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Biomass Conversion and Biorefinery
Erschienen in: Biomass Conversion and Biorefinery 7/2023

08.06.2021 | Original Article

Efficiency of eggshell as a low-cost adsorbent for removal of cadmium: kinetic and isotherm studies

verfasst von: Kahina Annane, Wahiba Lemlikchi, Sophie Tingry

Erschienen in: Biomass Conversion and Biorefinery | Ausgabe 7/2023

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Abstract

Eggshell (ES) is an alternative source of calcium carbonate that efficiently removes heavy metals in aqueous solution. The adsorption capacity of ES depends on their physico-chemical properties and the influence of experimental conditions, but in the majority of reports, not all the reaction parameters related to adsorption process of heavy metals are available, and the adsorption mechanism is not systematically studied. In this contribution, the use of ES waste is reported to establish an overall performance trend of the experimental parameters on cadmium ion (Cd2+) adsorption from an aqueous solution. Different physicochemical techniques Brunauer–Emmett–Teller (BET), Fourier-transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), thermogravimetric analysis (TGA), and X-ray diffraction (XRD) are used to characterize the physico-chemical properties of ES and the adsorption performance is studied as a function of contact time, pH, concentration, and adsorbent dosage. The highest adsorption capacity, 217.4 mg.g−1, obtained in 10 min at an initial pH = 5 with an adsorbent dose of 0.8 g.L−1, is mainly attributed to the high specific surface area of the eggshell used in this work. Adsorption kinetics are described by the pseudo-second-order model, in good agreement with the experimental data, and the sorption mechanism follows the isotherm model of Langmuir, characterized by the chemical adsorption of a homogeneous monolayer of Cd2+ on the surface of ES adsorbents. The desorption efficiency of cadmium ions is efficient in the presence of nitric acid. The outcomes provided by the study confirm the use of eggshell as an effective and inexpensive material, offering high efficiency for cadmium removal.

Graphical abstract

Vorheriger Artikel Experimental study on char production from the pyrolysis of biomass
Nächster Artikel Anaerobic digestion of elephant camp–derived wastes: methane potential, kinetic study, and biorefinery platform

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Metadaten
Titel
Efficiency of eggshell as a low-cost adsorbent for removal of cadmium: kinetic and isotherm studies
verfasst von
Kahina Annane
Wahiba Lemlikchi
Sophie Tingry
Publikationsdatum
08.06.2021
Verlag
Springer Berlin Heidelberg
Erschienen in
Biomass Conversion and Biorefinery / Ausgabe 7/2023
Print ISSN: 2190-6815
Elektronische ISSN: 2190-6823
DOI
https://doi.org/10.1007/s13399-021-01619-2

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