nach oben

Cellulose

Erschienen in:

11.01.2022 | Original Research

Development of chitosan, graphene oxide, and cerium oxide composite blended films: structural, physical, and functional properties

verfasst von: Pradeep Kumar Panda, Pranjyan Dash, Jen-Ming Yang, Yen-Hsiang Chang

Erschienen in: Cellulose | Ausgabe 4/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

In this study, we prepared chitosan-based composite blended films using simple solution casting and solvent evaporation techniques. The chemical and physical properties of all the films were evaluated by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), Wide-angle X-ray diffraction (WXRD), field emission scanning electron microscope (FESEM), mechanical property (tensile strength and elongation at break), water contact angle and UV–visible spectrophotometer. After adding graphene oxide and cerium oxide into the chitosan polymer matrix, its water contact angle and tensile strength increased, and elongation at break decreased. Moreover, all the prepared films were investigated for their antioxidant properties using 2, 2-Diphenyl-1-picrylhydrazyl (DPPH) assay (both dose and time-dependent) and barrier properties. It is found that chitosan, graphene oxide, and cerium oxide (Cs/GO/CeO₂) film showed the highest antioxidant activity compared to other prepared films (Cs, Cs/GO, and Cs/CeO₂) due to the synergetic effects of both GO and CeO₂. The obtained results suggest that the prepared nanocomposite films have the potential for food packaging applications.

Vorheriger Artikel Printable, castable, nanocrystalline cellulose-epoxy composites exhibiting hierarchical nacre-like toughening

Nächster Artikel Thermo-responsive hydrogels based on methylcellulose/Persian gum loaded with taxifolin enhance bone regeneration: an in vitro/in vivo study

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Ahmed J, Mulla M, Arfat YA, Thai TLA (2017) Mechanical, thermal, structural and barrier properties of crab shell chitosan/graphene oxide composite films. Food Hydrocoll 71:141–148. https://doi.org/10.1016/j.foodhyd.2017.05.013CrossRef

Aider M (2010) Chitosan application for active bio-based films production and potential in the food industry: review. LWT - Food Sci Techonol 43(6):837–842. https://doi.org/10.1016/j.lwt.2010.01.021CrossRef

Cazón P, Velazquez G, Ramírez JA, Vázquez M (2017) Polysaccharide-based films and coatings for food packaging: A review. Food Hydrocoll 68:136–148. https://doi.org/10.1016/j.foodhyd.2016.09.009CrossRef

Chang SH, Wu CH, Tsai GJ (2018) Effects of chitosan molecular weight on its antioxidant and antimutagenic properties. Carbohydr Polym 181:1026–1032. https://doi.org/10.1016/j.carbpol.2017.11.047CrossRefPubMed

Dash P, Yang J-M, Lin H, Lin AS (2020) Preparation and characterization of zinc gallate phosphor for electrochemical luminescence. J Lumin 228:117593. https://doi.org/10.1016/j.jlumin.2020.117593CrossRef

Deepa B, Abraham E, Pothan LA, Cordeiro N, Faria M, Thomas S (2016) Biodegradable nanocomposite films based on sodium alginate and cellulose nanofibrils. Materials 9(1):50. https://doi.org/10.3390/ma9010050CrossRefPubMedCentral

Dewangan R, Asthana A, Singh AK, Carabineiro SAC (2020) Control of surface functionalization of graphene-metal oxide polymer nanocomposites prepared by a hydrothermal method. Polym Bull 78(8):4665–4683. https://doi.org/10.1007/s00289-020-03342-wCrossRef

Dhand V, Rhee KY, Ju Kim H, Ho Jung D (2013) A Comprehensive review of graphene nanocomposites: research status and trends. J Nanomater 2013:1–14. https://doi.org/10.1155/2013/763953CrossRef

Dhand V, Yadav M, Kim SH, Rhee KY (2021) A comprehensive review on the prospects of multi-functional carbon nano onions as an effective, high- performance energy storage material. Carbon 175:534–575. https://doi.org/10.1016/j.carbon.2020.12.083CrossRef

Ehsani A, Heidari AA, Shiri HM (2019) Electrochemical pseudocapacitors based on ternary nanocomposite of conductive Polymer/Graphene/Metal oxide: an introduction and review to it in recent studies. Chem Rec 19(5):908–926. https://doi.org/10.1002/tcr.201800112CrossRefPubMed

El Knidri H, Belaabed R, Addaou A, Laajeb A, Lahsini A (2018) Extraction, chemical modification and characterization of chitin and chitosan. Int J Biol Macromol 120:1181–1189CrossRef

