Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 16/2017

09.05.2017 | Chemical routes to materials

Enhanced visible-light photocatalytic activity from graphene-like boron nitride anchored on graphitic carbon nitride sheets

verfasst von: Hang Xu, Zhang Wu, Yueting Wang, Chenshuo Lin

Erschienen in: Journal of Materials Science | Ausgabe 16/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Visible-light-driven, graphene-like boron nitride (g-BN)-mediated graphitic carbon nitride (g-C3N4) photocatalysts were firstly synthesized via a facile and green method. The as-prepared catalyst samples were characterized by their morphology, optical and electrochemical performance. The photocatalytic activity of the g-BN/g-C3N4 composites was evaluated by bisphenol A photodegradation and H2 evolution under visible-light irradiation. The results indicated that 0.9% g-BN/g-C3N4 exhibited the best photocatalytic activity amongst the hybrid photocatalysts. The enhanced photocatalytic activity was ascribed to excellent surface properties, an enhanced visible-light harvesting capability, a stable structure and a high-efficiency separation rate of photoinduced electron–hole pairs. This work will support the rational design of g-BN-based photocatalytic materials for use in energy conversion and environmental preservation.
Vorheriger Artikel RhAg/rGO nanocatalyst: ligand-controlled synthesis and superior catalytic performances for the reduction of 4-nitrophenol
Nächster Artikel Controlled release behavior of sulfentrazone herbicide encapsulated in Ca-ALG microparticles: preparation, characterization, mathematical modeling and release tests in field trial weed control

