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Cellulose

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01.11.2021 | Original Research

Effective degradation of cellulose by Microwave irradiation in alkaline solution

verfasst von: Lama Jabareen, Moorthy Maruthapandi, Arumugam Saravanan, Aharon Gedanken

Erschienen in: Cellulose | Ausgabe 18/2021

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Abstract

Lignocellulose biomass effectively produces chemicals and fuels, which are of importance for the establishment of a sustainable society. The conversion of cellulose, the main component of the biomass, into significant precursors that can be further converted to different chemicals or fuels under gentle conditions is a promising route. Organic acids such as acetic, glycolic and formic acid are significant examples. A novel method to produce important platform chemicals from micro-crystalline cellulose (MCC) was developed. MCC was degraded as a result of oxidation with potassium chlorate by microwave radiation in a one-pot procedure. Efficient reaction conditions such as short reaction time and full conversion of cellulose were identified. The reaction products were analyzed by ¹H and ¹³C NMR, XPS, TGA and XRD.

Vorheriger Artikel Synergetic effect of carbon dot at cellulose nanofiber for sustainable metal-free photocatalyst

Nächster Artikel Single fiber swelling behavior for natural and man-made cellulose fibers under alkaline treatment

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Aguilo A, Horlenko T (1980) Formic acid. Hydrocarb Process 59:120–130. https://doi.org/10.4324/9780429447341-40CrossRef

Al Shra’Ah A, Helleur R (2014) Microwave pyrolysis of cellulose at low temperature. J Anal Appl Pyrolysis 105:91–99. https://doi.org/10.1016/j.jaap.2013.10.007

Davaritouchaee M, Hiscox WC, Martinez-Fernandez J et al (2019) Effect of reactive oxygen species on biomass structure in different oxidative processes. Ind Crops Prod 137:484–494. https://doi.org/10.1016/j.indcrop.2019.05.063CrossRef

Delbecq F, Len C (2018) Recent advances in the microwave-assisted production of hydroxymethylfurfural by hydrolysis of cellulose derivatives—a review. Molecules. https://doi.org/10.3390/molecules23081973CrossRefPubMedPubMedCentral

Deng W, Zhang Q, Wang Y (2014) Catalytic transformations of cellulose and cellulose-derived carbohydrates into organic acids. Catal Today 234:31–41. https://doi.org/10.1016/j.cattod.2013.12.041CrossRef

Gromov NV, Taran OP, Delidovich IV et al (2016) Hydrolytic oxidation of cellulose to formic acid in the presence of Mo-V-P heteropoly acid catalysts. Catal Today 278:74–81. https://doi.org/10.1016/j.cattod.2016.03.030CrossRef

Heinze T, Koschella A (2005) Solvents applied in the field of cellulose chemistry: a mini review. Polímeros 15:84–90. https://doi.org/10.1590/s0104-14282005000200005CrossRef

Herrick RA, Lipták BG (2003) Carbon dioxide. Instrum Eng Handb Process Meas Anal Fourth Ed. https://doi.org/10.1016/b0-12-227090-8/00095-6CrossRef

Hussin MH, Husin NA, Bello I, et al (2018) Isolation of microcrystalline cellulose (MCC) from oil palm frond as potential natural filler for PVA-LiClO4 polymer electrolyte. Int J Electrochem Sci 13:3356–3371. https://doi.org/10.20964/2018.04.06

Isogai A, Atalla RH (1998) Dissolution of cellulose in aqueous NaOH solutions. Cellulose 5:309–319. https://doi.org/10.1023/A:1009272632367CrossRef

Isogai A, Hänninen T, Fujisawa S, Saito T (2018) Review: Catalytic oxidation of cellulose with nitroxyl radicals under aqueous conditions. Prog Polym Sci 86:122–148. https://doi.org/10.1016/j.progpolymsci.2018.07.007CrossRef

Li S, Deng W, Wang S et al (2018) Catalytic transformation of cellulose and its derivatives into functionalized organic acids. Chemsuschem 11:1995–2028. https://doi.org/10.1002/cssc.201800440CrossRefPubMed

Lin Y, Tanaka S (2006) Ethanol fermentation from biomass resources: current state and prospects. Appl Microbiol Biotechnol 69:627–642. https://doi.org/10.1007/s00253-005-0229-xCrossRefPubMed

Liu Z, Meng H, Li C et al (2020) Degradation of biologically treated coking wastewater over CuOx/PAC, CuOx/GAC, and CuOx/ACF catalysts under microwave irradiation in the presence of H2O2. J Environ Eng 146:04020014. https://doi.org/10.1061/(asce)ee.1943-7870.0001653CrossRef

Liu K, Du H, Zheng T et al (2021) Recent advances in cellulose and its derivatives for oilfield applications. Carbohydr Polym 259:117740. https://doi.org/10.1016/j.carbpol.2021.117740CrossRefPubMed

Lu T, Niu M, Hou Y et al (2016) Catalytic oxidation of cellulose to formic acid in H5PV2Mo10O40 + H2SO4 aqueous solution with molecular oxygen. Green Chem 18:4725–4732. https://doi.org/10.1039/c6gc01271jCrossRef

