nach oben

Erschienen in:

23.09.2021 | Original Research

Egg white protein-hypophosphorous acid-based fire retardant single bilayer coating assembly for cotton fabrics

verfasst von: Ajay Vishwakarma, Vennapusa Jagadeeswara Reddy, Baljinder K. Kandola, Vivek Kumar, Aravind Dasari, Sujay Chattopadhyay

Erschienen in: Cellulose | Ausgabe 16/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

The combination of egg white proteins (W) and hypophosphorous acid (HA) was used for developing a flame retardant coating for cotton fabrics by adopting the layer-by-layer assembly technique. This has resulted in a novel phosphorous-nitrogen-based assembly due to strong electrostatic interactions between W and HA. Coated cotton fabrics were characterized by using a variety of microscopic, analytical and thermal/combustion tests. Flammability properties of the fabrics were evaluated as per widely recognized standards like BS EN ISO 15025:2016 for protective clothing and ASTM D6413 for flame resistance of textiles. Coated cotton fabric showed self-extinguishing property with significant but fragile residual char structure, whereas uncoated fabric completely burnt with a little ash as residue. Thermogravimetric analysis revealed that decomposition temperature of coated fabric was lowered compared to control fabric, but char residue increased at 800 °C. Forced combustion cone calorimeter tests on the coated and uncoated fabrics showed that peak heat release rate, total heat released, and average rate of heat emission values reduced by 80%, 38%, and 40%, respectively, for coated fabrics as compared to control fabric. Even the mass loss rate value of the coated fabric has reduced significantly (from 514 g/m².s for the uncoated fabric to 2 g/m².s for coated fabric). Wash durability of the coated fabrics, though showed a slight reduction in flame-retardant properties as a consequence of ~ 9.7 wt% coating loss during soaking, yet there was no after-glow.

Graphic abstract

Vorheriger Artikel Environmental method for preparation of higher color strength dyeing cotton fabrics with colored nanosilica pigment

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Abou-Okeil A, El-Sawy SM, Abdel-Mohdy FA (2013) Flame retardant cotton fabrics treated with organophosphorus polymer. Carbohydr Polym 92:2293–2298. https://doi.org/10.1016/j.carbpol.2012.12.008CrossRefPubMed

Alongi J, Carletto RA, Bosco F et al (2014) Caseins and hydrophobins as novel green flame retardants for cotton fabrics. Polym Degrad Stab 99:111–117. https://doi.org/10.1016/j.polymdegradstab.2013.11.016CrossRef

Annalisa C, Francesca B, Giulio M et al (2016) DNA-chitosan crosslinking and photografting to cotton fabrics to improve washing fastness of the fire-resistant finishing. Cellulose 23:3963–3984. https://doi.org/10.1007/s10570-016-1067-yCrossRef

Bergbreiter DE, Tao G, Franchina JG, Sussman L (2001) Polyvalent hydrogen-bonding functionalization of ultrathin hyperbranched films on polyethylene and gold. Macromolecules 34:3018–3023. https://doi.org/10.1021/ma000873dCrossRef

Bosco F, Andrea R, Alongi J et al (2013) Thermal stability and flame resistance of cotton fabrics treated with whey proteins. Carbohydr Polym 94:372–377. https://doi.org/10.1016/j.carbpol.2012.12.075CrossRefPubMed

Bosco F, Casale A, Mollea C et al (2015) DNA coatings on cotton fabrics: effect of molecular size and pH on flame retardancy. Surf Coatings Technol 272:86–95. https://doi.org/10.1016/j.surfcoat.2015.04.019CrossRef

Braun U, Bahr H, Sturm H, Schartel B (2008) Flame retardancy mechanisms of metal phosphinates and metal phosphinates in combination with melamine cyanurate in glass-fiber reinforced poly (1, 4-butylene terephthalate ): the influence of metal cation. Polym Adv Technol. https://doi.org/10.1002/pat.1147CrossRef

Carosio F, Di Blasio A, Alongi J, Malucelli G (2013) Green DNA-based flame retardant coatings assembled through layer by layer. Polymer (guildf) 54:5148–5153. https://doi.org/10.1016/j.polymer.2013.07.029CrossRef

Carosio F, Fontaine G, Alongi J, Bourbigot S (2015) Starch-based layer by layer assembly: efficient and sustainable approach to cotton fire protection. ACS Appl Mater Interfaces 7:12158–12167. https://doi.org/10.1021/acsami.5b02507CrossRefPubMed

