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12.04.2021 | Original Research

Effect of poly(methylhydrogen)siloxane modification on adjusting mechanical properties of bamboo flour‐reinforced HDPE composites

verfasst von: Fuchuan Xiao, Jie Gao, Xuanting Huang, Qingjian Hu, Ran Li, Xinxiang Zhang

Erschienen in: Cellulose | Ausgabe 9/2021

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Abstract

Poly(methylhydrogen)siloxane (PMHS) was applied for hydrophobic modification of bamboo flour (BF) at room temperature based on the dehydrogenation between hydroxyl groups of BF and –Si–H of PMHS, and the effect of PMHS modification on mechanical properties of BF/HDPE (high-density polyethylene) (BF/HDPE) composites was investigated. It was found that the hydrophobicity of BF were significantly improved by PMHS modification, and the mechanical properties of BF/HDPE composites could be adjusted effectively. PMHS with reactive hydrogen content of 1.5 % was the best candidate modifier for improving the strength of BF/HDPE, while PMHS with reactive hydrogen content of 0.2 % is more suitable to improve the toughness of BF/HDPE. More importantly, with optimal weight ratio of PMHS to BF, the strength and toughness of BF/HDPE could be improved simultaneously. After a systematic discussion on the results of FTIR, XPS, SEM and the chemical structure of PMHS, the relationship between microstructure and properties of BF/HDPE composites was built and then the mechanism for PMHS modification on BF/HDPE composites was proposed.

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Vorheriger Artikel High mechanical properties of micro fibrillated cellulose/HDPE composites prepared with two different methods

Nächster Artikel Characterization of natural cellulosic fibers from Yucca aloifolia L. leaf as potential reinforcement of polymer composites

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Titel: Effect of poly(methylhydrogen)siloxane modification on adjusting mechanical properties of bamboo flour‐reinforced HDPE composites
verfasst von: Fuchuan Xiao
Jie Gao
Xuanting Huang
Qingjian Hu
Ran Li
Xinxiang Zhang
Publikationsdatum: 12.04.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 9/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03849-z

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