Skip to main content
Erschienen in: Clean Technologies and Environmental Policy 3/2005

01.11.2005 | Original paper

Converting liability into asset: novel mesoporous zeotype from fly ash using silatrane chemistry

verfasst von: Ganapati D. Yadav, Haresh G. Manyar

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 3/2005

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Fly ash has become a major liability. We report here a clean technology to convert this liability into an asset. Novel mesoporous zeotype, UDCaT-8 was synthesized by using a unique process based on silatrane chemistry. Instead of costly silanes and alkoxides, fly ash was utilized as a raw material. In this process, silicon and aluminium oxide dissolutions were carried out with ethylene glycol in the presence of amines as organic bases. The silatrane and alumatrane glycolate complexes thus formed were converted to a novel mesoporous zeotype via double-stage heating process (pyrolysis followed by oxidation).

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Bickmore CR, Laine RM (1996) Synthesis of oxynitride powders via fluidized-bed ammonolysis, part I: Large, porous, silica particles. J Am Ceram Soc 79(11):2865CrossRef Bickmore CR, Laine RM (1996) Synthesis of oxynitride powders via fluidized-bed ammonolysis, part I: Large, porous, silica particles. J Am Ceram Soc 79(11):2865CrossRef
Zurück zum Zitat Boer FP, Flynn JJ, Turley JW (1968) Structural studies of pentacoordinate silicon. III. Tetramethylammonium bis(o-phenylenedioxy)phenylsiliconate. J Am Chem Soc 90:6973CrossRef Boer FP, Flynn JJ, Turley JW (1968) Structural studies of pentacoordinate silicon. III. Tetramethylammonium bis(o-phenylenedioxy)phenylsiliconate. J Am Chem Soc 90:6973CrossRef
Zurück zum Zitat Brunauer S, Deming LS, Deming WS, Teller E (1940) On a theory of the van der Waals adsorption of gases. J Am Chem Soc 62:1723CrossRef Brunauer S, Deming LS, Deming WS, Teller E (1940) On a theory of the van der Waals adsorption of gases. J Am Chem Soc 62:1723CrossRef
Zurück zum Zitat Chang H–L, Shih W-H (1998) A general method for the conversion of fly ash into zeolites as Ion exchangers for cesium. Ind Eng Chem Res 37:71CrossRef Chang H–L, Shih W-H (1998) A general method for the conversion of fly ash into zeolites as Ion exchangers for cesium. Ind Eng Chem Res 37:71CrossRef
Zurück zum Zitat Corriu RJP, Reye C, Perz R, (1988) Reactivity of dianionic hexacoordinated silicon complexes toward nucleophiles: a new route to organosilanes from silica. Organometallics 7:1165CrossRef Corriu RJP, Reye C, Perz R, (1988) Reactivity of dianionic hexacoordinated silicon complexes toward nucleophiles: a new route to organosilanes from silica. Organometallics 7:1165CrossRef
Zurück zum Zitat Frye CL, (1964) Pentacoordinate silicon derivatives. II: Salts of Bis(o-arylenedioxy) organosiliconic Acids. J Am Chem Soc 86:3170CrossRef Frye CL, (1964) Pentacoordinate silicon derivatives. II: Salts of Bis(o-arylenedioxy) organosiliconic Acids. J Am Chem Soc 86:3170CrossRef
Zurück zum Zitat Frye CL (1967a) Hexacoordinate silicon complexes, US Patent 3,355,477 Frye CL (1967a) Hexacoordinate silicon complexes, US Patent 3,355,477
Zurück zum Zitat Frye CL (1967b) Penta-co-ordinate silicon complexes II, US Patent 3,360,525 Frye CL (1967b) Penta-co-ordinate silicon complexes II, US Patent 3,360,525
Zurück zum Zitat Kinrade SD, Del Nin JW, Schach AS, Sloan TA, Wilson KL, Knight CTG (1999) Stable five- and six-coordinated silicate anions in aqueous solution. Science 285:1542CrossRefPubMed Kinrade SD, Del Nin JW, Schach AS, Sloan TA, Wilson KL, Knight CTG (1999) Stable five- and six-coordinated silicate anions in aqueous solution. Science 285:1542CrossRefPubMed
