Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 4/2019

01.04.2019 | ORIGINAL PAPER

Dual responsive spiropyran-ended poly(N-vinyl caprolactam) for reversible complexation with metal ions

Erschienen in: Journal of Polymer Research | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

With the spiropyran-containing compound as the initiator, dual responsive spiropyran-ended poly(N-vinyl caprolactam) (SP-PNVCL) was synthesized by atom transfer radical polymerization. The structure of the resulting polymer was characterized by 1H NMR and gel permeation chromatography, and the polymer had both reversible light-responsive and thermo-sensitive behaviors. Metal ions could be bound between merocyanine formed by photoisomerization of spiropyran and the amino group of N-vinyl caprolactam unit through synergetic coordination. The complexation of SP-PNVCL with several metal ions was investigated by UV-Vis absorption spectroscopy, and it was found that SP-PNVCL might be used as a potential recognition probe for Fe2+, accompanied by obvious color change from colorless to brown by naked eye. The detection limit and photo-reversible recyclable behaviors of SP-PNVCL for Fe2+ were also investigated in details. The kind of spiropyran-ended poly(N-vinyl caprolactam) had great application potential in environment protection and biological area.
Vorheriger Artikel Kinetic and thermodynamic studies of molecularly imprinted polymers for the selective adsorption and specific enantiomeric recognition of D-mandelic acid
Nächster Artikel Preparation of covalently bonded polyaniline nanofibers/carbon nanotubes supercapacitor electrode materials using interfacial polymerization approach