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Wang Y, Chen J, Xu Q, Li Y, Fu T, Jiang G, Li Y, Zhao Z, Wei Y (2017) Novel visible-light-driven S-doped carbon dots/BiOI nanocomposites: improved photocatalytic activity and mechanism insight. J Mater Sci 12:7282–7293. doi:10.​1007/​s10853-017-0965-1 CrossRef
2.
Zhou L, Zhang H, Sun H, Liu S, Moses O, Wang S, Jin W (2016) Recent advances in non-metal modification of graphitic carbon nitride for photocatalysis: a historic review. Catal Sci Technol 6:7002–7023CrossRef
3.
Xu H, Wu Z, Ding M et al (2017) Microwave-assisted synthesis of flower-like BN/BiOCl composites for photocatalytic Cr(VI) reduction upon visible-light irradiation. Mater Des 114:129–138CrossRef
4.
Wang X, Maeda K, Thomas A, Takanabe K, Xin G, Carlsson JM, Domen K, Antonietti M (2009) A metal-free polymeric photocatalyst for hydrogen production from water under visible light. Nat Mater 8:76–80CrossRef
5.
Liu Q, Guo Y, Chen Z, Zhang Z (2016) Constructing a novel ternary Fe(III)/graphene/g-C3N4 composite photocatalyst with enhanced visible-light driven photocatalytic activity via interfacial charge transfer effect. Appl Catal B 183:231–241CrossRef
6.
Leong KH, Liu SL, Sim LC, Saravanan P, Jang M, Ibrahim S (2015) Surface reconstruction of titania with g-C3N4 and Ag for promoting efficient electrons migration and enhanced visible light photocatalysis. Appl Surf Sci 358:370–376CrossRef
7.
Feng QM, Shen YZ, Li MX, Zhang ZL, Zhao W, Xu JJ, Chen HY (2015) Dual-wavelength electrochemiluminescence ratiometry based on resonance energy transfer between Au nanoparticles functionalized g-C3N4 nanosheet and Ru (bpy)32+ for microRNA detection. Anal Chem 88:937–944CrossRef
8.
Li X, Li M, Yang J, Li X, Hu T, Wang J, Sui Y, Wu X, Kong L (2014) Synergistic effect of efficient adsorption g-C3N4/ZnO composite for photocatalytic property. J Phys Chem Solids 75:441–446CrossRef
9.
Xu M, Han L, Dong S (2013) Facile fabrication of highly efficient g-C3N4/Ag2O heterostructured photocatalysts with enhanced visible-light photocatalytic activity. ACS Appl Mater Interfaces 5:12533–12540CrossRef
10.
Fagan R, McCormack DE, Hinder SJ, Pillai SC (2016) Photocatalytic properties of g-C3N4–TiO2 heterojunctions under UV and visible light conditions. Materials 9:286–296CrossRef
11.
Yin S, Di J, Li M, Sun Y, Xia J, Xu H, Fan W, Li H (2016) Ionic liquid-assisted synthesis and improved photocatalytic activity of pn junction g-C3N4/BiOCl. J Mater Sci 51:4769–4777. doi:10.​1007/​s10853-016-9746-5 CrossRef
12.
Liu D, Jiang Z, Zhu C, Qian K, Wu Z, Xie J (2016) Graphene-analogue BN-modified microspherical BiOI photocatalysts driven by visible light. Dalton Trans 45:2505–2516CrossRef
13.
Sun J, Song J, Gondal M, Shi S, Lu Z, Xu Q, Chang X, Xiang D, Shen K (2015) Preparation of g-C3N4/BiOX (X = Cl, Br, I) composites, and their photocatalytic activity under visible light irradiation. Res Chem Intermed 41:6941–6955CrossRef
14.
Hu JY, Ke T, Hong J (2016) Improvement of phenol photodegradation efficiency by a combined g-C3N4/Fe(III)/persulfate system. Chemosphere 148:34–40CrossRef
15.
Sasaki Y, Iwase A, Kato H, Kudo A, Sasaki Y, Iwase A, Kato H, Kudo A (2008) The effect of co-catalyst for Z-scheme photocatalysis systems with an Fe3+/Fe2+ electron mediator on overall water splitting under visible light irradiation. J Catal 259:133–137CrossRef
16.
Guo SN, Min YL, Fan JC, Xu QJ (2015) Holey structured graphitic carbon nitride thin sheets with edge oxygen doping via photo-fenton reaction with enhanced photocatalytic activity. Appl Catal B 185:315–321CrossRef
17.
Neto AC, Novoselov K (2011) New directions in science and technology: two-dimensional crystals. Rep Prog Phys 74:082501CrossRef
18.
Han S, Hu L, Liang Z, Wageh S, Al-Ghamdi A, Chen Y, Fang X (2014) One-step hydrothermal synthesis of 2D hexagonal nanoplates of α-Fe2O3/graphene composites with enhanced photocatalytic activity. Adv Funct Mater 24:5719–5727CrossRef
19.
Tian Q, Wu W, Liu J et al (2017) Dimensional heterostructures of 1D CdS/2D ZnIn 2 S 4 composited with 2D graphene: designed synthesis and superior photocatalytic performance. Dalton Trans 46:2770–2777CrossRef
20.
