nach oben

Biomass Conversion and Biorefinery

Erschienen in:

07.08.2020 | Original Article

Effect of preparation method and B-side metal type on the physicochemical properties of LaBO₃ perovskite catalyst and its catalytic behaviour in the biomass pyrolysis

verfasst von: Nurgül Özbay, Rahmiye Zerrin Yarbay Şahin

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 10/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Although perovskites are extensively investigated in many areas, studies using perovskites as catalysts for biomass pyrolysis are still quite limited. While various transition metals can be inserted into perovskites to form different perovskites, it is critical to investigate the effects of various transition metallic substituents on the characterization of catalysts. This work involves the evaluation of nine perovskite-type catalysts in terms of their effectiveness and suitability for pyrolysis of date stone biomass. LaCoO₃, LaMnO₃ and LaNiO₃ perovskite catalysts were prepared by sol-gel, hydrothermal and microwave methods and characterized by X-ray powder diffraction, scanning electron microscopy and surface area measurement. Pyrolysis of date stones has been performed in tubular reactor at 520 °C with 100 °C/min and a nitrogen gas flow rate of 100 cm³/min. The influences of catalyst preparation method on catalytic cracking of pyrolysis vapours in terms of bio-oil yields were examined. Additionally, the effect of B metal in ABO₃ perovskite structure on catalyst character and pyrolysis yields were examined in detail. According to results, highest bio-oil yield was achieved as 23.4% with LaMnO₃ catalyst synthesized with sol-gel method. All perovskite-type catalysts have reduced the bio-oil yield and improved the water and gaseous yield as expected. This study paves the way for developing more challenging perovskite catalysts for the renewable energy sources.

Vorheriger Artikel Secretome produced by a newly isolated Aspergillus flavus strain in engineered medium shows synergy for biomass saccharification with a commercial cellulase

Nächster Artikel Usage potential of apple and carrot pomaces as raw materials for newly isolated yeast lipid-based biodiesel production

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Murata K, Kreethawate L, Larpkiattaworn S, Inaba M (2016) Evaluation of Ni-based catalysts for the catalytic fast pyrolysis of jatropha residues. J Anal Appl Pyrolysis. https://doi.org/10.1016/j.jaap.2016.02.014

Sepehri A, Sarrafzadeh MH (2018) Effect of nitrifiers community on fouling mitigation and nitrification efficiency in a membrane bioreactor. Chem Eng Process Process Intensif. https://doi.org/10.1016/j.cep.2018.04.006

Whyte HE, Loubar K, Awad S, Tazerout M (2015) Pyrolytic oil production by catalytic pyrolysis of refuse-derived fuels: investigation of low cost catalysts. Fuel Process Technol. https://doi.org/10.1016/j.fuproc.2015.08.022

Ozbay N, Yargic AS, Yarbay Sahin RZ (2018) Tailoring cu/Al2O3 catalysts for the catalytic pyrolysis of tomato waste. J Energy Inst. https://doi.org/10.1016/j.joei.2017.01.010

Kabir G, Hameed BH (2017) Recent progress on catalytic pyrolysis of lignocellulosic biomass to high-grade bio-oil and bio-chemicals. Renew Sust Energ Rev. https://doi.org/10.1016/j.rser.2016.12.001CrossRef

Hernando H, Fermoso J, Ochoa-Hernández C et al (2018) Performance of MCM-22 zeolite for the catalytic fast-pyrolysis of acid-washed wheat straw. Catal Today. https://doi.org/10.1016/j.cattod.2017.09.043

Özbay N, Yargıç AŞ, Yarbay Şahin RZ, Yaman E (2018) Research on the pyrolysis characteristics of tomato waste with Fe–Al 2 O 3 catalyst. Exergetic, Energ Environ Dimens:815–828. https://doi.org/10.1016/B978-0-12-813734-5.00046-9

Blasco J, Sánchez MC, Pérez-Cacho J et al (2002) Synthesis and structural study of LaNi1-xMnxO3+δ perovskites. J Phys Chem Solids. https://doi.org/10.1016/S0022-3697(01)00228-1

Jeon Y, Lee C, Rhee J et al (2017) Autothermal reforming of heavy-hydrocarbon fuels by morphology controlled perovskite catalysts using carbon templates. Fuel. https://doi.org/10.1016/j.fuel.2016.09.065

10.