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Sui BL, Tang SM, Liu TH, Kim BS, Belfield KD (2014) Novel BODIPY-based fluorescence turn-on sensor for Fe3+ and its bioimaging application in living cells. ACS Appl Mater Inter 6:18408–18412CrossRef
2.
Kagit R, Yildirim M, Ozay O, Yesilot S, Ozay H (2014) Phosphazene based multicentered naked-eye fluorescent sensor with high selectivity for Fe3+ ions. Inorg Chem 53:2144–2151CrossRef
3.
Santiago AA, Ibarra-Palos A, Cruz-Morales JA, Sierra JM, Abatal K (2018) Synthesis, characterization, and heavy metal adsorption properties of sulfonated aromatic polyamides. High Perform Polym 30:591–601CrossRef
4.
Jia YY, Wang L, Ma L, Yang ZG (2018) Speciation analysis of six arsenic species in marketed shellfish: extraction optimization and health risk assessment. Food Chem 244:311–316CrossRef
5.
Fu L, Shi SY, Chen XQ (2018) Accurate quantification of toxic elements in medicine food homologous plants using ICP-MS/MS. Food Chem 245:692–697CrossRef
6.
Cui HQ, Liu H, Chen S, Wang RM (2015) Synthesis of amphiphilic spiropyran-based random copolymer by atom transfer radical polymerization for Co2+ recognition. Dyes Pigments 115:50–57CrossRef
7.
Urek SK, Francic N, Turel M, Lobnik A (2013) Sensing heavy metals using mesoporous-based optical chemical sensors. J Nanomater:501320
8.
Lechuga LM (2015) Optical biochemical and chemical sensors. Anal Bioanal Chem 404:2795–2796CrossRef
9.
Hussein MA, Alam MM, Alenazi NA, Alamry KA, Asiri AM, Rahman MM (2018) Nanocomposite based functionalized Polyethersulfone and conjugated ternary ZnYCdO nanomaterials for the fabrication of selective Cd2+ sensor probe. J Polym Res 25:262CrossRef
10.
Ullah N, Mansha M, Khan I, Qurashi A (2018) Nanomaterial-based optical chemical sensors for the detection of heavy metals in water: recent advances and challenges. Trac-Trend Anal Chem 100:155–166CrossRef
11.
Otsuki J, Akasaka T, Araki K Molecular switches for electron and energy transfer processes based on metal complexes. Coordin. Chem. Rev 252:32–56CrossRef
12.
Wang F, Tang JT, Liu H, Yu GP, Zou YP (2019) Self-assembled polymeric micelles as amphiphilic particulate emulsifiers for controllable Pickering emulsions. Mater Chem Front 3:356–364CrossRef
13.
Wang F, Yu XY, Yang ZXS, Duan H, Zhang ZJ, Liu H (2018) Dual pH- and light-responsive amphiphilic random copolymer nanomicelles as particulate emulsifiers to stabilize the oil/water interface. J Phys Chem C 122:18995–19003CrossRef
14.
Wang F, Liu H (2018) Dual-functional emulsifying/antifogging coumarin-containing polymeric micelle. J Phys Chem C 122:3434–3442CrossRef
15.
Li LX, Lu B, Zhang Y, Xing XD, Wu XY, Liu ZL (2015) Multi-sensitive copolymer hydrogels of N-isopropylacrylamide with several polymerizable azobenzene-containing monomers. J Polym Res 22:176CrossRef
16.
Szymanski W, Beierle JM, Kistemaker HAV, Velema WA, Feringa BL (2013) Reversible photocontrol of biological systems by the incorporation of molecular photoswitches. Chem Rev 113:6114–6178CrossRef
17.
Bao LH, Sun JX, Li Q (2014) Synthesis and properties of waterborne polyurethane containing spiropyran groups. J Polym Res 21:575CrossRef
18.
Natali M, Aakeroey C, Desper J, Giordani S (2010) The role of metal ions and counterions in the switching behavior of a carboxylic acid functionalized spiropyran. Dalton T 39:8269–8277CrossRef
19.
Chernyshev AV, Voloshin NA, Metelitsa AV, Tkachev VV, Aldoshin SM, Solov'eva E, Rostovtseva I, Minkin VI (2013) Metal complexes of new photochromic chelator: structure, stability and photodissociation. J Photoch Photobio A 265:1–9CrossRef
20.
Paramonov SV, Lokshin V, Fedorova OA (2011) Spiropyran, chromene or spirooxazine ligands: insights into mutual relations between complexing and photochromic properties. J Photoch Photobio C 12:209–236CrossRef
21.
Suzuki T, Kawata Y, Kahata S, Kato T (2003) Photo-reversible Pb2+-complexation of insoluble poly(spiropyran methacrylate-co-perfluorohydroxy methacrylate) in polar solvents. Chem Commun (16):2004–2005
22.
Suzuki T, Hirahara Y, Bunya K, Shinozaki H (2010) Photo-reversible and selective Cu2+ complexation of a spiropyran-carrying sulfobetaine copolymer in saline solution. J Mater Chem 20:2773–2779CrossRef
23.
Fries K, Samanta S, Orski S, Locklin J (2008) Reversible colorimetric ion sensors based on surface initiated polymerization of photochromic polymers. Chem Commun (47):6288–6290
24.
Fries KH, Driskell JD, Samanta S, Locklin J (2010) Spectroscopic analysis of metal ion binding in spiropyran containing copolymer thin films. Anal Chem 82:3306–3314CrossRef
25.
Fries KH, Driskell JD, Sheppard GR, Locklin J (2011) Fabrication of spiropyran-containing thin film sensors used for the simultaneous identification of multiple metal ions. Langmuir 27:12253–12260CrossRef
26.
Fries KH, Sheppard GR, Bilbrey JA, Locklin J (2014) Tuning chelating groups and comonomers in spiropyran-containing copolymer thin films for color-specific metal ion binding. Polym Chem 5:2094–2102CrossRef
27.
Connal LA, Franks GV, Qiao GG (2010) Photochromic, metal-absorbing honeycomb structures. Langmuir 26:10397–10400CrossRef
28.