Xu Y, Xu H, Wang L, Yan J, Li H, Song Y, Huang L, Cai G (2013) The CNT modified white C3N4 composite photocatalyst with enhanced visible-light response photoactivity. Dalton Trans 42:7604–7613CrossRef
21.
Liao G, Chen S, Quan X, Yu H, Zhao H (2012) Graphene oxide modified g-C3N4 hybrid with enhanced photocatalytic capability under visible light irradiation. J Mater Chem 22:2721–2726CrossRef
22.
Tong Z, Yang D, Shi J, Nan Y, Sun Y, Jiang Z (2015) Three-dimensional porous aerogel constructed by g-C3N4 and graphene oxide nanosheets with excellent visible-light photocatalytic performance. ACS Appl Mater Interfaces 7:25693–25701CrossRef
23.
Deng Y, Liu K, Cao H, Luo M, Yan H (2015) Synthesis of graphene with both high nitrogen content and high surface area by annealing composite of graphene oxide and g-C3N4. J Iran Chem Soc 12:807–814CrossRef
24.
Gannett W, Regan W, Watanabe W, Taniguchi T, Crommie M, Zettl A (2011) Boron nitride substrates for high mobility chemical vapor deposited graphene. Appl Phys Lett 98:242–255CrossRef
25.
Kim KK, Hsu A, Jia X, Kim SM, Shi Y, Dresselhaus M, Palacios T, Kong J (2012) Synthesis and characterization of hexagonal boron nitride film as a dielectric layer for graphene devices. ACS Nano 6:8583–8590CrossRef
26.
Kiran M, Raidongia K, Ramamurty U, Rao C (2011) Improved mechanical properties of polymer nanocomposites incorporating graphene-like BN: dependence on the number of BN layers. Scr Mater 64:592–595CrossRef
27.
Li TL, Hsu SLC (2010) Enhanced thermal conductivity of polyimide films via a hybrid of micro-and nano-sized boron nitride. J Phys Chem B 114:6825–6829CrossRef
28.
Shin H, Guan J, Zgierski MZ, Kim KS, Kingston CT, Simard B (2015) Covalent functionalization of boron nitride nanotubes via reduction chemistry. ACS Nano 9:12573–12582CrossRef
29.
Ding S, Mao D, Yang S et al (2017) Graphene-analogue h-BN coupled Bi-rich Bi4O5Br 2 layered microspheres for enhanced visible-light photocatalytic activity and mechanism insight. Appl Catal B 2:1213–1258
30.
Liu D, Zhang M, Xie W, Sun L, Chen Y, Lei W (2017) Porous BN/TiO2 hybrid nanosheets as highly efficient visible-light-driven photocatalysts. Appl Catal B 207:72–78CrossRef
31.
Chen Z, Chen X, Di J, Liu Y, Yin S, Xia J, Li H (2017) Graphene-like boron nitride modified bismuth phosphate materials for boosting photocatalytic degradation of enrofloxacin. J Colloid Interface Sci 492:51–60CrossRef
32.
Dai K, Lu L, Liu Q, Zhu G, Wei X, Bai J, Xuan L, Wang H (2014) Sonication assisted preparation of graphene oxide/graphitic-C3N4 nanosheet hybrid with reinforced photocurrent for photocatalyst applications. Dalton Trans 43:6295–6299CrossRef
33.
Wu W, Lv X, Wang J, Xie J (2017) Integrating AgI/AgBr biphasic heterostructures encased by few layer h-BN with enhanced catalytic activity and stability. J Colloid Interface Sci 496:434–445CrossRef
34.
Silva ESD, Prevot V, Forano C, Wong-Wah-Chung P, Burrows HD, Sarakha M (2014) Heterogeneous photocatalytic degradation of pesticides using decatungstate intercalated macroporous layered double hydroxides. Environ Sci Pollut R 21:11218–11227CrossRef
35.
Ferencz Z, Szabados M, Ádok-Sipiczki M, Kukovecz A, Kónya Z, Sipos P, Pálinkó I (2014) Mechanochemically assisted synthesis of pristine Ca(II) Sn(IV)-layered double hydroxides and their amino acid intercalated nanocomposites. J Mater Sci 49:8478–8486. doi:10.​1016/​j.​jssc.​2015.​10.​038 CrossRef
36.
Fettkenhauer C (2015) Facile synthesis of new, highly efficient SnO2/carbon nitride composite photocatalysts for the hydrogen evolution reaction. Green Chem 17:3350–3361CrossRef
37.
Li XH, Zhang J, Chen X, Fischer A, Thomas A, Antonietti M, Wang X (2011) Condensed graphitic carbon nitride nanorods by nanoconfinement: promotion of crystallinity on photocatalytic conversion. Chem Mater 23:4344–4348CrossRef
38.
Nag A, Raidongia K, Hembram KP, Datta R, Waghmare UV, Rao C (2010) Graphene analogues of BN: novel synthesis and properties. ACS Nano 4:1539–1544CrossRef
39.
Clayton C, Lu Y (1986) A bipolar model of the passivity of stainless steel: the role of Mo addition. J Electrochem Soc 133:2465–2473CrossRef
40.
Li HJ, Sun BW, Sui L, Qian DJ, Chen M (2015) Preparation of water-dispersible porous g-C3N4 with improved photocatalytic activity by chemical oxidation. Phys Chem Chem Phys 17:3309–3315CrossRef
