nach oben

Journal of Polymer Research

Erschienen in:

01.10.2017 | ORIGINAL PAPER

Designing a low-temperature curable phenolic/benzoxazine-functionalized phthalonitrile copolymers for high performance composite laminates

verfasst von: Xulin Yang, Kui Li, Mingzhen Xu, Kun Jia, Xiaobo Liu

Erschienen in: Journal of Polymer Research | Ausgabe 11/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

A low-temperature curable phenolic/benzoxazine-functionalized phthalonitrile (SH/BZ-CN) copolymer system with well processability is designed and applied in high performance glass fiber (GF) composite laminates. Differential scanning calorimetry (DSC) results showed that plenty of phenolic hydroxyl groups on SH could catalyze the oxazine ring-opening and triazine/phthalonitrile ring-forming reaction of BZ-CN. The ring-opening peak and ring-forming peak of SH/BZ-CN systems are reduced by 47.1 °C and 17.0 °C than those of BZ-CN, respectively. The processability of SH/BZ-CN copolymers were improved and could be controlled by tuning SH content, processing temperature and time. These parameters provided ground for preparing SH/BZ-CN/GF composite laminates under a relatively mild condition. All SH/BZ-CN/GF composite laminates exhibit excellent flexural strength more than 500 MPa and flexural modulus over 22.0 Gpa. SH/BZ-CN/GF composites showed immiscible structures and double Tgs, and they could stand high temperature up to 350 °C. Low temperature curing, short processing time and low processing pressure are beneficial to large-scale manufacturing and application of SH/BZ-CN/GF composites.

Vorheriger Artikel Butanol-mediated oven-drying of nanocellulose with enhanced dehydration rate and aqueous re-dispersion

Nächster Artikel Atom transfer radical polymerization by [RuCl2(PPh3)2(amine)] catalysts: Cyclic amines as tuner of reactivity

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Laskoski M, Dominguez DD, Keller TM (2013) Alkyne-containing phthalonitrile resins: controlling mechanical properties by selective curing. J Polym Sci A Polym Chem 51(22):4774–4778CrossRef

Keller TM (1988) Phthalonitrile-based high temperature resin. J Polym Sci A Polym Chem 26(12):3199–3212CrossRef

Zhang J, Liu X, Wen H, Xie M, Cai X (1997) Investigation of the properties of phthalocyanine resin containing bismaleimide groups. Polym Int 42(4):363–366CrossRef

Zuo F, Liu X (2010) Synthesis and curing behavior of a novel benzoxazine-based bisphthalonitrile monomer. J Appl Polym Sci 117(3):1469–1475

Sastri SB, Armistead JP, Keller TM (1996) Phthalonitrile-carbon fiber composites. Polym Compos 17(6):816–822CrossRef

Keller TM, Price TR (1982) Amine-cured bisphenol-linked phthalonitrile resins. J Macromol Sci Chem 18(6):931–937CrossRef

Dominguez DD, Keller TM (2006) Low-melting phthalonitrile oligomers: preparation, polymerization and polymer properties. High Perform Polym 18(3):283–304CrossRef

Zeng K, Yang G (2012) Phthalonitrile matrix resins and composites. John Wiley & Sons, Inc., New Jersey

Keller TM (1994) Synthesis and polymerization of multiple aromatic ether phthalonitriles. Chem Mater 6(3):302–305CrossRef

10.

Sastri SB, Keller TM (1999) Phthalonitrile polymers: cure behavior and properties. J Polym Sci A Polym Chem 37(13):2105–2111CrossRef

11.

Sumner MJ, Sankarapandian M, McGrath JE, Riffle JS, Sorathia U (2002) Flame retardant novolac–bisphthalonitrile structural thermosets. Polymer 43(19):5069–5076CrossRef

12.

Keller TM (1992) Strong organic acid cured phthalonitrile resins for high temperature applications. Polym Prepr (USA) 33(1):422–423

13.

Burchill PJ (1994) On the formation and properties of a high-temperature resin from a bisphthalonitrile. J Polym Sci A Polym Chem 32(1):1–8CrossRef

14.

Zeng K, Zhou K, Zhou S, Hong H, Zhou H, Wang Y, Yang G (2009) Studies on self-promoted cure behaviors of hydroxy-containing phthalonitrile model compounds. Eur Polym J 45(4):1328–1335CrossRef

15.

Zhou H, Badashah A, Luo Z, Liu F, Zhao T (2011) Preparation and property comparison of ortho, meta, and para autocatalytic phthalonitrile compounds with amino group. Polym Adv Technol 22(10):1459–1465CrossRef

16.

Duro JA, de la Torre G, Barberá J, Serrano JL, Torres T (1996) Synthesis and liquid-crystal behavior of metal-free and metal-containing phthalocyanines substituted with long-chain amide groups. Chem Mater 8(5):1061–1066CrossRef

17.

Augustine D, Mathew D, Nair CR (2015) Phthalonitrile resin bearing cyanate ester groups: synthesis and characterization. RSC Adv 5(111):91254–91261CrossRef

18.

Zou X, Xu M, Jia K, Liu X (2014) Synthesis, polymerization, and properties of the allyl-functional phthalonitrile. J Appl Polym Sci 131(23)

19.