Zurück zum Zitat Laine RM (1991) Inorganic and organometallic polymers with special properties. NATO ASI Series E Appl Sci 30 Laine RM (1991) Inorganic and organometallic polymers with special properties. NATO ASI Series E Appl Sci 30
Zurück zum Zitat Laine RM, Blohowiak KY, Robinson TR, Hoppe ML, Nardi P, Kamp J, Uhm J (1991) Silicon and aluminum complexes: 5- and 6-coordinate silico- and alumino- glycolates. Nature 353:642CrossRef Laine RM, Blohowiak KY, Robinson TR, Hoppe ML, Nardi P, Kamp J, Uhm J (1991) Silicon and aluminum complexes: 5- and 6-coordinate silico- and alumino- glycolates. Nature 353:642CrossRef
Zurück zum Zitat Laine RM, Mueller BM, Hinklin T (1995) Neutral and mixed neutral/anionic polymetallooxanes, US Patent 5,418,298 Laine RM, Mueller BM, Hinklin T (1995) Neutral and mixed neutral/anionic polymetallooxanes, US Patent 5,418,298
Zurück zum Zitat Laine RM, Treadwell DR, Mueller BL, Bickmore CR, Waldner KE, Hinklin T (1996) Processable aluminosilicate alkoxide precursors from metal oxides and hydroxides: The oxide one-pot synthesis process. J Mater Chem 8:1441CrossRef Laine RM, Treadwell DR, Mueller BL, Bickmore CR, Waldner KE, Hinklin T (1996) Processable aluminosilicate alkoxide precursors from metal oxides and hydroxides: The oxide one-pot synthesis process. J Mater Chem 8:1441CrossRef
Zurück zum Zitat Laine RM, Bickmore CR, Waldner KE (1997) Double alkoxide monomers oligomers and polymers, US Patent 5,614,596 Laine RM, Bickmore CR, Waldner KE (1997) Double alkoxide monomers oligomers and polymers, US Patent 5,614,596
Zurück zum Zitat LaRosa JL, Kwan S, Grutzeck MW (1992) Zeolite formation in class F fly Ash blended cement pastes. J Am Ceram Soc 75(6):1574CrossRef LaRosa JL, Kwan S, Grutzeck MW (1992) Zeolite formation in class F fly Ash blended cement pastes. J Am Ceram Soc 75(6):1574CrossRef
Zurück zum Zitat Shigemoto N, Sugiyama S, Hayashi H (1995) Characterization of Na-X, Na-A and coal fly ash zeolites and their amorphous precursors by IR, MAS NMR and XPS. J Mater Sci 30:5777CrossRef Shigemoto N, Sugiyama S, Hayashi H (1995) Characterization of Na-X, Na-A and coal fly ash zeolites and their amorphous precursors by IR, MAS NMR and XPS. J Mater Sci 30:5777CrossRef
Zurück zum Zitat Shih W-H, Chang H-L (1996) Conversion of fly ash into zeolites for ion-exchange applications. Mater Lett 28:263CrossRef Shih W-H, Chang H-L (1996) Conversion of fly ash into zeolites for ion-exchange applications. Mater Lett 28:263CrossRef
Zurück zum Zitat Shih W-H, Chang H-L, Shen Z (1995) Conversion of class-F fly ash to zeolites. MRS Symp Proc 371:39 Shih W-H, Chang H-L, Shen Z (1995) Conversion of class-F fly ash to zeolites. MRS Symp Proc 371:39
Zurück zum Zitat Yoshida A, Inoue K (1986) Formation of faujasite-type zeolite from ground Shirasu volcanic glass. Zeolites 6:467CrossRef Yoshida A, Inoue K (1986) Formation of faujasite-type zeolite from ground Shirasu volcanic glass. Zeolites 6:467CrossRef
Metadaten
Titel
Converting liability into asset: novel mesoporous zeotype from fly ash using silatrane chemistry
verfasst von
Ganapati D. Yadav
Haresh G. Manyar
Publikationsdatum
01.11.2005
Verlag
Springer-Verlag
Erschienen in
Clean Technologies and Environmental Policy / Ausgabe 3/2005
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-005-0276-0

Weitere Artikel der Ausgabe 3/2005

Clean Technologies and Environmental Policy 3/2005 Zur Ausgabe