41.
Meng F, Zhang X, Xu B, Yue S, Guo H, Luo Y (2011) Alkali-treated graphene oxide as a solid base catalyst: synthesis and electrochemical capacitance of graphene/carbon composite aerogels. J Mater Chem 21:18537–18539CrossRef
42.
Wang XJ, Yang WY, Li FT, Xue YB, Liu RH, Hao YJ (2013) In situ microwave-assisted synthesis of porous N–TiO2/g-C3N4 heterojunctions with enhanced visible-light photocatalytic properties. Ind Eng Chem Res 52:17140–17150CrossRef
43.
Zhou Y, Zhang L, Huang W, Kong Q, Fan X, Wang M, Shi J (2016) N-doped graphitic carbon-incorporated g-C3N4 for remarkably enhanced photocatalytic H2 evolution under visible light. Carbon 99:111–117CrossRef
44.
Karbhal I, Devarapalli RR, Debgupta J, Pillai VK, Ajayan PM, Shelke MV (2016) Facile green synthesis of BCN nanosheets as high-performance electrode material for electrochemical energy storage. Chem Eur J 22:7134–7140CrossRef
45.
Li T, Zhao L, He Y, Cai J, Luo M, Lin J (2013) Synthesis of g-C3N4/SmVO4 composite photocatalyst with improved visible light photocatalytic activities in RhB degradation. Appl Catal B 129:255–263CrossRef
46.
Prakash A, Todi V, Sundaram KB, Ross L, Xu G, French M, Henry P, King SW (2015) Investigation of the dielectric and mechanical properties for magnetron sputtered BCN thin films. J Solid State Sci Technol 4:3122–3126CrossRef
47.
Xu H, Yan J, Xu Y, Song Y, Li H, Xia J, Huang C, Wan H (2013) Novel visible-light-driven AgX/graphite-like C3N4(X = Br, I) hybrid materials with synergistic photocatalytic activity. Appl Catal B 129:182–193CrossRef
48.
Wang K, Li Q, Liu B, Cheng B, Ho W, Yu J (2015) Sulfur-doped g-C3N4 with enhanced photocatalytic CO2-reduction performance. Appl Catal B 176:44–52CrossRef
49.
Sun Q, Lv K, Zhang Z, Li M, Li B (2015) Effect of contact interface between TiO2 and g-C3N4 on the photoreactivity of g-C3N4/TiO2 photocatalyst:(001) vs (101) facets of TiO2. Appl Catal B 164:420–427CrossRef
50.
Dong G, Ho W, Li Y, Zhang L (2015) Facile synthesis of porous graphene-like carbon nitride (C6N9H3) with excellent photocatalytic activity for NO removal. Appl Catal B 174:477–485CrossRef
51.
Yu J, Ran J (2011) Facile preparation and enhanced photocatalytic H2-production activity of Cu(OH)2 cluster modified TiO2. Energy Environ Sci 4:1364–1371CrossRef
52.
Hong Y, Jiang Y, Li C, Fan W, Yan X, Yan M, Shi W (2016) In-situ synthesis of direct solid-state Z-scheme V2O5/g-C3N4 heterojunctions with enhanced visible light efficiency in photocatalytic degradation of pollutants. Appl Catal B 180:663–673CrossRef
53.
Rokhsat E, Akhavan O (2016) Improving the photocatalytic activity of graphene oxide/ZnO nanorod films by UV irradiation. Appl Surf Sci 371:590–595CrossRef
54.
Ghafuri H, Movahedinia Z, Rahimi R, Zand HRE (2015) Synthesis of 5, 10, 15, 20-tetrakis [4-(naphthalen-2-yloxycarbonyl) phenyl] porphyrin (TNBP) and its complexes with zinc and cobalt and an investigation of the photocatalytic activity of nano Fe3O4/ZrO2–TNBP. RSC Adv 5:60172–60178CrossRef
Metadaten
Titel
Enhanced visible-light photocatalytic activity from graphene-like boron nitride anchored on graphitic carbon nitride sheets
verfasst von
Hang Xu
Zhang Wu
Yueting Wang
Chenshuo Lin
Publikationsdatum
09.05.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 16/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1167-6

Weitere Artikel der Ausgabe 16/2017

Journal of Materials Science 16/2017 Zur Ausgabe

Metals

Microstructural investigations on historical organ pipes

Review

Advances in carbon nanotubes as efficacious supports for palladium-catalysed carbon–carbon cross-coupling reactions

Metals

The disparity of corrosion resistance between Ni/Au and Ni–P/Au electrical contacts in mixed flowing and salt spray tests

Composites

Preparation of CeO2–ZrO2–Al2O3 composite with layered structure for improved Pd-only three-way catalyst

Ceramics

Phase formation and microstructure during laser sintering and crystallization of a 4.2 MgO·5.0 ZnO·44.1 CaO·26.7 Al2O3·20.0 SiO2 glass

Energy materials

Synthesis of mesoporous carbon nanospheres via “pyrolysis-deposition” strategy for CO2 capture

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise