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Erschienen in:
21.04.2018
Crystal structure and microwave dielectric properties of [(Mg0.6Zn0.4)0.95Co0.05]2TiO4-modified Ca0.6La0.8/3TiO3 cordierite ceramics with a near-zero temperature coefficient
Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 13/2018
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Abstract
The microstructure and dielectric properties of x[(Mg0.6Zn0.4)0.95Co0.05]2TiO4–(1 − x)Ca0.6La0.8/3TiO3 (x = 0.9–0.96) ceramics prepared via conventional solid-state method were investigated using scanning electron microscopy and a network analyzer. Mixed phases of [(Mg0.6Zn0.4)0.95Co0.05]2TiO4 and Ca0.6La0.8/3TiO3 were detected using X-ray diffraction. The microwave dielectric properties are strongly correlated with the sintering temperature. Temperature coefficient of resonant frequency could be controlled by amount of Ca0.6La0.8/3TiO3 and thus near-zero temperature coefficient value can be obtained. With x = 0.94 sintered at 1175 °C for 4 h, the proposed dielectric material, applicable to microwave devices, has the following dielectric properties: a dielectric constant ~ 18.1, a quality factor value of ~ 156,000 (at 9 GHz), and temperature coefficient of resonant frequency of 1.2 ppm/°C.