Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 6/2014

01.06.2014

Enhanced photovoltaic performance of quantum dot sensitized solar cells with Ag-doped TiO2 nanocrystalline thin films

verfasst von: A. Ranjitha, N. Muthukumarasamy, M. Thambidurai, Dhayalan Velauthapillai

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 6/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Ag-doped titanium dioxide (TiO2) nanocrystalline thin films have been prepared by the sol–gel dip coating method and used as photoanode to fabricate quantum dot sensitized solar cells. The X-ray diffraction studies reveal the formation of anatase phase without any impurity phase. The surface morphology studied using scanning electron microscope shows uniform distribution of particles. The optical band gap was found to be 3.5 and 3.4 eV for CdS quantum dot sensitized TiO2 and CdS quantum dot sensitized Ag-doped TiO2 thin film respectively. The Ag-doped TiO2 based solar cell exhibited a power conversion efficiency of 1.48 % which is higher than that of TiO2 (0.9 %).

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Youngjae Kwon, Hyunsu Kim, Sangmin Lee, In-Joo Chin, Tae-Yeon Seong, Wan In Lee, Chongmu Lee, Enhanced ethanol sensing properties of TiO2 nanotube sensors. Sens. Actuators B Chem. 173, 441–446 (2012)CrossRef Youngjae Kwon, Hyunsu Kim, Sangmin Lee, In-Joo Chin, Tae-Yeon Seong, Wan In Lee, Chongmu Lee, Enhanced ethanol sensing properties of TiO2 nanotube sensors. Sens. Actuators B Chem. 173, 441–446 (2012)CrossRef
2.
Zurück zum Zitat K. Awazu, M. Fujimaki, C. Rockstuhl, J. Tominaga, H. Murakami, Y. Ohki, N. Yoshida, T. Watanabe, A plasmonic photocatalyst consisting of silver nanoparticles embedded in titanium dioxide. J. Am. Chem. Soc. 130, 1676–1680 (2008)CrossRef K. Awazu, M. Fujimaki, C. Rockstuhl, J. Tominaga, H. Murakami, Y. Ohki, N. Yoshida, T. Watanabe, A plasmonic photocatalyst consisting of silver nanoparticles embedded in titanium dioxide. J. Am. Chem. Soc. 130, 1676–1680 (2008)CrossRef
3.
Zurück zum Zitat Yan-Qing Zhang, De-Kun Ma, Yan-Ge Zhang, Wei Chen, Shao-Ming Huang, N-doped carbon quantum dots for TiO2-based photocatalysts and dye-sensitized solar cells. Nano Energy 2, 545–552 (2013)CrossRef Yan-Qing Zhang, De-Kun Ma, Yan-Ge Zhang, Wei Chen, Shao-Ming Huang, N-doped carbon quantum dots for TiO2-based photocatalysts and dye-sensitized solar cells. Nano Energy 2, 545–552 (2013)CrossRef
4.
Zurück zum Zitat Zhigang Zang, Atsushi Nakamura, Jiro Temmyo, Single cuprous oxide films synthesized by radical oxidation at low temperature for PV application. Opt. Express 21, 11448–11456 (2013)CrossRef Zhigang Zang, Atsushi Nakamura, Jiro Temmyo, Single cuprous oxide films synthesized by radical oxidation at low temperature for PV application. Opt. Express 21, 11448–11456 (2013)CrossRef
5.
Zurück zum Zitat Lianfeng Zhang, Tatsuo Kanki, Noriaki Sano, Atsushi Toyoda, Development of TiO2 photocatalyst reaction for water purification. Sep. Purif. Technol. 31, 105–110 (2003)CrossRef Lianfeng Zhang, Tatsuo Kanki, Noriaki Sano, Atsushi Toyoda, Development of TiO2 photocatalyst reaction for water purification. Sep. Purif. Technol. 31, 105–110 (2003)CrossRef
6.
Zurück zum Zitat Alexis T. Bell, The impact of nanoscience on heterogeneous catalysis. Science 299, 1688–1691 (2003)CrossRef Alexis T. Bell, The impact of nanoscience on heterogeneous catalysis. Science 299, 1688–1691 (2003)CrossRef
7.
Zurück zum Zitat O. Carp, C.L. Huisman, A. Reller, Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32, 33–177 (2004)CrossRef O. Carp, C.L. Huisman, A. Reller, Photoinduced reactivity of titanium dioxide. Prog. Solid State Chem. 32, 33–177 (2004)CrossRef
8.
