Polym Chem 39:4236–4242CrossRef
19.
Zurück zum Zitat Lee SK, Kim BK (2009) High solid and high stability waterborne polyurethanes via ionic groups in soft segments and chain termini. J Colloid Interface Sci 336:208–214CrossRef Lee SK, Kim BK (2009) High solid and high stability waterborne polyurethanes via ionic groups in soft segments and chain termini. J Colloid Interface Sci 336:208–214CrossRef
20.
Zurück zum Zitat Gnanarajan TP, Iyer NP, Nasar AS, Radhakrishnan G (2002) Preparation and properties of poly(urethane-imide)s derived from amine-blocked-polyurethane prepolymer and pyromellitic dianhydride. Eur Polym J 38:487–495CrossRef Gnanarajan TP, Iyer NP, Nasar AS, Radhakrishnan G (2002) Preparation and properties of poly(urethane-imide)s derived from amine-blocked-polyurethane prepolymer and pyromellitic dianhydride. Eur Polym J 38:487–495CrossRef
21.
Zurück zum Zitat Zuo M, Takeichi T (1999) Preparation and characterization of poly(urethane–imide) films prepared from reactive polyimide and polyurethane prepolymer. Polymer 40:5153–5160CrossRef Zuo M, Takeichi T (1999) Preparation and characterization of poly(urethane–imide) films prepared from reactive polyimide and polyurethane prepolymer. Polymer 40:5153–5160CrossRef
22.
Zurück zum Zitat Yeganeh H, Shamekhi MA (2004) Poly(urethane-imide-imide), a new generation of thermoplastic polyurethane elastomers with enhanced thermal stability. Polymer 45:359–365CrossRef Yeganeh H, Shamekhi MA (2004) Poly(urethane-imide-imide), a new generation of thermoplastic polyurethane elastomers with enhanced thermal stability. Polymer 45:359–365CrossRef
Metadaten
Titel
Chemical hybridization of imidized waterborne polyurethane with silica particle
verfasst von
Dong H. Jung
Min A. Jeong
Han M. Jeong
Byung K. Kim
Publikationsdatum
01.10.2010
Verlag
Springer-Verlag
Erschienen in
Colloid and Polymer Science / Ausgabe 14-15/2010
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-010-2279-6

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