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2017 | OriginalPaper | Buchkapitel

3. Chemical Ideas of QED

verfasst von : Akitomo Tachibana

Erschienen in: New Aspects of Quantum Electrodynamics

Verlag: Springer Singapore

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Abstract

In Chap. 1, we have studied the symmetry-polarized internal self-stress tensor of electron. In Chap. 2, we have studied the antisymmetric component of the stress tensor of electron in detail. It remains a simple question: for what does the symmetric component work? The answer is first chemical idea of QED is the spindle structure of covalency predicted by the symmetric component of the stress tensor of electron. We have so long considered relativistic theory as merely a slight correction for the interpretation in chemical phenomena. However, we shall clarify that the Hamiltonian of QED, derived from the picture of “action through medium” based on the relativistic theory, gives a novel image of the chemical interaction even in the nonrelativistic limit. Actually, we shall use the primary Rigged QED theory for our purpose. As a result, conventional images of the chemical interaction based on “action at a distance” are replaced with the new images of them given by the picture of “action through medium” without exception. We shall visualize not only the spindle structure but also various basic chemical concepts in chemical reaction systems in real three-dimensional space. Shape volume discriminates the region of classical atoms and molecules. The regional chemical potential inequality principle gives the electron transferability from one region to another.

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Literatur
Zurück zum Zitat W.A. Bingel, Z. Naturforsch. 18a, 1249 (1963) W.A. Bingel, Z. Naturforsch. 18a, 1249 (1963)
Zurück zum Zitat W.A. Bingel, Theoret. Chim. Acta (Berl.) 8, 54 (1967) W.A. Bingel, Theoret. Chim. Acta (Berl.) 8, 54 (1967)
Zurück zum Zitat C.A. Coulson, Valence (2nd edn., Clarendon, Oxford, 1961) C.A. Coulson, Valence (2nd edn., Clarendon, Oxford, 1961)
Zurück zum Zitat I. Fleming, Frontier Orbitals and Organic Chemical Reactions (Wiley, New York, 1976) I. Fleming, Frontier Orbitals and Organic Chemical Reactions (Wiley, New York, 1976)
Zurück zum Zitat D.J. Henry, P. Szarek, K. Hirai, K. Ichikawa, A. Tachibana, I. Yarovsky, J. Phys. Chem. C 115, 1714 (2011)CrossRef D.J. Henry, P. Szarek, K. Hirai, K. Ichikawa, A. Tachibana, I. Yarovsky, J. Phys. Chem. C 115, 1714 (2011)CrossRef
Zurück zum Zitat K. Ichikawa, A. Wagatsuma, Y. Kurokawa, S. Sakaki, A. Tachibana, Theor. Chem. Accounts 130, 237 (2011)CrossRef K. Ichikawa, A. Wagatsuma, Y. Kurokawa, S. Sakaki, A. Tachibana, Theor. Chem. Accounts 130, 237 (2011)CrossRef
Zurück zum Zitat K. Ichikawa, H. Nozaki, N. Komazawa, A. Tachibana, AIP Advances 2, 042195 (16) (2012) K. Ichikawa, H. Nozaki, N. Komazawa, A. Tachibana, AIP Advances 2, 042195 (16) (2012)
Zurück zum Zitat K. Ichikawa, H. Nozaki, A. Tachibana, Mater. Sci. Forum. 783–786, 2207 (2014)CrossRef K. Ichikawa, H. Nozaki, A. Tachibana, Mater. Sci. Forum. 783–786, 2207 (2014)CrossRef
Zurück zum Zitat L.D. Landau, E.M. Lifshitz, Statistical Physics (Pergamon, Oxford, 1980), pp. 264–265 L.D. Landau, E.M. Lifshitz, Statistical Physics (Pergamon, Oxford, 1980), pp. 264–265
Zurück zum Zitat K. Nakamura, K. Doi, K. Fujitani, A. Tachibana, Phys. Rev. B 71, 045332(8) (2005) K. Nakamura, K. Doi, K. Fujitani, A. Tachibana, Phys. Rev. B 71, 045332(8) (2005)
Zurück zum Zitat H. Nozaki, Y. Ikeda, K. Ichikawa, A. Tachibana, J. Comput. Chem. 36, 1240 (2015)CrossRef H. Nozaki, Y. Ikeda, K. Ichikawa, A. Tachibana, J. Comput. Chem. 36, 1240 (2015)CrossRef
