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Erschienen in: Polymer Bulletin 7/2019

12.10.2018 | Original Paper

Efficient polymeric phosphorus flame retardant: flame retardancy, thermal property, and physical property on polylactide

verfasst von: Min-Ji Sim, Sang-Ho Cha

Erschienen in: Polymer Bulletin | Ausgabe 7/2019

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Abstract

A novel polymeric flame retardant, PBPP2, for polylactide (PLA) was synthesized via a two-step polymerization process. The flame retardancy of neat PLA and flame-retarded PLA films prepared via solution casting method with different PBPP2 ratios was then investigated. When only the 3 wt% PBPP2 was added to PLA, the limiting oxygen index was increased from 23 to 30%. Additionally, the required V-0 rating was achieved compared to neat PLA. It was also found that PBPP2 increases the maximum thermal decomposition temperature of PLA, indicating that 3 wt% of PBPP2 is sufficient to improve flame retardancy and thermal stability on PLA, simultaneously. From both the decrease in Tm and the increase in elongation for PLA with the 3 wt% addition of PBPP2, PBPP2 could be considered to also function as a plasticizer on PLA.

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Metadaten
Titel
Efficient polymeric phosphorus flame retardant: flame retardancy, thermal property, and physical property on polylactide
verfasst von
Min-Ji Sim
Sang-Ho Cha
Publikationsdatum
12.10.2018
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2019
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-018-2558-9

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