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Journal of Materials Science
Erschienen in: Journal of Materials Science 1/2015

01.01.2015 | Original Paper

Effect of MoO3, Nd2O3, and RuO2 on the crystallization of soda–lime aluminoborosilicate glasses

verfasst von: N. Chouard, D. Caurant, O. Majérus, J. L. Dussossoy, S. Klimin, D. Pytalev, R. Baddour-Hadjean, J. P. Pereira-Ramos

Erschienen in: Journal of Materials Science | Ausgabe 1/2015

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Abstract

The effect of adding Nd2O3, MoO3, and RuO2 separately or simultaneously on the crystallization of a soda–lime aluminoborosilicate glass during cooling from the melt or glass heating was studied by DTA, XRD (at room and high temperature), SEM, Raman, and optical absorption. Nd2O3 addition strongly reduces liquid–liquid phase separation and crystallization of calcium and sodium molybdates (CaMoO4 (powellite) and Na2MoO4) in Mo-rich compositions as long as Nd3+ ions remain solubilized in the glassy network. This suggests that (MoO4)2− entities and Nd3+ ions are close to each other in the glass structure (Nd3+ ions would prevent the clustering of molybdate entities). The effect of MoO3 addition in Nd-rich compositions is more complex since an increase of the solubility of Nd2O3 is observed, whereas the nucleation rate of an Nd-rich silicate apatite (Ca2Nd8(SiO4)6O2) in the bulk of the glass increases as soon as molybdates crystallized. The addition of RuO2 has a nucleating effect on apatite crystallization in the bulk but not on molybdates crystallization.
Vorheriger Artikel Composition dependence of some thermo-physical properties of multi-component Se78−x Te20Sn2Bi x (0 ≤ x ≤ 6) chalcogenide glasses
Nächster Artikel Near-threshold fatigue propagation of physically through-thickness short and long cracks in a low alloy steel

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Metadaten
Titel
Effect of MoO3, Nd2O3, and RuO2 on the crystallization of soda–lime aluminoborosilicate glasses
verfasst von
N. Chouard
D. Caurant
O. Majérus
J. L. Dussossoy
S. Klimin
D. Pytalev
R. Baddour-Hadjean
J. P. Pereira-Ramos
Publikationsdatum
01.01.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 1/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8581-9

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