Ozbay N, Yargic A, Sahin R et al (2019) Valorization of banana peel waste via in-situ catalytic pyrolysis using Al-modified SBA-15. Elsevier 140:633–646. https://doi.org/10.1016/j.renene.2019.03.071CrossRef

11.

Yang Y, Lv G, Deng L et al (2017) Renewable aromatic production through hydrodeoxygenation of model bio-oil over mesoporous Ni/SBA-15 and co/SBA-15. Microporous Mesoporous Mater. https://doi.org/10.1016/j.micromeso.2017.05.022

12.

Kim YM, Jae J, Lee HW et al (2016) Ex-situ catalytic pyrolysis of citrus fruit peels over mesoporous MFI and Al-MCM-41. Energy Convers Manag. https://doi.org/10.1016/j.enconman.2016.02.065

13.

Grieco EM, Gervasio C, Baldi G (2013) Lanthanum-chromium-nickel perovskites for the catalytic cracking of tar model compounds. Fuel. https://doi.org/10.1016/j.fuel.2012.09.017CrossRef

14.

Ammendola P, Lisi L, Piriou B, Ruoppolo G (2009) Rh-perovskite catalysts for conversion of tar from biomass pyrolysis. Chem Eng J. https://doi.org/10.1016/j.cej.2009.04.010

15.

Sun X, Wang S, Wang Z et al (2008) Anode performance of LST–xCeO2 for solid oxide fuel cells. J Power Sources 183:114–117. https://doi.org/10.1016/J.JPOWSOUR.2008.05.007CrossRef

16.

Hameed BH, Salman JM, Ahmad AL (2009) Adsorption isotherm and kinetic modeling of 2,4-D pesticide on activated carbon derived from date stones. J Hazard Mater. https://doi.org/10.1016/j.jhazmat.2008.06.069

17.

Al-Omari SAB (2009) Evaluation of the biomass “date stones” as a fuel in furnaces: a comparison with coal combustion. Int Commun Heat Mass Transf. https://doi.org/10.1016/j.icheatmasstransfer.2009.06.016

18.

Bouchelta C, Medjram MS, Bertrand O, Bellat JP (2008) Preparation and characterization of activated carbon from date stones by physical activation with steam. J Anal Appl Pyrolysis. https://doi.org/10.1016/j.jaap.2007.12.009

19.

Taallah B, Guettala A (2016) The mechanical and physical properties of compressed earth block stabilized with lime and filled with untreated and alkali-treated date palm fibers. Constr Build Mater. https://doi.org/10.1016/j.conbuildmat.2015.12.007

20.

Sekirifa ML, Hadj-Mahammed M, Pallier S et al (2013) Preparation and characterization of an activated carbon from a date stones variety by physical activation with carbon dioxide. J Anal Appl Pyrolysis. https://doi.org/10.1016/j.jaap.2012.10.007

21.

Ahmed MJ (2016) Preparation of activated carbons from date (Phoenix dactylifera L.) palm stones and application for wastewater treatments: review. Process Saf Environ Prot

22.

Khelaifia FZ, Hazourli S, Nouacer S et al (2016) Valorization of raw biomaterial waste-date stones-for Cr (VI) adsorption in aqueous solution: thermodynamics, kinetics and regeneration studies. Int Biodeterior Biodegrad. https://doi.org/10.1016/j.ibiod.2016.06.002

23.

Abbas AF, Ahmed MJ (2016) Mesoporous activated carbon from date stones (Phoenix dactylifera L.) by one-step microwave assisted K2CO3 pyrolysis. J Water Process Eng. https://doi.org/10.1016/j.jwpe.2016.01.004

24.

