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Erschienen in: Journal of Materials Science: Materials in Electronics 3/2019

10.12.2018

Crystal structures, intrinsic properties and phonon characteristics of non-stoichiometric Nd[Mg1/2(1+x)Sn1/2]O3 ceramics

verfasst von: Juhui Zhang, Guohua Chen, Jing Wang, Jianzhu Li, Chao Xing, Ze-Ming Qi, Feng Shi

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 3/2019

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Abstract

The non-stoichiometric Nd[Mg1/2(1+x)Sn1/2]O3 (NMS, − 0.04 ≤ x ≤ 0.04) were synthesized through a routine solid-state reaction process. The phase composition, phonon characteristics, and microwave dielectric properties were investigated by X-ray diffraction patterns, Scanning electron microscopy Raman and Fourier transform far-infrared reflection. The best crystallinity with uniformly distributed grains and clear grain boundaries at x = 0.01. The intrinsic properties were calculated by four-parameter semi-quantum model based on far-infrared reflectivity data, which agree well with those values obtained from the microscopic polarizabilities & damping coefficient angle. The correlations between intrinsic properties and lattice vibrational modes were discussed in particular.

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Metadaten
Titel
Crystal structures, intrinsic properties and phonon characteristics of non-stoichiometric Nd[Mg1/2(1+x)Sn1/2]O3 ceramics
verfasst von
Juhui Zhang
Guohua Chen
Jing Wang
Jianzhu Li
Chao Xing
Ze-Ming Qi
Feng Shi
Publikationsdatum
10.12.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 3/2019
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-018-0518-7

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