Farahmandjou M, M Zarinkamar, Firoozabadi TP (2016) Synthesis of Cerium Oxide (CeO2) nanoparticles using simple CO-precipitation method. Revista Mexicana de Física 62: 496–499

Fathy RM, Mahfouz AY (2021) Eco-friendly graphene oxide-based magnesium oxide nanocomposite synthesis using fungal fermented by-products and gamma rays for outstanding antimicrobial, antioxidant, and anticancer activities. J Nanostruct Chem 11(2):301–321. https://doi.org/10.1007/s40097-020-00369-3CrossRef

Feng Y, Xia W (2011) Preparation, characterization and antibacterial activity of water-soluble O-fumaryl-chitosan. Carbohydr Polym 83(3):1169–1173. https://doi.org/10.1016/j.carbpol.2010.09.026CrossRef

Fereidoon Shahidi JKVA, Jeon Y-J (1999) Food applications of chitin and chitosans. Trends Food Sci Technol 10:37–51. https://doi.org/10.1016/S0924-2244(99)00017-5CrossRef

Garavand F, Rouhi M, Razavi SH, Cacciotti I, Mohammadi R (2017) Improving the integrity of natural biopolymer films used in food packaging by crosslinking approach: a review. Int J Biol Macromol 104(Pt A):687–707. https://doi.org/10.1016/j.ijbiomac.2017.06.093CrossRefPubMed

Goudar N, Vanjeri VN, Kasai D, Gouripur G, Malabadi RB, Masti SP, Chougale RB (2021) ZnO NPs Doped PVA/Spathodea campanulata thin films for food packaging. J Polym Environ 29(9):2797–2812. https://doi.org/10.1007/s10924-021-02070-0CrossRef

Grande Tovar CD, Castro JI, Valencia CH, Zapata PA, Solano MA, Florez Lopez E, Mina Hernandez JH (2020) Synthesis of chitosan beads incorporating graphene oxide/titanium dioxide nanoparticles for in vivo studies. Molecules 25(10):2308. https://doi.org/10.3390/molecules25102308CrossRefPubMedCentral

He L, Wang H, Xia G, Sun J, Song R (2014) Chitosan/graphene oxide nanocomposite films with enhanced interfacial interaction and their electrochemical applications. Appl Surf Sci 314:510–515. https://doi.org/10.1016/j.apsusc.2014.07.033CrossRef

Hosseini M, Mozafari M (2020) Cerium oxide nanoparticles: recent advances in tissue engineering. Materials (basel) 13(14):3072. https://doi.org/10.3390/ma13143072CrossRef

Huang X, Li L-D, Lyu G-M, Shen B-Y, Han Y-F, Shi J-L, Yan C-H (2018) Chitosan-coated cerium oxide nanocubes accelerate cutaneous wound healing by curtailing persistent inflammation. Inorg Chem Front 5(2):386–393. https://doi.org/10.1039/C7QI00707HCrossRef

Kalantari K, Mostafavi E, Saleh B, Soltantabar P, Webster TJ (2020) Chitosan/PVA hydrogels incorporated with green synthesized cerium oxide nanoparticles for wound healing applications. Eur Polym J 134:109853. https://doi.org/10.1016/j.eurpolymj.2020.109853CrossRef

Kalaycıoğlu Z, Kahya N, Adımcılar V, Kaygusuz H, Torlak E, Akın-Evingür G, Erim FB (2020) Antibacterial nano cerium oxide/chitosan/cellulose acetate composite films as potential wound dressing. Eur Polym J 133:109777. https://doi.org/10.1016/j.eurpolymj.2020.109777CrossRef

Kaya M, Khadem S, Cakmak YS, Mujtaba M, Ilk S, Akyuz L, Deligöz E (2018) Antioxidative and antimicrobial edible chitosan films blended with stem, leaf and seed extracts of Pistacia terebinthus for active food packaging. RSC Adv 8(8):3941–3950. https://doi.org/10.1039/C7RA12070BCrossRef

Kaygusuz H, Erim FB (2020) Biopolymer-assisted green synthesis of functional cerium oxide nanoparticles. Chem Pap 74(7):2357–2363. https://doi.org/10.1007/s11696-020-01084-7CrossRef

Kim D, Dhand V, Rhee K, Park S-J (2015) Study on the effect of silanization and improvement in the tensile behavior of graphene-chitosan-composite. Polymers 7(3):527–551. https://doi.org/10.3390/polym7030527CrossRef