Cheng XW, Guan JP, Yang XH et al (2019) A bio-resourced phytic acid/chitosan polyelectrolyte complex for the flame retardant treatment of wool fabric. J Clean Prod 223:342–349. https://doi.org/10.1016/j.jclepro.2019.03.157CrossRef

Chung C, Lee M, Choe EK (2004) Characterization of cotton fabric scouring by FT-IR ATR spectroscopy. Carbohydr Polym 58:417–420. https://doi.org/10.1016/j.carbpol.2004.08.005CrossRef

Decher G, Hong JD (1991) Buildup of ultrathin multilayer films by a self-assembly process: ii. consecutive adsorption of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces. Berichte Der Bunsengesellschaft Für Phys Chemie 95:1430–1434. https://doi.org/10.1002/bbpc.19910951122CrossRef

Evarts B (2019) Fire loss in the United States during 2018. Natl Fire Prot Assoc USA October 2019

Gallo E, Braun U, Schartel B et al (2009) Halogen-free flame retarded poly ( butylene terephthalate) (PBT) using metal oxides/PBT nanocomposites in combination with aluminium phosphinate. Polym Degrad Stab 94:1245–1253. https://doi.org/10.1016/j.polymdegradstab.2009.04.014CrossRef

Legler J, Brouwer A (2003) Are brominated flame retardants endocrine disruptors? Environ Int 29:879–885. https://doi.org/10.1016/S0160-4120(03)00104-1CrossRefPubMed

Li Y, Schulz J, Mannen S et al (2010) Flame retardant behavior of polyelectrolyte—clay thin film assemblies on cotton fabric. ACS Nano 4:3325–3337. https://doi.org/10.1021/nn100467eCrossRefPubMed

Lin D, Zeng X, Li H et al (2019) One-pot fabrication of superhydrophobic and flame-retardant coatings on cotton fabrics via sol-gel reaction. J Colloid Interface Sci 533:198–206. https://doi.org/10.1016/j.jcis.2018.08.060CrossRefPubMed

Liu L, Pan Y, Wang Z et al (2017) Layer-by-layer assembly of hypophosphorous acid-modified chitosan based coating for flame-retardant polyester-cotton blends. Ind Eng Chem Res 56:9429–9436. https://doi.org/10.1021/acs.iecr.7b02303CrossRef

Liu X, Zhang Q, Peng B et al (2020) Flame retardant cellulosic fabrics via layer-by-layer self-assembly double coating with egg white protein and phytic acid. J Clean Prod 243:118641. https://doi.org/10.1016/j.jclepro.2019.118641CrossRef

Malucelli G, Carosio F, Alongi J et al (2014) Materials engineering for surface-confined flame retardancy. Mater Sci Eng R Rep 84:1–20. https://doi.org/10.1016/j.mser.2014.08.001CrossRef

Nielsen GD, Wolkoff P (2010) Cancer effects of formaldehyde: a proposal for an indoor air guideline value. Arch Toxicol 84:423–446. https://doi.org/10.1007/s00204-010-0549-1CrossRefPubMedPubMedCentral

Oatway L, Vasanthan T, Helm JH (2001) Phytic acid. Food Rev Int 17:419–431. https://doi.org/10.1081/FRI-100108531CrossRef

Pan H, Song L, Ma L et al (2014) Layer-by-layer assembled thin films based on fully biobased polysaccharides: Chitosan and phosphorylated cellulose for flame-retardant cotton fabric. Cellulose 21:2995–3006. https://doi.org/10.1007/s10570-014-0276-5CrossRef

Pan Y, Liu L, Zhang Y et al (2019) Effect of genipin crosslinked layer-by-layer self-assembled coating on the thermal stability, flammability and wash durability of cotton fabric. Carbohydr Polym 206:396–402. https://doi.org/10.1016/j.carbpol.2018.11.037CrossRefPubMed

Priolo MA, Gamboa D, Grunlan JC (2010) Transparent clay-polymer nano brick wall assemblies with tailorable oxygen barrier. ACS Appl Mater Interfaces 2:312–320. https://doi.org/10.1021/am900820kCrossRef

Qiu X, Li Z, Li X, Zhang Z (2018) Flame retardant coatings prepared using layer by layer assembly: a review. Chem Eng J 334:108–122. https://doi.org/10.1016/j.cej.2017.09.194CrossRef

Rahman F, Langford KH, Scrimshaw MD, Lester JN (2001) Polybrominated diphenyl ether (PBDE) flame retardants. Sci Total Environ 275:1–17. https://doi.org/10.1016/S0048-9697(01)00852-XCrossRefPubMed

