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Erschienen in: Journal of Materials Science: Materials in Electronics 10/2016

08.06.2016

Effect of Ba2+ doping on microstructure and electric properties of calcium copper titanate (CaCu3Ti4O12) ceramics

verfasst von: Shuang Wu, Pei Liu, Yuanming Lai, Weiming Guan, Zihan Huang, Jiao Han, Yao Xiang, Wei Yi, Yiming Zeng

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 10/2016

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Abstract

The Ba2+ doped ceramics of Ca1−xBaxCu3Ti4O12 (x = 0.005, 0.01, 0.03, 0.05 and 0.1) were sintered via conventional solid-state reaction at 1050 °C for 8 h in air. The microstructure and electric properties of Ba2+ doping ceramics were investigated. The lattice parameters of Ca1−xBaxCu3Ti4O12 (CBCTO) ceramics decreased with the Ba2+ doping, and Ba1.31Ti8O16 as secondary phase was confirmed at x = 0.1. The doping of Ba2+ resulted in uniformly distribution of small size grain (~4 μm). All the doped samples showed lower value of dielectric constant than CaCu3Ti4O12 (CCTO), due to low resistivity of the grain boundary with the Ba2+ doped samples. The nonlinear coefficient and breakdown field were significantly enhanced by Ba2+ doping.

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Metadaten
Titel
Effect of Ba2+ doping on microstructure and electric properties of calcium copper titanate (CaCu3Ti4O12) ceramics
verfasst von
Shuang Wu
Pei Liu
Yuanming Lai
Weiming Guan
Zihan Huang
Jiao Han
Yao Xiang
Wei Yi
Yiming Zeng
Publikationsdatum
08.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 10/2016
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-016-5118-9

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