Kim SJ, Chung BH (2016) Antioxidant activity of levan coated cerium oxide nanoparticles. Carbohydr Polym 150:400–407. https://doi.org/10.1016/j.carbpol.2016.05.021CrossRefPubMed

Komarov BA, Baskakov SA, Baskakova YV, Lesnichaya VA, Kabachkov EN, Shul’ga YM (2019) Mechanical properties of films of graphene oxide doped with chitosan. Russian J Phys Chem A 93(3):538–541. https://doi.org/10.1134/S0036024419030105CrossRef

Konwar A, Kalita S, Kotoky J, Chowdhury D (2016) Chitosan-iron oxide coated graphene oxide nanocomposite hydrogel: a robust and soft antimicrobial biofilm. ACS Appl Mater Interfaces 8(32):20625–20634. https://doi.org/10.1021/acsami.6b07510CrossRefPubMed

Kumar MNVR (2000) A review of chitin and chitosan applications. React Funct Polym 46:1–27. https://doi.org/10.1016/S1381-5148(00)00038-9CrossRef

Li Y, Feng Z, Huang L, Essa K, Bilotti E, Zhang H, Hao L (2019) Additive manufacturing high performance graphene-based composites: a review. Compos - A Appl Sci Manuf 124:105483. https://doi.org/10.1016/j.compositesa.2019.105483CrossRef

Liu Z, Ge X, Lu Y, Dong S, Zhao Y, Zeng M (2012) Effects of chitosan molecular weight and degree of deacetylation on the properties of gelatine-based films. Food Hydrocoll 26(1):311–317. https://doi.org/10.1016/j.foodhyd.2011.06.008CrossRef

Mahmoudi N, Ostadhossein F, Simchi A (2016) Physicochemical and antibacterial properties of chitosan-polyvinylpyrrolidone films containing self-organized graphene oxide nanolayers. J Appl Polym Sci 133(11):43194. https://doi.org/10.1002/app.43194CrossRef

Martucci JF, Ruseckaite RA (2009) Biodegradation of three-layer laminate films based on gelatin under indoor soil conditions. Polym Degrad Stab 94(8):1307–1313. https://doi.org/10.1016/j.polymdegradstab.2009.03.018CrossRef

Muruganantham Chelliah JBR, Uma Maheshwari K (2012) Synthesis and characterization of cerium oxide nanoparticles by hydroxide mediated approach. J Appl Sci 12:1734–1737. https://doi.org/10.3923/jas.2012.1734.1737CrossRef

Orsuwan A, Shankar S, Wang L-F, Sothornvit R, Rhim J-W (2016) Preparation of antimicrobial agar/banana powder blend films reinforced with silver nanoparticles. Food Hydrocoll 60:476–485. https://doi.org/10.1016/j.foodhyd.2016.04.017CrossRef

Pan Y, Wu T, Bao H, Li L (2011) Green fabrication of chitosan films reinforced with parallel aligned graphene oxide. Carbohydr Polym 83(4):1908–1915. https://doi.org/10.1016/j.carbpol.2010.10.054CrossRef

Panda PK, Yang JM, Chang YH (2021a) Preparation and characterization of ferulic acid-modified water soluble chitosan and poly (gamma-glutamic acid) polyelectrolyte films through layer-by-layer assembly towards protein adsorption. Int J Biol Macromol 171:457–464. https://doi.org/10.1016/j.ijbiomac.2020.12.226CrossRefPubMed

Panda PK, Yang JM, Chang YH (2021b) Water-induced shape memory behavior of poly (vinyl alcohol) and p-coumaric acid-modified water-soluble chitosan blended membrane. Carbohydr Polym 257:117633. https://doi.org/10.1016/j.carbpol.2021.117633CrossRefPubMed

Panda PK, Yang JM, Chang YH, Su WW (2019) Modification of different molecular weights of chitosan by p-Coumaric acid: preparation, characterization and effect of molecular weight on its water solubility and antioxidant property. Int J Biol Macromol 136:661–667. https://doi.org/10.1016/j.ijbiomac.2019.06.082CrossRefPubMed

Pop OL, Mesaros A, Vodnar DC, Suharoschi R, Tabaran F, Magerusan L, Socaciu C (2020) Cerium oxide nanoparticles and their efficient antibacterial application in vitro against gram-positive and gram-negative pathogens. Nanomaterials (basel) 10(8):1614. https://doi.org/10.3390/nano10081614CrossRef

Ray Chowdhuri A, Tripathy S, Chandra S, Roy S, Sahu SK (2015) A ZnO decorated chitosan–graphene oxide nanocomposite shows significantly enhanced antimicrobial activity with ROS generation. RSC Adv 5(61):49420–49428. https://doi.org/10.1039/C5RA05393ECrossRef