Rehan M, El-Naggar ME, Mashaly HM, Wilken R (2018) Nanocomposites based on chitosan/silver/clay for durable multi-functional properties of cotton fabrics. Carbohydr Polym 182:29–41. https://doi.org/10.1016/j.carbpol.2017.11.007CrossRefPubMed

Shariatinia Z, Javeri N, Shekarriz S (2015) Flame retardant cotton fibers produced using novel synthesized halogen-free phosphoramide nanoparticles. Carbohydr Polym 118:183–198. https://doi.org/10.1016/j.carbpol.2014.11.039CrossRefPubMed

Shimazaki Y, Mitsuishi M, Ito S, Yamamoto M (1997) Preparation of the layer-by-layer deposited ultrathin film based on the charge-transfer interaction. Langmuir 13:1385–1387. https://doi.org/10.1021/la9609579CrossRef

Sun J, Wu T, Liu F et al (2000) Covalently attached multilayer assemblies by sequential adsorption of polycationic diazo-resins and polyanionic poly(acrylic acid). Langmuir 16:4620–4624. https://doi.org/10.1021/la991482zCrossRef

Vakhitova L, Drizhd V, Taran N et al (2016) The effect of organoclays on the fire-proof efficiency of intumescent coatings. Eastern-Eur J Enterp Technol 6:10–16. https://doi.org/10.15587/1729-4061.2016.84391CrossRef

van der Veen I, de Boer J (2012) Phosphorus flame retardants: Properties, production, environmental occurrence, toxicity and analysis. Chemosphere 88:1119–1153. https://doi.org/10.1016/j.chemosphere.2012.03.067CrossRefPubMed

Wang YW, Shen R, Wang Q, Vasquez Y (2018) ZnO microstructures as flame-retardant coatings on cotton fabrics. ACS Omega 3:6330–6338. https://doi.org/10.1021/acsomega.8b00371CrossRefPubMedPubMedCentral

Wu K, Wang Z (2008) Intumescent flame retardation of EVA using microencapsulated ammonium polyphosphate and pentaerythritols. Polym Plast Technol Eng 47:247–254. https://doi.org/10.1080/03602550701866733CrossRef

Xiong Z, Zhang Y, Du X et al (2019) Green and Scalable fabrication of core-shell biobased flame retardants for reducing flammability of polylactic acid. ACS Sustain Chem Eng 7:8954–8963. https://doi.org/10.1021/acssuschemeng.9b01016CrossRef

Yang CQ, Chen D, Guan J, He Q (2010) Crosslinking cotton cellulose by the combination of maleic acid and sodium hypophosphite. 1. Fabric wrinkle resistance. Ind Eng Chem Res 49:8325–8332. https://doi.org/10.1021/ie1007294CrossRef

Yu X, Pan Y, Wang D et al (2017) Fabrication and properties of biobased layer-by-layer coated ramie fabric-reinforced unsaturated polyester resin composites. Ind Eng Chem Res 56:4758–4767. https://doi.org/10.1021/acs.iecr.7b00101CrossRef

Yuan H, Xing W, Zhang P et al (2012) Functionalization of cotton with UV-cured flame retardant coatings. Ind Eng Chem Res 51:5394–5401. https://doi.org/10.1021/ie202468uCrossRef

Zhang XLY, Ren BCY, Chen QZ et al (2018) Preparation of durable and flame retardant lyocell fibers by a one-pot chemical treatment. Cellulose 25:6745–6758. https://doi.org/10.1007/s10570-018-2005-yCrossRef

Titel: Egg white protein-hypophosphorous acid-based fire retardant single bilayer coating assembly for cotton fabrics
verfasst von: Ajay Vishwakarma
Vennapusa Jagadeeswara Reddy
Baljinder K. Kandola
Vivek Kumar
Aravind Dasari
Sujay Chattopadhyay
Publikationsdatum: 23.09.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 16/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-04208-8

Springer Professional

Abstract

Graphic abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 16/2021

Application of enzyme technology in biopulping and biobleaching

Synergetic effect of cationic starch (ether/ester) and Pluronics for improving inkjet printing quality of office papers

Preparation of cellulose-based fluorescent materials as coating pigment by use of DMSO/DBU/CO2 system

Controllable Fe ion-anchored graphene heterostructures for robust and highly thermal conductive cellulose nanofiber composites

Confocal analysis of cellulose nanocrystal (CNC) based hydrogels and suspensions

Structural properties of cellulose nanofibril foam depending on wet foaming conditions in Pickering stabilization