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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 5/2021

02.01.2020 | Original Article

Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts

verfasst von: Tarun Pratap Singh Jadon, Arun Kumar Jana, Parimal A. Parikh

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 5/2021

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Abstract

We studied acetone butylation over KF/Na-ZSM-5 and ZSM-5 impregnated with other K-compounds which impart basicity. These base catalysts have, so far, not been reported for ketone alkylation. These catalysts did not contain any metal any of metal which are conventionally used to affect dehydrogenation-hydrogenation reactions which have been reported to be involved in mechanism of acetone alkylation. Absence of such metals reduces catalyst costs and eliminates metal sintering. Catalyst basicity was determined by FTIR of pyrrole-adsorbed samples and CO2 adsorption method. Coke deposited after reaction for 20 h time-on-stream on promising catalyst, namely, 10 wt% KF/Na-ZSM-5, was characterized by TGA and GCMS. This confirmed stability of KF on Na-ZSM-5, without leaching of F. Acetone conversion (60%) and ketone plus alcohol selectivity (exceeding 90%) surpassed reported performance at comparable operating conditions.
Vorheriger Artikel Improved environmental and socio-economic impacts of ethanol production from rice straw
Nächster Artikel Catalytic production of 5-hydroxymethylfurfural from sucrose and molasses by aluminum chloride in green aqueous γ-valerolactone system

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Metadaten
Titel
Conversion of biorenewably available acetone and butanol to liquid fuels using base catalysts
verfasst von
Tarun Pratap Singh Jadon
Arun Kumar Jana
Parimal A. Parikh
Publikationsdatum
02.01.2020
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 5/2021
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-019-00563-6

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