Zurück zum Zitat G.L. Zhao, H. Kozuka, T. Yoko, Sol–gel preparation and photoelectrochemical properties of TiO2 films containing Au and Ag metal particles. Thin Solid Films 277, 147–154 (1996)CrossRef G.L. Zhao, H. Kozuka, T. Yoko, Sol–gel preparation and photoelectrochemical properties of TiO2 films containing Au and Ag metal particles. Thin Solid Films 277, 147–154 (1996)CrossRef
9.
Zurück zum Zitat G.L. Zhao, H. Kozuka, T. Yoko, Effects of the incorporation of silver and gold nanoparticles on the photoanodic properties of rose Bengal sensitized TiO2 film electrodes prepared by sol–gel method. Sol. Energy Mater. Sol. Cells 46, 219–231 (1997)CrossRef G.L. Zhao, H. Kozuka, T. Yoko, Effects of the incorporation of silver and gold nanoparticles on the photoanodic properties of rose Bengal sensitized TiO2 film electrodes prepared by sol–gel method. Sol. Energy Mater. Sol. Cells 46, 219–231 (1997)CrossRef
10.
Zurück zum Zitat J. Sarkar, V.T. John, J. He, C. Brooks, D. Gandhi, A. Nunes, G. Ramanath, A. Bose, Surfactant-templated synthesis and catalytic properties of patterned nanoporous Titania supports loaded with platinum nanoparticles. Chem. Mater. 20, 5301–5306 (2008)CrossRef J. Sarkar, V.T. John, J. He, C. Brooks, D. Gandhi, A. Nunes, G. Ramanath, A. Bose, Surfactant-templated synthesis and catalytic properties of patterned nanoporous Titania supports loaded with platinum nanoparticles. Chem. Mater. 20, 5301–5306 (2008)CrossRef
11.
Zurück zum Zitat J.A. Rodriguez, J. Evans, J. Graciani, J.B. Park, P. Liu, J. Hrbek, J.F. Sanz, High water-gas shift activity in TiO2(110) supported Cu and Au nanoparticles: role of the oxide and metal particle size. J. Phys. Chem. C 113, 7364–7370 (2009)CrossRef J.A. Rodriguez, J. Evans, J. Graciani, J.B. Park, P. Liu, J. Hrbek, J.F. Sanz, High water-gas shift activity in TiO2(110) supported Cu and Au nanoparticles: role of the oxide and metal particle size. J. Phys. Chem. C 113, 7364–7370 (2009)CrossRef
12.
Zurück zum Zitat H. Li, G.L. Zhao, Z.J. Chen, B. Song, G.R. Han, TiO2–Ag nanocomposites by low- temperature sol-gel processing. J. Am. Ceram. Soc. 93, 445–449 (2010)CrossRef H. Li, G.L. Zhao, Z.J. Chen, B. Song, G.R. Han, TiO2–Ag nanocomposites by low- temperature sol-gel processing. J. Am. Ceram. Soc. 93, 445–449 (2010)CrossRef
13.
Zurück zum Zitat B. Shanghavi, P.V. Kamat, Interparticle electron transfer in metal/semiconductor composites. Picosecond dynamics of CdS capped gold nanoclusters. J. Phys. Chem. B 101, 7675–7679 (1997)CrossRef B. Shanghavi, P.V. Kamat, Interparticle electron transfer in metal/semiconductor composites. Picosecond dynamics of CdS capped gold nanoclusters. J. Phys. Chem. B 101, 7675–7679 (1997)CrossRef
14.
Zurück zum Zitat G. Merga, L.C. Cass, D.M. Chipman, D. Meisel, Probing silver nanoparticles during catalytic H2 evolution. J. Am. Chem. Soc. 130, 7067–7076 (2008)CrossRef G. Merga, L.C. Cass, D.M. Chipman, D. Meisel, Probing silver nanoparticles during catalytic H2 evolution. J. Am. Chem. Soc. 130, 7067–7076 (2008)CrossRef
15.
Zurück zum Zitat Y. Tian, T. Tatsuma, Mechanisms and applications of plasmon-induced charge separation at TiO2 films loaded with gold nanoparticles. J. Am. Chem. Soc. 127, 7632–7637 (2005)CrossRef Y. Tian, T. Tatsuma, Mechanisms and applications of plasmon-induced charge separation at TiO2 films loaded with gold nanoparticles. J. Am. Chem. Soc. 127, 7632–7637 (2005)CrossRef
16.
