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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 8/2020

14.03.2020

Direct in situ assembly of bimetallic Co–Ni hydroxide/polyaniline-modified reduced graphene oxide nanocomposite for asymmetric flexible supercapacitor electrode

verfasst von: Defu Wang, Yanhua Zhang, Lan Yang, Guoli Fan, Yanjun Lin, Feng Li

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 8/2020

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Abstract

In the present work, a novel hybrid nanocomposite of bimetallic Co–Ni hydroxide and polyaniline-modified partially reduced graphene oxide (PRGO) was assembled via in situ growth route for supercapacitor application. A series of characterizations demonstrated that large quantities of bimetallic Co–Ni hydroxide nanosheets could longitudinally grow on the surface of PRGO substrate and intercross together, forming a hierarchical honeycomb-like micro/nanostructure array. As-assembled CoNi(OH)2/PRGO nanocomposite showed a much higher specific capacitance of 2760 ± 160 F g−1 at 1.0 A g−1 in three-electrode measurements, in comparison with pristine bimetallic Co–Ni hydroxide, Co(OH)2/PRGO, and Ni(OH)2/PRGO reference electrodes, which originated from the synergy effect between component units and unique three-dimensional conductive porous framework of nanocomposite, thereby greatly promoting the redox processes of metal ions and facilitating the ion diffusion between the electrolyte and the electrode, as well as the electron transfer. Furthermore, after 1000 charge–discharge cycles, as-assembled nanocomposite electrode possessed good cycling stability, along with a high 93.2% retention level of capacitance at 10 A g−1. An asymmetric flexible all-solid-state supercapacitor device was equipped with poly (vinyl alcohol) film as the solid electrolyte, and as-assembled CoNi(OH)2/PRGO as the positive electrode delivered a 74.84 ± 1.46 wh kg−1 energy density and a 374.34 ± 0.15 w kg−1 power density at 0.5 A g−1, indicating good supercapacitor performance for energy storage and applications in flexible and wearable electronics.
Vorheriger Artikel Analytical investigation of ion-sensitive field effect transistor based on graphene
Nächster Artikel Influence of trivalent lanthanides substitution on the thermoelectric properties of nanostructured Ca1−xLn3 +xMnO3−δ (Ln3+ = Sm, Ce, La; x = 0, 0.1)

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Metadaten
Titel
Direct in situ assembly of bimetallic Co–Ni hydroxide/polyaniline-modified reduced graphene oxide nanocomposite for asymmetric flexible supercapacitor electrode
verfasst von
Defu Wang
Yanhua Zhang
Lan Yang
Guoli Fan
Yanjun Lin
Feng Li
Publikationsdatum
14.03.2020
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 8/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-020-03202-3

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