Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
ATZ-Fachkongress

Chassis.tech plus 2024


4 Kongresse in einer Veranstaltung

Treffen Sie in München die Fachleute von Chassis, Lenkung, Bremsen sowie Reifen/Räder.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 4/2012

01.08.2012 | Original Paper

Effect of secondary forces in the compatibility of two incompatible biodegradable polymers

verfasst von: P. M. Chou, M. Mariatti, A. Zulkifli, M. Todo

Erschienen in: Polymer Bulletin | Ausgabe 4/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Poly(ethylene adipate) (PEA) and polytetramethylene ether glycol (PTMEG) were used as compatibilizers in the biodegradable polymer blend of poly(l-lactic acid)/poly(butylene succinate-co-l-lactate) (PLLA/PBSL). The compatibilizers of various contents were incorporated into the blend using a Haake internal mixer. The compatibilization between PEA and PTMEG on the blends was measured using thermogravimetric analysis (TGA), flexural test, field emission scanning electron microscopy (FESEM), and Fourier transform infrared (FTIR) spectroscopy. From the TGA results, it was found that the thermal stability of the blend improved with the addition of PEA. The flexural strength showed a dependency on the extent of the secondary forces interaction between PEA and PTMEG with the blends. This observation corresponded well with the FESEM micrographs. Based on the FTIR analysis, the physical interaction between PEA and PLLA/PBSL was due to the presence of secondary forces.
Vorheriger Artikel Synthesis and photovoltaic properties of 1-(2,6-diisopropylphenyl)-2,5-di(2-thienyl)pyrrole-based low-bandgap polymers
Nächster Artikel Surface tension of viscous biopolymer solutions measured using the du Nouy ring method and the drop weight methods

