Skip to main content
Erschienen in: Journal of Materials Science 7/2017

19.12.2016 | Original Paper

Efficient strategy of chlorine-assisted liquid-phase exfoliation of graphite

verfasst von: Xiao-Feng Tang, Zhen-Guo Yang, Jia-Hui Liang

Erschienen in: Journal of Materials Science | Ausgabe 7/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A large-scale, inexpensive, and facile strategy has been successfully developed for preparation of high-quality graphene nanosheets by combining electron-absorbing materials and chorine in N-methyl-2-pyrrolidone. The as-obtained graphene sheets were proven to contain low levels of naturally absorbed oxygen inherited from the starting graphite by Fourier transform infrared spectroscopy, Raman spectroscopy, thermogravimetric analysis, and X-ray diffraction. Meanwhile, the structure of produced graphene sheets was further characterized using scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. Compared to the previous techniques, this eco-friendly approach demonstrates obvious advantages, such as low cost and simplicity, which could be an alternative method to prepare graphene-based composites for the potential applications in the near future.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Kozbial A, Li Z, Conaway C, McGinley R, Dhingra S, Vahdat V, Zhou F, D’Urso B, Liu H, Li L (2014) Study on the surface energy of graphene by contact angle measurements. Langmuir 30:8598–8606CrossRef Kozbial A, Li Z, Conaway C, McGinley R, Dhingra S, Vahdat V, Zhou F, D’Urso B, Liu H, Li L (2014) Study on the surface energy of graphene by contact angle measurements. Langmuir 30:8598–8606CrossRef
2.
Zurück zum Zitat Khan U, O’Neill A, Lotya M, De S, Coleman JN (2010) High-concentration solvent exfoliation of graphene. Small 6:864–871CrossRef Khan U, O’Neill A, Lotya M, De S, Coleman JN (2010) High-concentration solvent exfoliation of graphene. Small 6:864–871CrossRef
3.
Zurück zum Zitat Qian W, Hao R, Hou Y, Tian Y, Shen C, Gao H, Liang X (2009) Solvothermal-assisted exfoliation process to produce graphene with high yield and high quality. Nano Res 2:706–712CrossRef Qian W, Hao R, Hou Y, Tian Y, Shen C, Gao H, Liang X (2009) Solvothermal-assisted exfoliation process to produce graphene with high yield and high quality. Nano Res 2:706–712CrossRef
4.
Zurück zum Zitat Green AA, Hersam MC (2009) Solution phase production of graphene with controlled thickness via density differentiation. Nano Lett 9:4031–4036CrossRef Green AA, Hersam MC (2009) Solution phase production of graphene with controlled thickness via density differentiation. Nano Lett 9:4031–4036CrossRef
5.
Zurück zum Zitat Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun Z, De S, McGovern IT, Holland B, Byrne M, Gun’Ko YK, Boland JJ, Niraj P, Duesberg G, Krishnamurthy S, Goodhue R, Hutchison J, Scardaci V, Ferrari AC, Coleman JN (2008) High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol 3:563–568CrossRef Hernandez Y, Nicolosi V, Lotya M, Blighe FM, Sun Z, De S, McGovern IT, Holland B, Byrne M, Gun’Ko YK, Boland JJ, Niraj P, Duesberg G, Krishnamurthy S, Goodhue R, Hutchison J, Scardaci V, Ferrari AC, Coleman JN (2008) High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol 3:563–568CrossRef
6.
Zurück zum Zitat Nuvoli D, Valentini L, Alzari V, Scognamillo S, Bon SB, Piccinini M, Illescas J, Mariani A (2011) High concentration few-layer graphene sheets obtained by liquid phase exfoliation of graphite in ionic liquid. J Mater Chem 21:3428–3431CrossRef Nuvoli D, Valentini L, Alzari V, Scognamillo S, Bon SB, Piccinini M, Illescas J, Mariani A (2011) High concentration few-layer graphene sheets obtained by liquid phase exfoliation of graphite in ionic liquid. J Mater Chem 21:3428–3431CrossRef
7.
Zurück zum Zitat Liu Y-T, Xie X-M, Ye X-Y (2011) High-concentration organic solutions of poly(styrene-co-butadiene-co-styrene)-modified graphene sheets exfoliated from graphite. Carbon 49:3529–3537CrossRef Liu Y-T, Xie X-M, Ye X-Y (2011) High-concentration organic solutions of poly(styrene-co-butadiene-co-styrene)-modified graphene sheets exfoliated from graphite. Carbon 49:3529–3537CrossRef
8.
Zurück zum Zitat Zhu Y, Tour JM (2010) Graphene nanoribbon thin films using layer-by-layer assembly. Nano Lett 10:4356–4362CrossRef Zhu Y, Tour JM (2010) Graphene nanoribbon thin films using layer-by-layer assembly. Nano Lett 10:4356–4362CrossRef
9.
Zurück zum Zitat Liu W, Zhou R, Zhou D, Ding G, Soah JM, Yue CY, Lu X (2015) Lignin-assisted direct exfoliation of graphite to graphene in aqueous media and its application in polymer composites. Carbon 83:188–197CrossRef Liu W, Zhou R, Zhou D, Ding G, Soah JM, Yue CY, Lu X (2015) Lignin-assisted direct exfoliation of graphite to graphene in aqueous media and its application in polymer composites. Carbon 83:188–197CrossRef