Dunne A, Delaney C, McKeon A, Nesterenko P, Paull B, Benito-Lopez F, Diamond D, Flores L (2018) Micro-capillary coatings based on spiropyran polymeric brushes for metal ion binding, detection, and release in continuous flow. Sensors 18:1083CrossRef
29.
Xie BQ, Qiu ZS, Huang WA, Cao J, Zhong HY (2013) Characterization and aqueous solution behavior of novel thermo-associating polymers. J Macromol Sci A 50:230–237CrossRef
30.
Cortez-Lemus NA, Licea-Claverie A (2016) Poly(N-vinylcaprolactam), a comprehensive review on a thermoresponsive polymer becoming popular. Prog Polym Sci 53:1–51CrossRef
31.
Mohammed MN, Bin Yusoh K, Shariffuddin JHBH (2018) Poly(N-vinyl caprolactam) thermoresponsive polymer in novel drug delivery systems: a review. Mater Express 8:21–34CrossRef
32.
Ventura C, Byrne R, Audouin F, Heise A (2011) Atom transfer radical polymerization synthesis and photoresponsive solution behavior of spiropyran end-functionalized polymers as simplistic molecular probes. J Polym Sci Pol Chem 49:3455–3463CrossRef
33.
Nakahara Y, Nakamura J, Shirotani N, Kimura K (2012) Synthesis of amphiphilic copolymers bearing a spirobenzopyran moiety at the end group and their photoresponsive micellar behaviors in water. Chem Lett 41:1142–1144CrossRef
34.
Shen HJ, Zhou M, Zhang Q, Keller A, Shen Y (2015) Zwitterionic light-responsive polymeric micelles for controlled drug delivery. Colloid Polym Sci 293:1685–1694CrossRef
35.
Wang F, Xu WS, Ouyang YS, Zhang LL, Liu H (2018) Reversible crosslinking terpolymer shell-based mesoporous silica nanoparticles as on-off nanocarriers for pyrene-releasing application. J Taiwan Inst Chem E 91:578–587CrossRef
36.
Zakharova MI, Coudret C, Pimienta V, Micheau JC, Sliwa M, Poizat O, Buntinx G, Delbaere S, Vermeersch G, Metelitsa AV, Voloshin N, Minkin VI (2011) Kinetic modelling of the photochromism and metal complexation of a spiropyran dye: application to the co(II)-spiroindoline-diphenyloxazolebenzopyran system. Dyes Pigments 89:324–329CrossRef
37.
Shiraishi Y, Matsunaga Y, Hirai T (2012) Selective colorimetric sensing of co(II) in aqueous media with a spiropyran-amide-dipicolylamine linkage under UV irradiation. Chem Commun 48:5485–5487CrossRef
38.
Sahoo PR, Kumar S (2016) Synthesis of an optically switchable salicylaldimine substituted naphthopyran for selective and reversible Cu2+ recognition in aqueous solution. RSC Adv 6:20145–20154CrossRef
39.
Heng S, McDevitt CA, Stubing DB, Whittall JJ, Thompson JG, Engler TK, Abell AD, Monro TM (2013) Microstructured optical fibers and live cells: a water-soluble, photochromic zinc sensor. Biomacromolecules 14:3376–3379CrossRef
40.
Banerjee A, Sahana A, Guha S, Lohar S, Hauli I, Mukhopadhyay SK, Matalobos JS, Das D (2012) Nickel(II)-induced excimer formation of a naphthalene-based fluorescent probe for living cell imaging. Inorg Chem 51:5699–5704CrossRef
41.
Han SL, Chen Y (2011) Mercury ion induced activation of the C-O bond in a photo-responsive spiropyran. Dyes Pigments 88:235–239CrossRef
42.
Bing QJ, Wang L, Li DL, Wang G (2018) A new high selective and sensitive turn-on fluorescent and ratiometric absorption chemosensor for Cu2+ based on benzimidazole in aqueous solution and its application in live cell. Spectrochim Acta A 202:305–313CrossRef
43.
Qi Y, Zhao J, Weng GJ, Li JJ, Zhu J, Zhao JW (2018) Modification-free colorimetric and visual detection of Hg2+ based on the etching from core-shell structural au-ag nanorods to nanorices. Sensor Actuat B-Chem 267:181–190CrossRef
44.
Choodum A, Sriprom W, Wongniramaikul W (2019) Portable and selective colorimetric film and digital image colorimetry for detection of iron. Spectrochim Acta A 208:40–47CrossRef
45.
Najarzadekan H, Sereshti H (2018) Transparent polycaprolactam electrospun nanofibers doped with 1,10-phenanthroline optical sensor for colorimetric determination of iron (II) and vitamin C. Fiber Polym 19:2149–2156CrossRef
Metadaten
Titel
Dual responsive spiropyran-ended poly(N-vinyl caprolactam) for reversible complexation with metal ions
Publikationsdatum
01.04.2019
Erschienen in
Journal of Polymer Research / Ausgabe 4/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1747-z

Weitere Artikel der Ausgabe 4/2019

Journal of Polymer Research 4/2019 Zur Ausgabe

ORIGINAL PAPER

Thermo-mechanical properties and morphology of epoxy resins with co-poly (phthalazinone ether nitrile)

ORIGINAL PAPER

Investigation of mercaptan/ε-caprolactam initiated bulk copolymerization of methyl methacrylate with vinyl monomers

ORIGINAL PAPER

Properties and characterization of near infrared-triggered natural rubber (NR)/carnauba wax (CW)/carbon nanotube (CNT) shape memory bio-nanocomposites

ORIGINAL PAPER

Optimization of reaction parameters for synthesis of Cyclodextrin nanosponges in controlled nanoscopic size dimensions

ORIGINAL PAPER

Cationic electrolyte copolymers of diallyldimethylammonium chloride with carboxybetaine 2-(diallyl(methyl) ammonio) acetate of various compositions in water solutions of different ionic strengths

ORIGINAL PAPER

Pretreatment of banana pseudostem fibre for green composite packaging film preparation with polyvinyl alcohol

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise