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Colloid and Polymer Science

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11.10.2023 | Research

Encapsulation of ultraviolet filter into cationic polystyrene particles via miniemulsion polymerization with poly(vinyl alcohol)

verfasst von: Takashi Yamazaki, Minori Shimizu, Sayuri Yamada, Rina Kanda, Toshikazu Tsuji

Erschienen in: Colloid and Polymer Science | Ausgabe 1/2024

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Abstract

In this study, diethylamino hydroxybenzoyl hexyl benzoate (DHHB)-encapsulated cationic polystyrene particles (PS-DHHB) were synthesized and dispersed in water using miniemulsion polymerization. Low-molecular-weight poly(vinyl alcohol) was employed as an emulsifier, facilitating both the formation of monomer droplets and the subsequent polymerization process. Importantly, the inclusion of polystyrene (PS) in the monomer droplet increased the solid content and acted as a stabilizing agent, thereby enhancing the encapsulation efficiency of DHHB. The synthesized PS-DHHB particles exhibited ultraviolet (UV) absorption properties closely akin to those of DHHB. Additionally, the introduction of aqueous alcohol, used as an antibacterial agent, did not lead to the leaching of DHHB from the PS-DHHB particles. The study further revealed that PS-DHHB adhered more effectively to hair compared to anionic PS-DHHB and was superior in mitigating UV-induced hair protein loss in the 320–400 nm range compared to cationic PS particles without DHHB. In summary, the study resulted in the development of water-dispersible PS-DHHB particles with significant applications in polymer science and cosmetics, owing to their efficient UV absorption and effective hair adhesion capabilities.

Vorheriger Artikel The effects of a phosphorus/nitrogen-containing diphenol on the flammability, thermal stability, and mechanical properties of rigid polyurethane foam

Nächster Artikel A facile preparation of biochar-anchored magnetic photocatalytic PVDF composite for water remediation

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Holick MF (1995) Environmental factors that influence the cutaneous production of vitamin D. Am J Clin Nutr 61:638S-645S. https://doi.org/10.1093/ajcn/61.3.638SCrossRefPubMed

Wright KP, McHill AW, Birks BR, Griffin BR, Rusterholz T, Chinoy ED (2013) Entrainment of the human circadian clock to the natural light-dark cycle. Curr Biol 23:1554–1558. https://doi.org/10.1016/j.cub.2013.06.039CrossRefPubMedPubMedCentral

Benedetti F, Colombo C, Barbini B, Campori E, Smeraldi E (2001) Morning sunlight reduces length of hospitalization in bipolar depression. J Affect Disord 62:221–223. https://doi.org/10.1016/S0165-0327(00)00149-XCrossRefPubMed

Ziegler A, Jonason AS, Leffellt DJ, Simon JA, Sharma HW, Kimmelman J, Remington L, Jacks T, Brash DE (1994) Sunburn and P53 in the onset of skin cancer. Nature 372:773–776. https://doi.org/10.1038/372773a0CrossRefPubMed

Serpone N, Dondi D, Albini A (2007) Inorganic and organic UV filters: their role and efficacy in sunscreens and suncare products. Inorganica Chim Acta 360:794–802. https://doi.org/10.1016/j.ica.2005.12.057CrossRef

Landfester K (2009) Miniemulsion polymerization and the structure of polymer and hybrid nanoparticles. Angew Chem Int Ed 48:4488–4507. https://doi.org/10.1002/anie.200900723CrossRef

Landfester K, Weiss CK (2010) Encapsulation by Miniemulsion Polymerization. In: Caruso F (ed) Mod. Tech. nano- microreactors/-reactions. Springer Berlin Heidelberg, Berlin. https://doi.org/10.1007/12_2009_43

Tiarks F, Landfester K, Antonietti M (2001) Preparation of polymeric nanocapsules by miniemulsion polymerization. Langmuir 17:908–918. https://doi.org/10.1021/la001276nCrossRef

Cao ZH, Shan GR, Sheibat-Othman N, Putaux JL, Bourgeat-Lami E (2010) Synthesis of oily core-hybrid shell nanocapsules through interfacial free radical copolymerization in miniemulsion: droplet formation and nucleation. J Polym Sci Part A Polym Chem 48:593–603. https://doi.org/10.1002/pola.23809CrossRef

10.

Antonietti M, Landfester K (2002) Polyreactions in miniemulsions. Prog Polym Sci 27:689–757. https://doi.org/10.1016/S0079-6700(01)00051-XCrossRef

11.