10.
Zurück zum Zitat Chen Z, Yan H, Liu T, Niu S, Ma J (2015) Improved mechanical and tribological properties of bismaleimide composites by surface-functionalized reduced graphene oxide and MoS2 coated with cyclotriphosphazene polymer. RSC Adv 5:97883–97890CrossRef Chen Z, Yan H, Liu T, Niu S, Ma J (2015) Improved mechanical and tribological properties of bismaleimide composites by surface-functionalized reduced graphene oxide and MoS2 coated with cyclotriphosphazene polymer. RSC Adv 5:97883–97890CrossRef
11.
Zurück zum Zitat Parvez K, Wu Z-S, Li R, Liu X, Graf R, Feng X, Müllen K (2014) Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. J Am Chem Soc 136:6083–6091CrossRef Parvez K, Wu Z-S, Li R, Liu X, Graf R, Feng X, Müllen K (2014) Exfoliation of graphite into graphene in aqueous solutions of inorganic salts. J Am Chem Soc 136:6083–6091CrossRef
12.
Zurück zum Zitat Lotya M, Hernandez Y, King PJ, Smith RJ, Nicolosi V, Karlsson LS, Blighe FM, De S, Wang Z, McGovern IT, Duesberg GS, Coleman JN (2009) Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions. J Am Chem Soc 131:3611–3620CrossRef Lotya M, Hernandez Y, King PJ, Smith RJ, Nicolosi V, Karlsson LS, Blighe FM, De S, Wang Z, McGovern IT, Duesberg GS, Coleman JN (2009) Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions. J Am Chem Soc 131:3611–3620CrossRef
13.
Zurück zum Zitat Posudievsky OY, Khazieieva OA, Cherepanov VV, Dovbeshko GI, Shkavro AG, Koshechko VG, Pokhodenko VD (2013) Improved dispersant-free liquid exfoliation down to the graphene-like state of solvent-free mechanochemically delaminated bulk MoS2. J Mater Chem C 1:6411–6415CrossRef Posudievsky OY, Khazieieva OA, Cherepanov VV, Dovbeshko GI, Shkavro AG, Koshechko VG, Pokhodenko VD (2013) Improved dispersant-free liquid exfoliation down to the graphene-like state of solvent-free mechanochemically delaminated bulk MoS2. J Mater Chem C 1:6411–6415CrossRef
14.
Zurück zum Zitat Du W, Jiang X, Zhu L (2013) From graphite to graphene: direct liquid-phase exfoliation of graphite to produce single- and few-layered pristine graphene. J Mater Chem A 1:10592–10606CrossRef Du W, Jiang X, Zhu L (2013) From graphite to graphene: direct liquid-phase exfoliation of graphite to produce single- and few-layered pristine graphene. J Mater Chem A 1:10592–10606CrossRef
15.
Zurück zum Zitat Ciesielski A, Samori P (2014) Graphene via sonication assisted liquid-phase exfoliation. Chem Soc Rev 43:381–398CrossRef Ciesielski A, Samori P (2014) Graphene via sonication assisted liquid-phase exfoliation. Chem Soc Rev 43:381–398CrossRef
16.
Zurück zum Zitat Ma J, Cai P, Qi W, Kong D, Wang H (2013) The layer-by-layer assembly of polyelectrolyte functionalized graphene sheets: a potential tool for biosensing. Coll Surf A 426:6–11CrossRef Ma J, Cai P, Qi W, Kong D, Wang H (2013) The layer-by-layer assembly of polyelectrolyte functionalized graphene sheets: a potential tool for biosensing. Coll Surf A 426:6–11CrossRef
17.
Zurück zum Zitat Bouša D, Luxa J, Mazánek V, Jankovský O, Sedmidubský D, Klĺmová K, Pumerab M, Sofer Z (2016) Toward graphene chloride: chlorination of graphene and graphene oxide. RSC Adv 6:66884–66892CrossRef Bouša D, Luxa J, Mazánek V, Jankovský O, Sedmidubský D, Klĺmová K, Pumerab M, Sofer Z (2016) Toward graphene chloride: chlorination of graphene and graphene oxide. RSC Adv 6:66884–66892CrossRef
18.
Zurück zum Zitat Poh HL, Šimek P, Sofer Z, Pumera M (2013) Halogenation of graphene with chlorine, bromine, or iodine by exfoliation in a halogen atmosphere. Chem Eur J 19:2655–2662CrossRef Poh HL, Šimek P, Sofer Z, Pumera M (2013) Halogenation of graphene with chlorine, bromine, or iodine by exfoliation in a halogen atmosphere. Chem Eur J 19:2655–2662CrossRef
19.
Zurück zum Zitat Vineesh TV, Nazrulla MA, Krishnamoorthy S, Narayanan TN, Alwarappan S (2015) Synergistic effects of dopants on the spin density of catalytic active centres of N-doped fluorinated graphene for oxygen reduction reaction. Appl Mater Today 1:74–79CrossRef Vineesh TV, Nazrulla MA, Krishnamoorthy S, Narayanan TN, Alwarappan S (2015) Synergistic effects of dopants on the spin density of catalytic active centres of N-doped fluorinated graphene for oxygen reduction reaction. Appl Mater Today 1:74–79CrossRef
Metadaten
Titel
Efficient strategy of chlorine-assisted liquid-phase exfoliation of graphite
verfasst von
Xiao-Feng Tang
Zhen-Guo Yang
Jia-Hui Liang
Publikationsdatum
19.12.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0600-6

Weitere Artikel der Ausgabe 7/2017

Journal of Materials Science 7/2017 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.