Shanta Pokhrel PNY, Rameshwar A (2015) Applications of chitin and chitosan in Industry and medical science: a review. Nepal J f Sci Technol 16(1):99–104. https://doi.org/10.3126/njst.v16i1.14363CrossRef

Wang H, Qian J, Ding F (2018) Emerging chitosan-based films for food packaging applications. J Agric Food Chem 66(2):395–413. https://doi.org/10.1021/acs.jafc.7b04528CrossRefPubMed

Wang J, Yao W, Gu P, Yu S, Wang X, Du Y, Wang X (2016) Efficient coagulation of graphene oxide on chitosan–metal oxide composites from aqueous solutions. Cellulose 24(2):851–861. https://doi.org/10.1007/s10570-016-1176-7CrossRef

Yang J-M, Wang S-A (2015) Preparation of graphene-based poly(vinyl alcohol)/chitosan nanocomposites membrane for alkaline solid electrolytes membrane. J Membr Sci 477:49–57. https://doi.org/10.1016/j.memsci.2014.12.028CrossRef

Yang JM, Olanrele OS, Zhang X, Hsu CC (2018) Fabrication of hydrogel materials for biomedical applications. Novel Biomater Regen Med. https://doi.org/10.1007/978-981-13-0947-2_12CrossRef

Yang X, Tu Y, Li L, Shang S, Tao XM (2010) Well-dispersed chitosan/graphene oxide nanocomposites. ACS Appl Mater Interfaces 2(6):1707–1713. https://doi.org/10.1021/am100222mCrossRefPubMed

Yong H, Wang X, Bai R, Miao Z, Zhang X, Liu J (2019a) Development of antioxidant and intelligent pH-sensing packaging films by incorporating purple-fleshed sweet potato extract into chitosan matrix. Food Hydrocoll 90:216–224. https://doi.org/10.1016/j.foodhyd.2018.12.015CrossRef

Yong H, Wang X, Zhang X, Liu Y, Qin Y, Liu J (2019b) Effects of anthocyanin-rich purple and black eggplant extracts on the physical, antioxidant and pH-sensitive properties of chitosan film. Food Hydrocoll 94:93–104. https://doi.org/10.1016/j.foodhyd.2019.03.012CrossRef

Yu Y, Wang X, Gao W, Li P, Yan W, Wu S, Ding K (2017) Trivalent cerium-preponderant CeO₂/graphene sandwich-structured nanocomposite with greatly enhanced catalytic activity for the oxygen reduction reaction. J Mater Chem A 5(14):6656–6663. https://doi.org/10.1039/C6TA10415KCrossRef

Zhai Y, Zhou K, Xue Y, Qin F, Yang L, Yao X (2013) Synthesis of water-soluble chitosan-coated nanoceria with excellent antioxidant properties. RSC Adv 3(19):6833–6838. https://doi.org/10.1039/C3RA22251ACrossRef

Zhang C, Ping Q, Zhang H, Shen J (2003) Synthesis and characterization of water-soluble O-succinyl-chitosan. EurPolym J 39(8):1629–1634. https://doi.org/10.1016/S0014-3057(03)00068-5CrossRef

Zhang Y, Zhang M, Jiang H, Shi J, Li F, Xia Y, Li H (2017) Bio-inspired layered chitosan/graphene oxide nanocomposite hydrogels with high strength and pH-driven shape memory effect. Carbohydr Polym 177:116–125. https://doi.org/10.1016/j.carbpol.2017.08.106CrossRefPubMed

Titel: Development of chitosan, graphene oxide, and cerium oxide composite blended films: structural, physical, and functional properties
verfasst von: Pradeep Kumar Panda
Pranjyan Dash
Jen-Ming Yang
Yen-Hsiang Chang
Publikationsdatum: 11.01.2022
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2022
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04348-x

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 4/2022

Microwave assisted ultrafast immobilization of CuO nanostructures in paper matrices for antimicrobial applications

Green nanoarchitectonics for next generation electronics devices: patterning of conductive nanowires on regenerated cellulose substrates

Characterization and modeling the hygroscopic behavior of cellulose acetate membranes

Construction of hydrogels based on the chitin from Hericium erinaceus residue: role of molecular weight

Study and characterization of the lignocellulosic Fique (Furcraea Andina spp.) fiber

Insight into the performance of lignin-containing cellulose nanofibers (LCNFs) via lignin content regulation by p-toluenesulfonic acid delignification