Wu PS, Huang LN, Guo YC, Lin CC (2014) Effects of the novel poly(methyl methacrylate) (PMMA)-encapsulated organic ultraviolet (UV) filters on the UV absorbance and in vitro sun protection factor (SPF). J Photochem Photobiol B Biol 131:24–30. https://doi.org/10.1016/j.jphotobiol.2014.01.006CrossRef

12.

Lorca BSS, Bessa ES, Nele M, Santos EP, Pinto JC (2012) Preparation of PMMA nanoparticles loaded with benzophenone-3 through miniemulsion polymerization. Macromol Symp 319:246–250. https://doi.org/10.1002/masy.201100252CrossRef

13.

Frizzo MS, Feuser PE, Berres PH, Ricci-Júnior E, Campos CEM, Costa C, de Araújo PHH, Sayer C (2019) Simultaneous encapsulation of zinc oxide and octocrylene in poly(methyl methacrylate-co-styrene) nanoparticles obtained by miniemulsion polymerization for use in sunscreen formulations. Colloids Surf A 561:39–46. https://doi.org/10.1016/j.colsurfa.2018.10.062CrossRef

14.

Agner T, Serup J, Handlos V, Batsberg W (1989) Different skin irritation abilities of different qualities of sodium lauryl sulphate. Contact Derm 21:184–188. https://doi.org/10.1111/j.1600-0536.1989.tb04733.xCrossRef

15.

Agner T, Serup J (1990) Sodium lauryl sulphate for irritant patch testing -a dose-response study using bioengineering methods for determination of skin irritation. J Invest Dermatol 95:543–547. https://doi.org/10.1111/1523-1747.ep12504896CrossRefPubMed

16.

Moore PN, Puvvada S, Blankschtein D (2003) Challenging the surfactant monomer skin penetration model: penetration of sodium dodecyl sulfate micelles into the epidermis. J Cosmet Sci 54:29–46. PMID: 12644857

17.

Robbins CR (1988) Chemical and physical behavior of human hair. Springer, New York. https://doi.org/10.1007/978-1-4757-2009-9_6CrossRef

18.

Dario MF, Baby AR, Velasco MVR (2015) Effects of solar radiation on hair and photoprotection. J Photochem Photobiol B Biol 153:240–246. https://doi.org/10.1016/j.jphotobiol.2015.09.025CrossRef

19.

DeMerlis CC, Schoneker DR (2003) Review of the oral toxicity of polyvinyl alcohol (PVA). Food Chem Toxicol 41:319–326. https://doi.org/10.1016/S0278-6915(02)00258-2CrossRefPubMed

20.

Chiellini E, Corti A, D’Antone S, Solaro R (2003) Biodegradation of poly (vinyl alcohol) based materials. Prog Polym Sci 28:963–1014. https://doi.org/10.1016/S0079-6700(02)00149-1CrossRef

21.

Blehn GF, Ernsberger ML (1948) Polyvinyl alcohol as an emulsifying agent. Ind Eng Chem 40:1449–1453. https://doi.org/10.1021/ie50464a024CrossRef

22.

Lankveld JMG, Lyklema J (1972) Adsorption of polyvinyl alcohol on the paraffin-water interface. III. Emulsification of paraffin in aqueous solutions of polyvinyl alcohol and the properties of paraffin-in-water emulsions stabilized by polyvinyl alcohol. J Colloid Interface Sci 41:475–483. https://doi.org/10.1016/0021-9797(72)90371-2CrossRef

23.

Zambaux MF, Bonneaux F, Gref R, Maincent P, Dellacherie E, Alonso MJ, Labrude P, Vigneron C (1998) Influence of experimental parameters on the characteristics of poly(lactic acid) nanoparticles prepared by a double emulsion method. J Control Release 50:31–40. https://doi.org/10.1016/S0168-3659(97)00106-5CrossRefPubMed

24.

Sahoo SK, Panyam J, Prabha S, Labhasetwar V (2022) Residual polyvinyl alcohol associated with poly(d, l-lactide-co-glycolide) nanoparticles affects their physical properties and cellular uptake. J Control Release 82:105–114. https://doi.org/10.1016/S0168-3659(02)00127-XCrossRef

25.

Kemala T, Budianto E, Soegiyono B (2012) Preparation and characterization of microspheres based on blend of poly(lactic acid) and poly(ε-caprolactone) with poly(vinyl alcohol) as emulsifier. Arab J Chem 5:103–108. https://doi.org/10.1016/j.arabjc.2010.08.003CrossRef

26.

Taniguchi Y, Nomura S (2012) Prediction of preservative effectiveness of cosmetics from a predictive formula on the basis of the minimum inhibitory concentration (MIC). J Soc Cosmet Chem Japan 46:295–300. https://doi.org/10.5107/sccj.46.295CrossRef

27.