Chaisuwan T, Ishida H (2006) High-performance maleimide and nitrile-functionalized benzoxazines with good processibility for advanced composites applications. J Appl Polym Sci 101(1):548–558CrossRef

20.

Zhang B, Luo Z, Zhou H, Liu F, Yu R, Pan Y, Zhao T (2012) Addition-curable phthalonitrile-functionalized novolac resin. High Perform Polym 24(5):398–404CrossRef

21.

Keller TM (1993) Imide-containing phthalonitrile resin. Polymer 34(5):952–955CrossRef

22.

Xu M, Yang X, Zhao R, Liu X (2013) Copolymerizing behavior and processability of benzoxazine/epoxy systems and their applications for glass fiber composite laminates. J Appl Polym Sci 128(2):1176–1184CrossRef

23.

Dominguez DD, Keller TM (2008) Phthalonitrile-epoxy blends: cure behavior and copolymer properties. J Appl Polym Sci 110(4):2504–2515CrossRef

24.

Guo H, Lei Y, Zhao X, Yang X, Zhao R, Liu X (2012) Curing behaviors and properties of novolac/bisphthalonitrile blends. J Appl Polym Sci 125(1):649–656CrossRef

25.

Zou X, Xu M, Jia K, Liu X (2015) Copolymerizing behavior and processability of allyl-functional bisphthalonitrile/bismaleimide system. Polym Compos 38(8):1591–1599

26.

Ghosh NN, Kiskan B, Yagci Y (2007) Polybenzoxazines—new high performance thermosetting resins: synthesis and properties. Prog Polym Sci 32(11):1344–1391CrossRef

27.

Yagci Y, Kiskan B, Ghosh NN (2009) Recent advancement on polybenzoxazine—a newly developed high performance thermoset. J Polym Sci A Polym Chem 47(21):5565–5576CrossRef

28.

Agag T, Takeichi T (2003) Synthesis and characterization of novel benzoxazine monomers containing allyl groups and their high performance thermosets. Macromolecules 36(16):6010–6017CrossRef

29.

Kiskan B, Colak D, Muftuoglu AE, Cianga I, Yagci Y (2005) Synthesis and characterization of thermally curable benzoxazine-functionalized polystyrene macromonomers. Macromol Rapid Commun 26(10):819–824CrossRef

30.

Liu YL, Yu JM (2006) Cocuring behaviors of benzoxazine and maleimide derivatives and the thermal properties of the cured products. J Polym Sci A Polym Chem 44(6):1890–1899CrossRef

31.

Kumar KS, Nair CR, Ninan KN (2009) Investigations on the cure chemistry and polymer properties of benzoxazine–cyanate ester blends. Eur Polym J 45(2):494–502CrossRef

32.

Kimura H, Ohtsuka K, Matsumoto A (2011) Curing reaction of bisphenol-A based benzoxazine with cyanate ester resin and the properties of the cured thermosetting resin. Express Polym Lett 5(12):1113–1122CrossRef

33.

Li X, Gu Y (2011) The co-curing process of a benzoxazine-cyanate system and the thermal properties of the copolymers. Polym Chem 2(12):2778–2781CrossRef

34.

Lin CH, Huang SJ, Wang PJ, Lin HT, Dai SA (2012) Miscibility, microstructure, and thermal and dielectric properties of reactive blends of dicyanate ester and diamine-based benzoxazine. Macromolecules 45(18):7461–7466CrossRef

35.

Wang MW, Jeng RJ, Lin CH (2015) Origin of the rapid trimerization of cyanate ester in a benzoxazine/cyanate ester blend. Macromolecules 48(8):2417–2421CrossRef

36.

Liu J, Scott C, Winroth S, Maia J, Ishida H (2015) Copolymers based on telechelic benzoxazine with a reactive main-chain and anhydride: monomer and polymer synthesis, and thermal and mechanical properties of carbon fiber composites. RSC Adv 5(22):16785–16791CrossRef

37.

Kornmann X, Berglund LA, Lindberg H (2000) Stiffness improvements and molecular mobility in epoxy-clay nanocomposites MRS Online Proceedings Library Archive, 628

Titel: Designing a low-temperature curable phenolic/benzoxazine-functionalized phthalonitrile copolymers for high performance composite laminates
verfasst von: Xulin Yang
Kui Li
Mingzhen Xu
Kun Jia
Xiaobo Liu
Publikationsdatum: 01.10.2017
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 11/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-017-1360-y

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 11/2017

Preparation and characterization of poly (styrene-co-Methacrylic acid) copolymer nanoparticles via precipitation polymerization

Preparation of gelatin/epigallocatechin gallate self-assembly nanoparticles for transdermal drug delivery

Effects of various monomers and micro-structure of polyhydroxyalkanoates on the behavior of endothelial progenitor cells and endothelial cells for vascular tissue engineering

Thiacalix[3]Triazine-centered regioregular poly(3-hexylthiophene) star: synthesis, structure and anion binding

Experimental determination of microphase separation conversion during photopolymerization of cross-linking monomers to control the evolution of optical inhomogeneities in the volume of the forming polymer

Molecular simulation and experimental studies of the miscibility of PLA/PLAx-PEGy-PLAx blends

Premium Partner

Marktübersichten