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Drumright RE, Gruber PR, Henton DE (2000) Polylactic acid technology. Adv Mater 12(23):1841–1846CrossRef
2.
Kulkarni RK, Moore EG, Hegyeli AF, Leonard F (1971) Biodegradable poly(lactic acid) polymers. J Biomed Mater Res 5(3):169–181CrossRef
3.
Peesan M, Supaphol P, Rujiravanit R (2005) Preparation and characterization of hexanoyl chitosan/polylactide blend films. Carbohydr Polym 60:343CrossRef
4.
Vilay V, Mariatti M, Zulkifli A, Pasomsouk K, Todo M (2009) Characterization of the mechanical and thermal properties and morphological behavior of biodegradable poly(l-lactide)/poly(ε-caprolactone) and poly(l-lactide)/poly(butylene succinate-co-l-lactate) polymeric blends. J Appl Polym Sci 114:1784–1792CrossRef
5.
Focarete M, Scandola M, Dobrzynski P, Kowalczuk M (2002) Miscibility and mechanical properties of blends of (l)-lactide copolymers with atactic Poly(3-hydroxybutyrate). Macromolecules 35(22):8472–8477CrossRef
6.
Ikehara T, Nishikawa Y, Nishi T (2003) Evidence for the formation of interpenetrated spherulites in poly(butylene succinate-co-butylene carbonate)/poly(l-lactic acid) blends investigated by atomic force microscopy. Polymer 44(21):6657–6661CrossRef
7.
Shibata M, Inoue Y, Miyoshi M (2006) Mechanical properties, morphology, and crystallization behavior of blends of poly(l-lactide) with poly(butylene succinate-co-l-lactate) and poly(butylene succinate). Polymer 47(10):3557–3564CrossRef
8.
Tsuji H, Muramatsu H (2001) Blends of aliphatic polyesters IV morphology, swelling behavior, and surface and bulk properties of blends from hydrophobic poly(l-lactide) and hydrophilic poly(vinyl alcohol). J Appl Polym Sci 81(9):2151–2160CrossRef
9.
Cao X, Mohamed A, Gordon SH, Willett JL, Sessa DJ (2003) DSC study of biodegradable poly(lactic acid) and poly(hydroxyl ester ether) blends. Thermochim Acta 406(1–2):115–127CrossRef
10.
Folkes MJ, Hope PS (1993) Polymer blends and alloys. Blackie Academic and Professional, LondonCrossRef
11.
Washiyama J, Kramer E, Hui C (1993) Fracture mechanisms of polymer interfaces reinforced with block copolymers: transition from chain pullout to crazing. Macromolecules 26(11):2928–2934CrossRef
12.
Horak Z, Hlavata D, Hromadkova J, Kotek J, Hasova V, Mikesova J, Pleska A (2002) Effect of selected structural parameters of styrene–butadiene block copolymers on their compatibilization efficiency in polystyrene/polybutadiene blends. J Polym Sci B 40(23):2612–2623CrossRef
13.
Heino M, Kirjava J, Hietaoja P, Seppala J (1997) Compatibilization of polyethylene terephthalate/polypropylene blends with styrene–ethylene/butylene–styrene (SEBS) block copolymers. J Appl Polym Sci 65(2):241–249CrossRef
14.
Shibata M, Teramoto N, Inoue Y (2007) Mechanical properties, morphologies, and crystallization behavior of plasticized poly(l-lactide)/poly(butylene succinate-co-l-lactate) blends. Polymer 48(9):2768–2777CrossRef
15.
Vilay V, Todo M, Takayama T, Mariatti M, Zulkifli A, Pasomsouk K (2009) Effects of lysine triisocyanate on the mode I fracture behavior of polymer blend of poly (l-lactic acid) and poly (butylene succinate-co-l-lactate). J Mater Sci 44(11):3006–3009CrossRef
16.
Vilay V, Mariatti M, Zulkifli A, Pasomsouk K, Todo M (2010) Effect of PEO–PPO–PEO copolymer on the mechanical and thermal properties and morphological behavior of biodegradable poly (l-lactic acid) (PLLA) and poly (butylene succinate-co-l-lactate) (PBSL) blends. Polym Adv Technol 22(12):1786–1793CrossRef
17.
Mekhilef N, Hadjiandreou P (1995) Miscibility behaviour of ethylene vinyl acetate/Novolac blends. Polymer 36(11):2165–2171CrossRef
18.
Shafee EE (2002) Studies on the miscibility and phase structure in blends of poly(epichlorohydrin) and poly(vinyl acetate). Polymer 43(3):921–927CrossRef
19.
Kim S, Kim H (2006) Study of miscibility of melamine-formaldehyde resin and poly(vinyl acetate) blends for use as adhesives in engineered flooring. J Adhesion Sci Technol 20:209–219CrossRef
20.
Naveen Kumar HMP, Prabhakar MN, Venkata Prasad C, Madhusudhan Rao K, Ashok Kumar Reddy TV, Chowdoji Rao K, Subha MCS (2010) Compatibility studies of chitosan/PVA blend in 2% aqueous acetic acid solution at 30 °C. Carbohydr Polym 82:251–255CrossRef
21.
Wong ACY, Lam F (2002) Material characterisation: study of selected thermal characteristics of polypropylene/polyethylene binary blends using DSC and TGA. Polym Test 21(6):691–696CrossRef
22.
Murariu M, Ferreira ADS, Pluta M, Bonnaud L, Alexandre M, Dubois P (2008) Polylactide (PLA)-CaSO4 composites toughened with low molecular weight and polymeric ester-like plasticizers and related performances. Eur Polym J 44:3842–3852CrossRef
23.
Sarazin P, Li G, Orts WL, Favis BD (2008) Binary and ternary blends of polylactide, polycaprolactone and thermoplastic starch. Polymer 49(2):599–609CrossRef
24.
Dong J, Ozaki Y (1997) FTIR and FT-Raman studies of partially miscible poly(methyl methacrylate)/poly(4-vinylphenol) blends in solid states. Macromolecules 30:286–292CrossRef
25.
Pardini OR, Amalvy JI (2008) FTIR, H-NMR spectra, and thermal characterization of water-based polyurethane/acrylic hybrids. J Appl Polym Sci 107:1207–1214CrossRef
26.
Nyquist RA (2001) Interpreting infrared, Raman, and nuclear magnetic resonance spectra: variables in data interpretation of infrared and Raman spectra. Academic Press, San Diego
Metadaten
Titel
Effect of secondary forces in the compatibility of two incompatible biodegradable polymers
verfasst von
P. M. Chou
M. Mariatti
A. Zulkifli
M. Todo
Publikationsdatum
01.08.2012
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 4/2012
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-012-0748-4

Weitere Artikel der Ausgabe 4/2012

Polymer Bulletin 4/2012 Zur Ausgabe

Original Paper

SET LRP of MMA mediated by Fe(0)/EDTA in the presence of air

Original Paper

Polymeric membranes composed of polystyrenes tethering amino acids for preferential CO2 separation over H2

Original Paper

Cyclopolymers from N,N-diallyl-N-propargyl-(12-N′-formylamino)-1-dodecylammonium chloride and their use as inhibitors for mild steel corrosion

Original Paper

Synthesis and characterization of hydrophobic long-chain fatty acylated cellulose and its self-assembled nanoparticles

Retraction Note

Retraction Note: Surface modification of aramid fibers with novel chemical approach

Original Paper

Synthesis and photovoltaic properties of 1-(2,6-diisopropylphenyl)-2,5-di(2-thienyl)pyrrole-based low-bandgap polymers

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise