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Metallurgical and Materials Transactions A
Erschienen in: Metallurgical and Materials Transactions A 2/2011

01.02.2011 | Symposium: International Symposium on Stress Corrosion Cracking in Structural Materials

Dissolution Condensation Mechanism of Stress Corrosion Cracking in Liquid Metals: Driving Force and Crack Kinetics

verfasst von: Evgeny E. Glickman

Erschienen in: Metallurgical and Materials Transactions A | Ausgabe 2/2011

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Abstract

Stress corrosion cracking (SCC) in aqueous solution is driven by exothermic reactions of metal oxidation. This stimulus, as well as classical mechanisms of SCC, does not apply to SCC in liquid metals (LMs). In the framework of the dissolution-condensation mechanism (DCM), we analyzed the driving force and crack kinetics for this nonelectrochemical mode of SCC that is loosely called “liquid metal embrittlement” (LME). According to DCM, a stress-induced increase in chemical potential at the crack tip acts as the driving force for out-of-the-tip diffusion mass transfer that is fast because diffusion in LMs is very fast and surface energy at the solid-liquid interface is small. In this article, we review two versions of DCM mechanism, discuss the major physics behind them, and develop DCM further. The refined mechanism is applied then to the experimental data on crack velocity V vs stress intensity factor, the activation energy of LME, and alloying effects. It is concluded that DCM provides a good conceptual framework for analysis of a unified kinetic mechanism of LME and may also contribute to SCC in aqueous solutions.
Vorheriger Artikel Foreword: International Symposium on the Stress Corrosion Cracking in Structural Materials at Ambient Temperatures
Nächster Artikel The Use of Atomic Force Microscopy to Study Crack Tips in Glass

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Metadaten
Titel
Dissolution Condensation Mechanism of Stress Corrosion Cracking in Liquid Metals: Driving Force and Crack Kinetics
verfasst von
Evgeny E. Glickman
Publikationsdatum
01.02.2011
Verlag
Springer US
Erschienen in
Metallurgical and Materials Transactions A / Ausgabe 2/2011
Print ISSN: 1073-5623
Elektronische ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-010-0429-6

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