Danish M, Hashim R, Ibrahim MNM, Sulaiman O (2014) Optimized preparation for large surface area activated carbon from date (Phoenix dactylifera L.) stone biomass. Biomass Bioenergy. https://doi.org/10.1016/j.biombioe.2013.12.008

25.

Belhamdi B, Merzougui Z, Trari M, Addoun A (2016) A kinetic, equilibrium and thermodynamic study of L-phenylalanine adsorption using activated carbon based on agricultural waste (date stones). J Appl Res Technol. https://doi.org/10.1016/j.jart.2016.08.004CrossRef

26.

Danish M, Khanday WA, Hashim R et al (2017) Application of optimized large surface area date stone (Phoenix dactylifera) activated carbon for rhodamin B removal from aqueous solution: Box-Behnken design approach. Ecotoxicol Environ Saf. https://doi.org/10.1016/j.ecoenv.2017.02.001

27.

Al-Badri HT, Lafta SJ, Barbooti MM, Al-Sammerrai DA (1989) The thermogravimetry and pyrolysis of date stones. Thermochim Acta. https://doi.org/10.1016/0040-6031(89)85183-4

28.

Yarbay RZ, Figen HE, Baykara SZ (2012) Effects of cobalt and nickel substitution οn physical properties of perovskite type oxides prepared by the sol-gel citrate method. Acta Phys Pol A 121:44–46. https://doi.org/10.12693/APhysPolA.121.44CrossRef

29.

Guldal NO, Figen HE, Baykara SZ (2017) Production of hydrogen from hydrogen sulfide with perovskite type catalysts: LaMO3. Chem Eng J. https://doi.org/10.1016/j.cej.2016.11.057

30.

Zhang L, Zhang Y, Dai H et al (2010) Hydrothermal synthesis and catalytic performance of single-crystalline La2-xSrxCuO4 for methane oxidation. Catal Today. https://doi.org/10.1016/j.cattod.2010.02.059CrossRef

31.

Ifrah S, Kaddouri A, Gelin P, Leonard D (2007) Conventional hydrothermal process versus microwave-assisted hydrothermal synthesis of La1-xAgxMnO3+δ (x = 0, 0.2) perovskites used in methane combustion. Comptes Rendus Chim. https://doi.org/10.1016/j.crci.2007.08.002

32.

Adjaye JD, Bakhshi NN (1995) Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part II: Comparative catalyst performance and reaction pathways. Fuel Process Technol. https://doi.org/10.1016/0378-3820(95)00040-E

33.

Maisano S, Urbani F, Mondello N, Chiodo V (2017) Catalytic pyrolysis of Mediterranean Sea plant for bio-oil production. Int J Hydrog Energy. https://doi.org/10.1016/j.ijhydene.2017.07.124

34.

Özçimen D, Ersoy-Meriçboyu A (2010) Characterization of biochar and bio-oil samples obtained from carbonization of various biomass materials. Renew Energy. https://doi.org/10.1016/j.renene.2009.11.042

35.

Soleymani M, Moheb A, Joudaki E (2009) High surface area nano-sized La0.6Ca0.4 MnO3 perovskite powder prepared by low temperature pyrolysis of a modified citrate gel. Cent Eur J Chem. https://doi.org/10.2478/s11532-009-0083-2

36.

Campagnoli E, Tavares A, Fabbrini L et al (2005) Effect of preparation method on activity and stability of LaMnO 3 and LaCoO 3 catalysts for the flameless combustion of methane. Appl Catal B Environ. https://doi.org/10.1016/j.apcatb.2004.07.010

37.

Vaz T, Salker AV (2007) Preparation, characterization and catalytic CO oxidation studies on LaNi1-xCoxO3 system. Mater Sci Eng B Solid-State Mater Adv Technol. https://doi.org/10.1016/j.mseb.2007.07.027

38.

Makshina EV, Zhilinskaya EA, Aboukais A, Romanovskii BV (2007) Valence and coordination state of cobalt atoms in bulk and deposited lanthanum cobaltates. Mosc Univ Chem Bull. https://doi.org/10.3103/S0027131407010026

39.