Zurück zum Zitat H. Nozaki, K. Ichikawa, A. Tachibana, Int. J. Quant. Chem. 116, 504 (2016)CrossRef H. Nozaki, K. Ichikawa, A. Tachibana, Int. J. Quant. Chem. 116, 504 (2016)CrossRef
Zurück zum Zitat L. Pauling, The Nature of the Chemical Bond, 3rd edn. (Cornell University, New York, 1960) L. Pauling, The Nature of the Chemical Bond, 3rd edn. (Cornell University, New York, 1960)
Zurück zum Zitat L. Pauling, E.B. Wilson Jr., Introduction to Quantum Mechanics with Application to Chemistry (McGraw-Hill, New York, 1935) L. Pauling, E.B. Wilson Jr., Introduction to Quantum Mechanics with Application to Chemistry (McGraw-Hill, New York, 1935)
Zurück zum Zitat J.B. Perrin, Les Atomes (Liberairie Felix Alcan, 1914) J.B. Perrin, Les Atomes (Liberairie Felix Alcan, 1914)
Zurück zum Zitat L.E. Reichl, A Modern Course in Statistical Physics (University of Texas, Austin, 1980), pp. 45–47 L.E. Reichl, A Modern Course in Statistical Physics (University of Texas, Austin, 1980), pp. 45–47
Zurück zum Zitat M. Senami, Y. Ikeda, A. Fukushima, A. Tachibana, AIP Adv. 1, 042106(12) (2011)CrossRef M. Senami, Y. Ikeda, A. Fukushima, A. Tachibana, AIP Adv. 1, 042106(12) (2011)CrossRef
Zurück zum Zitat P. Szarek, Y. Sueda, A. Tachibana, J. Chem. Phys. 129, 094102(16) (2008)CrossRef P. Szarek, Y. Sueda, A. Tachibana, J. Chem. Phys. 129, 094102(16) (2008)CrossRef
Zurück zum Zitat P. Szarek, K. Urakami, C. Zhouz, H. Cheng, A. Tachibana, J. Chem. Phys. 130, 084111(9) (2009)CrossRef P. Szarek, K. Urakami, C. Zhouz, H. Cheng, A. Tachibana, J. Chem. Phys. 130, 084111(9) (2009)CrossRef
Zurück zum Zitat A. Tachibana, in Conceptual Trends in Quantum Chemistry, ed by E. S. Kryachko, J. L. Calais. (Kluwer, Dordrecht, 1994), pp. 101–118CrossRef A. Tachibana, in Conceptual Trends in Quantum Chemistry, ed by E. S. Kryachko, J. L. Calais. (Kluwer, Dordrecht, 1994), pp. 101–118CrossRef
Zurück zum Zitat A. Tachibana, in The Transition State – A Theoretical Approach, ed by T. Fueno. (Kodansha/Gordon and Breach, Tokyo/Amsterdam, 1999b), pp. 217–247 A. Tachibana, in The Transition State – A Theoretical Approach, ed by T. Fueno. (Kodansha/Gordon and Breach, Tokyo/Amsterdam, 1999b), pp. 217–247
Zurück zum Zitat A. Tachibana, in Reviews in Modern Quantum Chemistry:A Celebration of the Contributions of Robert Parr, ed by K. D. Sen. (World Scientific, Singapore, 2002) Chap.45, pp. 1327–1366 A. Tachibana, in Reviews in Modern Quantum Chemistry:A Celebration of the Contributions of Robert Parr, ed by K. D. Sen. (World Scientific, Singapore, 2002) Chap.45, pp. 1327–1366
Zurück zum Zitat A. Tachibana, in Fundamental Perspectives in Quantum Chemistry: A Tribute to the Memory of Per-Olov Löwdin, vol. 2, ed. by E. Brändas, E. Kryachko (Kluwer, Dordrecht, 2003), pp. 211–239 A. Tachibana, in Fundamental Perspectives in Quantum Chemistry: A Tribute to the Memory of Per-Olov Löwdin, vol. 2, ed. by E. Brändas, E. Kryachko (Kluwer, Dordrecht, 2003), pp. 211–239
Zurück zum Zitat A. Tachibana, in Concepts and Methods in Modern Theoretical Chemistry: Electronic Structure and Reactivity (Atoms, Molecules, and Clusters), ed by S. K. Ghosh, P. K. Chattaraj. (Taylor & Francis/CRC, New York, 2013) , Chap.12, pp. 235–251 A. Tachibana, in Concepts and Methods in Modern Theoretical Chemistry: Electronic Structure and Reactivity (Atoms, Molecules, and Clusters), ed by S. K. Ghosh, P. K. Chattaraj. (Taylor & Francis/CRC, New York, 2013) , Chap.12, pp. 235–251
Metadaten
Titel
Chemical Ideas of QED
verfasst von
Akitomo Tachibana
Copyright-Jahr
2017
Verlag
Springer Singapore
DOI
https://doi.org/10.1007/978-981-10-3132-8_3