Zurück zum Zitat M.S. Devadas, K. Kwak, J.W. Park, J.H. Choi, C.H. Jun, E. Sinn, G. Ramakrishna, D. Lee, Directional electron transfer in chromophore-labeled quantum-sized Au25 clusters: Au25 as an electron donor. J. Phys. Chem. Lett. 1, 1497–1503 (2010)CrossRef M.S. Devadas, K. Kwak, J.W. Park, J.H. Choi, C.H. Jun, E. Sinn, G. Ramakrishna, D. Lee, Directional electron transfer in chromophore-labeled quantum-sized Au25 clusters: Au25 as an electron donor. J. Phys. Chem. Lett. 1, 1497–1503 (2010)CrossRef
17.
Zurück zum Zitat Y. Nishijima, K. Ueno, Y. Yokota, K. Murakoshi, H. Misawa, Plasmon-assisted photocurrent generation from visible to near-infrared wavelength using a Au- nanorods/TiO2 electrode. J. Phys. Chem. Lett. 1, 2031–2036 (2010)CrossRef Y. Nishijima, K. Ueno, Y. Yokota, K. Murakoshi, H. Misawa, Plasmon-assisted photocurrent generation from visible to near-infrared wavelength using a Au- nanorods/TiO2 electrode. J. Phys. Chem. Lett. 1, 2031–2036 (2010)CrossRef
18.
Zurück zum Zitat S.D. Standridge, G.C. Schatz, J.T. Hupp, Distance dependence of plasmon-enhanced photocurrent in dye- sensitized solar cells. J. Am. Chem. Soc. 131, 8407–8409 (2009)CrossRef S.D. Standridge, G.C. Schatz, J.T. Hupp, Distance dependence of plasmon-enhanced photocurrent in dye- sensitized solar cells. J. Am. Chem. Soc. 131, 8407–8409 (2009)CrossRef
19.
Zurück zum Zitat S.D. Standridge, G.C. Schatz, H.T. Hupp, Toward plasmonic solar cells: protection of silver nanoparticles via atomic layer deposition of TiO2. Langmuir 25, 2596–2600 (2009)CrossRef S.D. Standridge, G.C. Schatz, H.T. Hupp, Toward plasmonic solar cells: protection of silver nanoparticles via atomic layer deposition of TiO2. Langmuir 25, 2596–2600 (2009)CrossRef
20.
Zurück zum Zitat M.D. Brown, T. Suteewong, R.S.S. Kumar, V. DInnocenzo, A. Petrozza, M.M. Lee, U. Wiesner, H.J. Snaith, Plasmonic dye-sensitized solar cells using core- shell metal- insulator nanoparticles. Nano Lett. 11, 438–445 (2011)CrossRef M.D. Brown, T. Suteewong, R.S.S. Kumar, V. DInnocenzo, A. Petrozza, M.M. Lee, U. Wiesner, H.J. Snaith, Plasmonic dye-sensitized solar cells using core- shell metal- insulator nanoparticles. Nano Lett. 11, 438–445 (2011)CrossRef
21.
Zurück zum Zitat Z. Liu, W. Hou, P. Pavaskar, M. Aykol, S.B. Cronin, Plasmon resonant enhancement of photocatalytic water splitting under visible illumination. Nano Lett. 11, 1111–1116 (2011)CrossRef Z. Liu, W. Hou, P. Pavaskar, M. Aykol, S.B. Cronin, Plasmon resonant enhancement of photocatalytic water splitting under visible illumination. Nano Lett. 11, 1111–1116 (2011)CrossRef
22.
Zurück zum Zitat C. Damm, G. Israel, Photoelectric properties and photocatalytic activity of silver-coated titanium dioxides. Dyes Pigments 75, 612–618 (2007)CrossRef C. Damm, G. Israel, Photoelectric properties and photocatalytic activity of silver-coated titanium dioxides. Dyes Pigments 75, 612–618 (2007)CrossRef
23.
Zurück zum Zitat H. Tran, J. Scott, K. Chiang, R. Amal, Clarifying the role of silver deposits on titania for the photocatalytic mineralization of organic compounds. J. Photochem. Photobiol. A Chem. 183, 41–52 (2006)CrossRef H. Tran, J. Scott, K. Chiang, R. Amal, Clarifying the role of silver deposits on titania for the photocatalytic mineralization of organic compounds. J. Photochem. Photobiol. A Chem. 183, 41–52 (2006)CrossRef
24.