Le Dréau L (2011) Phase transitions and oxygen ordering in La2CoO4+δ and (T, T’)-La2CuO4: single crystal growth and structural studies using synchrotron and neutron diffraction methods. PhD Dissertation. Université Rennes. https://tel.archives-ouvertes.fr/tel-00634848

40.

Guo J, Lou H, Zhu Y, Zheng X (2003) La-based perovskite precursors preparation and its catalytic activity for CO2 reforming of CH4. Mater Lett. https://doi.org/10.1016/S0167-577X(03)00341-0

41.

Kirchnerova J, Klvana D (1999) Synthesis and characterization of perovskite catalysts. Solid State Ionics. https://doi.org/10.1016/S0167-2738(99)00102-2

42.

Fidalgo A, Ciriminna R, Lopes L et al (2013) The sol-gel entrapment of noble metals in hybrid silicas: a molecular insight. Chem Cent J. https://doi.org/10.1186/1752-153X-7-161

43.

Keav S, Matam SK, Ferri D, Weidenkaff A (2014) Structured perovskite-based catalysts and their application as three-way catalytic converters-a review. Catalysts. https://doi.org/10.3390/catal4030226CrossRef

44.

Lesmana D, Wu HS (2015) Pyrolysis of waste oil in the presence of a spent catalyst. J Environ Chem Eng. https://doi.org/10.1016/j.jece.2015.09.019

45.

Song X, Wu Y, Cai F et al (2017) High-efficiency and low-cost li/ZnO catalysts for synthesis of glycerol carbonate from glycerol transesterification: the role of li and ZnO interaction. Appl Catal A Gen. https://doi.org/10.1016/j.apcata.2016.12.019

46.

Karagöz S, Kawakami T, Kako A et al (2016) Single shot pyrolysis and on-line conversion of lignocellulosic biomass with HZSM-5 catalyst using tandem micro-reactor-GC-MS. RSC Adv. https://doi.org/10.1039/c6ra04225b

47.

Karnjanakom S, Suriya-umporn T, Bayu A et al (2017) High selectivity and stability of mg-doped Al-MCM-41 for in-situ catalytic upgrading fast pyrolysis bio-oil. Energy Convers Manag. https://doi.org/10.1016/j.enconman.2017.03.049

48.

Sutton D, Kelleher B, Ross JRH (2001) Review of literature on catalysts for biomass gasification. Fuel Process Technol. https://doi.org/10.1016/S0378-3820(01)00208-9CrossRef

49.

Shadangi KP, Mohanty K (2014) Thermal and catalytic pyrolysis of Karanja seed to produce liquid fuel. Fuel. https://doi.org/10.1016/j.fuel.2013.07.053

50.

Vasalos IA, Lappas AA, Kopalidou EP, Kalogiannis KG (2016) Biomass catalytic pyrolysis: process design and economic analysis. Wiley Interdiscip Rev Energy Environ. https://doi.org/10.1002/wene.192

Titel: Effect of preparation method and B-side metal type on the physicochemical properties of LaBO3 perovskite catalyst and its catalytic behaviour in the biomass pyrolysis
verfasst von: Nurgül Özbay
Rahmiye Zerrin Yarbay Şahin
Publikationsdatum: 07.08.2020
Verlag: Springer Berlin Heidelberg
Erschienen in: Biomass Conversion and Biorefinery / Ausgabe 10/2022
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-020-00925-5

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 10/2022

Valorizing food wastes: assessment of novel yeast strains for enhanced production of single-cell protein from wasted date molasses

Real measurement of carbon monoxide, total suspended particulate, and thermal efficiency in modern biomass household boilers

Two-phase nutrient recovery from livestock wastewaters combining novel membrane technologies

Manure biostabilization by effective microorganisms as a way to improve its agronomic value

Valorisation of source-separated food waste to bioethanol: pilot-scale demonstration

Insights into influences of bamboo biochar on nitrous oxide emission and diazotrophs during cow manure and bagasse composting