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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 3/2013

01.05.2013

Comparison of electrolyte effects for poly(3,4-ethylenedioxythiophene) and poly(3-octylthiophene) by electrochemical impedance spectroscopy and polymerization parameters with morphological analyses on coated films

verfasst von: Murat Ates, Tolga Karazehir, Fatih Arican, Nuri Eren

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 3/2013

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Abstract

3,4-Ethylenedioxythiophene and 3-octylthiophene were electropolymerized on glassy carbon electrodes (GCE) to compare with four different electrolytes [lithium perchlorate (LiClO4), sodium perchlorate, tetraethylammonium tetrafluoroborate, and tetrabutylammonium tetrafluoroborate] in a solvent of acetonitrile (CH3CN). Modified electrodes were characterized by cyclic voltammetry, attenuated total reflectance–Fourier transform IR spectroscopy, scanning electron microscopy, energy dispersive X-ray analysis, atomic force microscopy, and electrochemical impedance spectroscopy (EIS). Nyquist and Bode plots for magnitude, phase, admittance, and capacitance on both polymer-modified electrodes were comparatively investigated in detail. The highest low-frequency capacitance (C LF) and double-layer capacitance (C dl) were obtained in 0.1 M LiClO4/CH3CN for poly(3,4-ethylenedioxythiophene) and poly(octylthiophene)/GCE. EIS data were fitted to the equivalent circuit model of R(Q(R(C(R(C(RW))))))(CR), which is used to investigate circuit parameters.
Vorheriger Artikel Rheological studies of two component high build epoxy and polyurethane based high performance coatings
Nächster Artikel High performance moisture cured poly(ether–urethane) amide coatings based on renewable resource (cottonseed oil)

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Metadaten
Titel
Comparison of electrolyte effects for poly(3,4-ethylenedioxythiophene) and poly(3-octylthiophene) by electrochemical impedance spectroscopy and polymerization parameters with morphological analyses on coated films
verfasst von
Murat Ates
Tolga Karazehir
Fatih Arican
Nuri Eren
Publikationsdatum
01.05.2013
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 3/2013
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-012-9448-0

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