Lu T, Hou Y, Wu W et al (2018) Catalytic oxidation of cellulose to formic acid in V(V)-Fe(III)-H2SO4 aqueous solution with O2. Fuel Process Technol 173:197–204. https://doi.org/10.1016/j.fuproc.2018.02.001CrossRef

Milanovic JZ, Milosevic M, Jankovic-Castvan I et al (2021) Capillary rise and sorption ability of hemp fibers oxidized by non-selective oxidative agents: hydrogen peroxide and potassium permanganate. J Nat Fibers 16:1–6. https://doi.org/10.1080/15440478.2020.1870609CrossRef

Motasemi F, Afzal MT (2013) A review on the microwave-assisted pyrolysis technique. Renew Sustain Energy Rev 28:317–330. https://doi.org/10.1016/j.rser.2013.08.008CrossRef

Newman RH, Davies LM, Harris PJ (1996) Solid-state 13C nuclear magnetic resonance characterization of cellulose in the cell walls of Arabidopsis thaliana leaves. Plant Physiol 111:475–485. https://doi.org/10.1104/pp.111.2.475CrossRefPubMedPubMedCentral

Okushita K, Komatsu T, Chikayama E et al (2012) Statistical approach for solid-state NMR spectra of cellulose derived from a series of variable parameters. Polym J 44:895–900. https://doi.org/10.1038/pj.2012.82CrossRef

Pang Q, Wang L, Yang H et al (2014) Cellulose-derived carbon bearing–Cl and–SO 3 H groups as a highly selective catalyst for the hydrolysis of cellulose to glucose. RSC Adv 4:41212–41218CrossRef

Peroxide H, Kelly MT, Blaise A, et al (2019) Permanganate food and nutritional analy—sis|wine physical and chemical treatment processes for leachate redox transformations spectrophotometry|inorganic compounds fundamentals: ligands, complexes, synthesis, purification, and structure secondar

Rosli N, Ambak K, Daniel BD et al (2015) Jurnal Teknologi 1:1–6

Sugano Y, Kumar N, Peurla M et al (2016) Specific electrocatalytic oxidation of cellulose at carbon electrodes modified by gold nanoparticles. ChemCatChem 8:2401–2405. https://doi.org/10.1002/cctc.201600190CrossRef

Sundarraj AA, Ranganathan TV (2018) A review on cellulose and its utilization from agro-industrial waste. Drug Invent Today 10:89–94

Tao Y, Teng C, Musho TD et al (2021) Direct measurement of the selective microwave-induced heating of agglomerates of dipolar molecules: the origin of and parameters controlling a microwave specific superheating effect. J Phys Chem B 125:2146–2156. https://doi.org/10.1021/acs.jpcb.0c10291CrossRefPubMed

Toshikj E, Tarbuk A, Grgić K et al (2019) Influence of different oxidizing systems on cellulose oxidation level: introduced groups versus degradation model. Cellulose 26:777–794. https://doi.org/10.1007/s10570-018-2133-4CrossRef

Wang X, Chen H, Luo K et al (2008) The influence of microwave drying on biomass pyrolysis. Energy Fuels 22:67–74. https://doi.org/10.1021/ef700300mCrossRef

Wang T, Park YB, Caporini MA et al (2013a) Sensitivity-enhanced solid-state NMR detection of expansin’s target in plant cell walls. Proc Natl Acad Sci 110:16444–16449. https://doi.org/10.1073/pnas.1316290110CrossRefPubMedPubMedCentral

Wang Z-L, Yan J-M, Ping Y et al (2013b) An efficient CoAuPd/C catalyst for hydrogen generation from formic acid at room temperature. Angew Chemie 125:4502–4505. https://doi.org/10.1002/ange.201301009CrossRef

Wang G, Meng Y, Zhou J, Zhang L (2018a) Selective hydrothermal degradation of cellulose to formic acid in alkaline solutions. Cellulose 25:5659–5668. https://doi.org/10.1007/s10570-018-1979-9CrossRef

Wang M, Ma J, Liu H et al (2018b) sustainable productions of organic acids and their derivatives from biomass via selective oxidative cleavage of C–C bond. ACS Catal 8:2129–2165. https://doi.org/10.1021/acscatal.7b03790CrossRef

Zacharska M, Podyacheva OY, Kibis LS et al (2015) Ruthenium clusters on carbon nanofibers for formic acid decomposition: effect of doping the support with nitrogen. ChemCatChem 7:2910–2917. https://doi.org/10.1002/cctc.201500216CrossRef

Zhang S, Metin Ö, Su D, Sun S (2013) Monodisperse AgPd alloy nanoparticles and their superior catalysis for the dehydrogenation of formic acid. Angew Chemie - Int Ed 52:3681–3684. https://doi.org/10.1002/anie.201300276CrossRef

Zhou L, Li N, Shu J et al (2018) One-pot preparation of carboxylated cellulose nanocrystals and their liquid crystalline behaviors. ACS Sustain Chem Eng 6:12403–12410. https://doi.org/10.1021/acssuschemeng.8b02926CrossRef

Titel: Effective degradation of cellulose by Microwave irradiation in alkaline solution
verfasst von: Lama Jabareen
Moorthy Maruthapandi
Arumugam Saravanan
Aharon Gedanken
Publikationsdatum: 01.11.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 18/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04274-y

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