Smith PK, Krohn RI, Hermanson GT, Mallia AK, Gartner FH, Provenzano MD, Fujimoto EK, Goeke NM, Olson BJ, Klenk DC (1985) Measurement of protein using bicinchoninic acid. Anal Biochem 150:76–85. https://doi.org/10.1016/0003-2697(85)90442-7CrossRefPubMed

28.

Budhlall BM, Landfester K, Sudol ED, Dimonie VL, Klein A, El-Aasser MS (2003) Characterization of partially hydrolyzed poly(vinyl alcohol). Effect of poly(vinyl alcohol) molecular architecture on aqueous phase conformation. Macromolecules 36:9477–9484. https://doi.org/10.1021/ma030027dCrossRef

29.

Landfester K, Bechthold N, Förster S, Antonietti M (1999) Evidence for the preservation of the particle identity in miniemulsion polymerization. Macromol Rapid Commun 20:81–84. https://doi.org/10.1002/(SICI)1521-3927(19990201)20:2<81::AID-MARC81>3.0.CO;2-G

30.

Lovell PA, Joseph Schork F (2020) Fundamentals of emulsion polymerization. Biomacromol 21(11):4396–4441. https://doi.org/10.1021/acs.biomac.0c00769

31.

Blythe PJ, Morrison BR, Mathauer KA, Sudol ED, El-Aasser MS (2000) Polymerization of miniemulsions containing predissolved polystyrene and using hexadecane as costabilizer. Langmuir 16:898–904. https://doi.org/10.1021/la990126dCrossRef

32.

Landfester K, Bechthold N, Tiarks F, Antonietti M (1999) Formulation and stability mechanisms of polymerizable miniemulsions. Macromolecules 32:5222–5228. https://doi.org/10.1021/ma990299+CrossRef

33.

Bechthold N, Tiarks F, Willert M, Landfester K, Antonietti M (2000) Miniemulsion polymerization: applications and new materials. Macromol Symp 151:549–555. https://doi.org/10.1002/1521-3900(200002)151:1<549::AID-MASY549>3.0.CO;2-D

34.

Landfester K (2001) Polyreactions in miniemulsions. Macromol Rapid Commun 22:896–936. https://doi.org/10.1002/1521-3927(20010801)22:12<896::AID-MARC896>3.0.CO;2-R

35.

Kamogawa K, Kuwayama N, Katagiri T, Akatsuka H, Sakai T, Sakai H, Abe M (2003) Dispersion and stabilization in water of droplets of hydrophobic organic liquids with the addition of hydrophobic polymers. Langmuir 19:4063–4069. https://doi.org/10.1021/la020749iCrossRef

36.

Lelu S, Novat C, Graillat C, Guyot A, Bourgeat-Lami E (2003) Encapsulation of an organic phthalocyanine blue pigment into polystyrene latex particles using a miniemulsion polymerization process. Polym Int 52:542–547. https://doi.org/10.1002/pi.1029CrossRef

37.

Hu Z, Xue M, Zhang Q, Sheng Q, Liu Y (2008) Nanocolorants: A novel class of colorants, the preparation and performance characterization. Dyes Pigm 76:173–178. https://doi.org/10.1016/j.dyepig.2006.08.026CrossRef

38.

Deshmukh OS, van den Ende D, Stuart MC, Mugele F, Duits MH (2015) Hard and soft colloids at fluid interfaces: adsorption, interactions, assembly & rheology. Adv Coll Interface Sci 222:215–227. https://doi.org/10.1016/j.cis.2014.09.003CrossRef

39.

Nogueira ACS, Joekes I (2004) Hair color changes and protein damage caused by ultraviolet radiation. J Photochem Photobiol B Biol 74:109–117. https://doi.org/10.1016/j.jphotobiol.2004.03.001CrossRef

40.

Jeon SY, Long QP, Lee WS (2008) Comparison of hair shaft damage after UVA and UVB irradiation. Int J Cosmet Sci 59:151–156. https://doi.org/10.1111/j.1468-2494.2008.00452_5.xCrossRef

Titel: Encapsulation of ultraviolet filter into cationic polystyrene particles via miniemulsion polymerization with poly(vinyl alcohol)
verfasst von: Takashi Yamazaki
Minori Shimizu
Sayuri Yamada
Rina Kanda
Toshikazu Tsuji
Publikationsdatum: 11.10.2023
Verlag: Springer Berlin Heidelberg
Erschienen in: Colloid and Polymer Science / Ausgabe 1/2024
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-023-05181-3

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