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01.03.2021 | ORIGINAL PAPER

Enhanced crystallization rate of bio-based poly(butylene succinate-co-propylene succinate) copolymers motivated by glycerol

verfasst von: Hsu-I. Mao, Li-Yuan Wang, Chin-Wen Chen, Kai-Hung Hsu, Cheng-Hang Tsai, Chia-Jung Cho, Yang-Yen Yu, Syang-Peng Rwei, Chi-Ching Kuo

Erschienen in: Journal of Polymer Research | Ausgabe 3/2021

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Abstract

Isothermal crystallization kinetics are performed in poly(butylene succinate-co-propylene succinate) (PBSPS) in a BS/PS ratio of 10/0(PBS) to 7/3 with 0 and 0.02 mol% glycerol, indicating PBSPS copolymers are 3D growths initiated by heterogeneous nucleation. Crystallization growth rates of BS/PS = 10/0(PBS) to 7/3 with 0.02 mol% glycerol are faster than with 0 mol% glycerol, for a given temperature range. Nonisothermal crystallization kinetics are performed to clarify the effects of different glycerol proportions for BS/PS = 7/3. The 0.01 mol% glycerol is used to form a nucleation site, in which the kinetic energy of the molecular chain can be driven to increase the packing ability. When glycerol is increased to 0.02 mol%, the restriction of the glycerol on the movement of the molecular chain becomes more extensive to decrease the relative crystallinity. Hence, a small amount of glycerol content can improve the relative crystallinity and crystallization rate of PBSPS copolymer.

Vorheriger Artikel The effect of microspheres surface morphology on the enhanced microwave absorbing properties of MWCNTs

Nächster Artikel Optical properties of Bromothymol Blue/PVA Composite: Development of flexible high performance laser filter

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Titel: Enhanced crystallization rate of bio-based poly(butylene succinate-co-propylene succinate) copolymers motivated by glycerol
verfasst von: Hsu-I. Mao
Li-Yuan Wang
Chin-Wen Chen
Kai-Hung Hsu
Cheng-Hang Tsai
Chia-Jung Cho
Yang-Yen Yu
Syang-Peng Rwei
Chi-Ching Kuo
Publikationsdatum: 01.03.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 3/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02460-x

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