Zurück zum Zitat L.Z. Zhang, J.C. Yu, A simple approach to reactive silver-coated titanium dioxide photocatalyst. Catal. Commun. 6, 684–687 (2005)CrossRef L.Z. Zhang, J.C. Yu, A simple approach to reactive silver-coated titanium dioxide photocatalyst. Catal. Commun. 6, 684–687 (2005)CrossRef
25.
Zurück zum Zitat V. Vamathevan, R. Amal, D. Beydoun, G. Low, S. McEvoy, Photocatalytic oxidation of organics in water using pure and silver-modified titanium dioxide particles. J. Photochem. Photobiol. A Chem. 148, 233–245 (2002)CrossRef V. Vamathevan, R. Amal, D. Beydoun, G. Low, S. McEvoy, Photocatalytic oxidation of organics in water using pure and silver-modified titanium dioxide particles. J. Photochem. Photobiol. A Chem. 148, 233–245 (2002)CrossRef
26.
Zurück zum Zitat S.X. Liu, Z.P. Qu, X.W. Han, C.L. Sun, A mechanism for enhanced photocatalytic activity of silver-loaded titanium dioxide. Catal. Today 93–95, 877–884 (2004)CrossRef S.X. Liu, Z.P. Qu, X.W. Han, C.L. Sun, A mechanism for enhanced photocatalytic activity of silver-loaded titanium dioxide. Catal. Today 93–95, 877–884 (2004)CrossRef
27.
Zurück zum Zitat I.M. Arabatzis, T. Stergiopoulos, M.C. Bernard, D. Labou, S.G. Neophytides, P. Falaras, Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange. Appl. Catal. B: Environ. 42, 187–201 (2003)CrossRef I.M. Arabatzis, T. Stergiopoulos, M.C. Bernard, D. Labou, S.G. Neophytides, P. Falaras, Silver-modified titanium dioxide thin films for efficient photodegradation of methyl orange. Appl. Catal. B: Environ. 42, 187–201 (2003)CrossRef
28.
Zurück zum Zitat C.C. Wang, J.Y. Ying, Sol–gel synthesis and hydrothermal processing of anatase and rutile titania nanocrystals. Chem. Mater. 11, 3113–3120 (1999)CrossRef C.C. Wang, J.Y. Ying, Sol–gel synthesis and hydrothermal processing of anatase and rutile titania nanocrystals. Chem. Mater. 11, 3113–3120 (1999)CrossRef
29.
Zurück zum Zitat B. Li, X. Wang, M. Yan, L. Li, Preparation and characterization of nano-TiO2 powder. Mater. Chem. Phys. 78, 184–188 (2002)CrossRef B. Li, X. Wang, M. Yan, L. Li, Preparation and characterization of nano-TiO2 powder. Mater. Chem. Phys. 78, 184–188 (2002)CrossRef
30.
Zurück zum Zitat J. Yang, S. Mei, J.M.F. Ferreira, Hydrothermal processing of nanocrystalline anatase film from tetraethylammonium hydroxide peptized titania sols. J. Eur. Ceram. Soc. 24, 335–339 (2004)CrossRef J. Yang, S. Mei, J.M.F. Ferreira, Hydrothermal processing of nanocrystalline anatase film from tetraethylammonium hydroxide peptized titania sols. J. Eur. Ceram. Soc. 24, 335–339 (2004)CrossRef
31.
Zurück zum Zitat C. Su, C.M. Tseng, L.F. Chen, B.H. You, B.C. Hsu, S.S. Chen, Sol-hydrothermal preparation and photocatalysis of titanium dioxide. Thin Solid Films 498, 259–265 (2006)CrossRef C. Su, C.M. Tseng, L.F. Chen, B.H. You, B.C. Hsu, S.S. Chen, Sol-hydrothermal preparation and photocatalysis of titanium dioxide. Thin Solid Films 498, 259–265 (2006)CrossRef
32.
Zurück zum Zitat J. Yang, S. Mei, J.M.F. Ferreira, Hydrothermal synthesis of nanosized titania powders: influence of tetra alkylammonium hydroxides on particle characteristics. J. Am. Ceram. Soc. 84, 1696–1702 (2001)CrossRef J. Yang, S. Mei, J.M.F. Ferreira, Hydrothermal synthesis of nanosized titania powders: influence of tetra alkylammonium hydroxides on particle characteristics. J. Am. Ceram. Soc. 84, 1696–1702 (2001)CrossRef
33.
Zurück zum Zitat H. Cheng, J. Ma, Z. Zhao, L. Qi, Hydrothermal preparation of uniform nanosize rutile and anatase particles. Chem. Mater. 7, 663–671 (1995)CrossRef H. Cheng, J. Ma, Z. Zhao, L. Qi, Hydrothermal preparation of uniform nanosize rutile and anatase particles. Chem. Mater. 7, 663–671 (1995)CrossRef
34.
Zurück zum Zitat K.M. Reddy, D. Guin, S.V. Manorama, A.R. Reddy, Selective synthesis of nanosized TiO2 by hydrothermal route: characterization, structure property relation and photochemical application. J. Mater. Res. 19, 2567–2575 (2004)CrossRef K.M. Reddy, D. Guin, S.V. Manorama, A.R. Reddy, Selective synthesis of nanosized TiO2 by hydrothermal route: characterization, structure property relation and photochemical application. J. Mater. Res. 19, 2567–2575 (2004)CrossRef
35.
Zurück zum Zitat K.N.P. Kumar, K. Keizer, A. Bruggraaf, Nature 48, 358 (1992) K.N.P. Kumar, K. Keizer, A. Bruggraaf, Nature 48, 358 (1992)
36.
Zurück zum Zitat B.D. Culty, Elements of X-ray Diffraction (Addision-Wesley, New York, 1978) B.D. Culty, Elements of X-ray Diffraction (Addision-Wesley, New York, 1978)
37.
Zurück zum Zitat Sang Hoon Nam, Hee-Sang Shim, Yong-Su Kim, Mushtaq Ahmad Dar, Jong Guk Kim, Won Bae Kim, Ag or Au nanoparticle-embedded one-dimensional composite TiO2 nanofibers prepared via electrospinning for use in lithium–ion batteries. Appl. Mater. Interface 2, 2046–2052 (2010)CrossRef Sang Hoon Nam, Hee-Sang Shim, Yong-Su Kim, Mushtaq Ahmad Dar, Jong Guk Kim, Won Bae Kim, Ag or Au nanoparticle-embedded one-dimensional composite TiO2 nanofibers prepared via electrospinning for use in lithium–ion batteries. Appl. Mater. Interface 2, 2046–2052 (2010)CrossRef
39.
Zurück zum Zitat L.A.A. Pettersson, S.R. Lucimara, O. Inganas, Modeling photocurrent action spectra of photovoltaic devices based on organic thin films. J. Appl. Phys. 86, 487–496 (1999)CrossRef L.A.A. Pettersson, S.R. Lucimara, O. Inganas, Modeling photocurrent action spectra of photovoltaic devices based on organic thin films. J. Appl. Phys. 86, 487–496 (1999)CrossRef
40.
Zurück zum Zitat V. Subramanian, E. Wolf, P.V. Kamat, Semiconductor-Metal composite nanostructures. To what extent metal nanoparticles (Au, Pt, Ir) improve the photocatalytic activity of TiO2 films. J. Phys. Chem. B 105, 11439–11446 (2001)CrossRef V. Subramanian, E. Wolf, P.V. Kamat, Semiconductor-Metal composite nanostructures. To what extent metal nanoparticles (Au, Pt, Ir) improve the photocatalytic activity of TiO2 films. J. Phys. Chem. B 105, 11439–11446 (2001)CrossRef
41.
Zurück zum Zitat Yu. Gnatyuk, E. Manujlov, N. Smirnova, A. Eremenko, NATO Science Series II Functional properties of nanostructured materials, ed. by R. Kassing et al. (Springer, The Netherlands, 2006), p. 223, 485–490 Yu. Gnatyuk, E. Manujlov, N. Smirnova, A. Eremenko, NATO Science Series II Functional properties of nanostructured materials, ed. by R. Kassing et al. (Springer, The Netherlands, 2006), p. 223, 485–490
Metadaten
Titel
Enhanced photovoltaic performance of quantum dot sensitized solar cells with Ag-doped TiO2 nanocrystalline thin films
verfasst von
A. Ranjitha
N. Muthukumarasamy
M. Thambidurai
Dhayalan Velauthapillai
Publikationsdatum
01.06.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 6/2014
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-014-1935-x

Weitere Artikel der Ausgabe 6/2014

Journal of Materials Science: Materials in Electronics 6/2014 Zur Ausgabe

Neuer Inhalt