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Journal of Materials Science: Materials in Electronics
Erschienen in: Journal of Materials Science: Materials in Electronics 2/2020

03.12.2019

Enhancement of thermoelectric performance through synergy of Pb acceptor doping and superstructure modulation for p-type Bi2Te3

verfasst von: Wei Wu, Wenxin Liu, Fengrong Yu

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 2/2020

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Abstract

A facile and efficient way in optimizing thermoelectric performance of Bi2Te3 alloy was reported through synergy of Pb acceptor doping and superstructure modulation. By varying the amount of Pb doping, the substitutional defect \({\text{Pb}}^{\prime}_{\text{Bi}}\), arranging along the c-axis of PbBi2Te4 and PbBi4Te7 and acting as electron acceptor and superstructure, was formed successively in the Bi2Te3 matrix. This significantly reduced the lattice thermal conductivity and suppressed the bipolar effect. The figure of merit was enhanced and modulated, exhibiting a peak ZT of 1.06 and a broadened and optimized average ZT of 0.9 in a wide temperature range of 323–503 K.
Vorheriger Artikel Synthesis and characterization of Z-scheme Ag2WO4/Bi2MoO6 heterojunction photocatalyst: enhanced visible-light photodegradation of organic pollutant
Nächster Artikel Chemical bath deposition of Co-doped PbS thin films for solar cell application

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Literatur
1.
C. Gayner, K.K. Kar, Recent advances in thermoelectric materials. Prog. Mater. Sci. 83, 330–382 (2016)CrossRef
2.
Goldsmid, H.J.: The improvement of a specific material—bismuth telluride. In: Hull, R., Osgood, R.M., Parisi, J., Warlimont, H. (eds) Introduction to Thermoelectricity, 2nd edn. Springer, Heidelberg, pp. 85–108 (2016)CrossRef
3.
Y. Pei, A. LaLonde, S. Iwanaga, G.J. Snyder, High thermoelectric figure of merit in heavy hole dominated PbTe. Energy Environ. Sci. 4, 2085–2089 (2011)CrossRef
4.
X. Shi, J. Yang, J.R. Salvador, M. Chi, J.Y. Cho, H. Wang, S. Bai, J. Yang, W. Zhang, L. Chen, Multiple-filled skutterudites: high thermoelectric figure of merit through separately optimizing electrical and thermal transports. J. Am. Chem. Soc. 133, 7837–7846 (2011)CrossRef
5.
S.J. Poon, Half Heusler compounds: promising materials for mID-to-high temperature thermoelectric conversion. J. Phys. D 52, 493001 (2019)CrossRef
6.
S. Demirel, E. Altin, E. Oz, S. Altin, A. Bayri, An enhancement ZT and spin state transition of Ca3Co4O9 with Pb doping. J. Alloys Comp. 627, 430–437 (2015)CrossRef
7.
D. Champier, Thermoelectric generators: a review of applications. Energy Convers. Manage 140, 167–181 (2017)CrossRef
8.
X. Shi, L. Chen, Thermoelectric materials step up. Nat. Mater. 15, 691–692 (2016)CrossRef
9.
B. Poudel, Q. Hao, Y. Ma, Y. Lan, A. Minnich, B. Yu, X. Yan, D. Wang, A. Muto, D. Vashaee, X. Chen, J. Liu, M.S. Dresselhaus, G. Chen, Z. Ren, High-thermoelectric performance of nanostructured bismuth antimony telluride bulk alloys. Science 320, 634–638 (2008)CrossRef
10.
F. Shufen, J. Zhao, J. Guo, Qingyu Yan, Jan Ma, and Huey Hoon Hng, p-type Bi0.4Sb1.6Te3 nanocomposites with enhanced figure of merit. Appl. Phys. Lett. 96, 182104 (2010)CrossRef
11.
Zhang, C., Mata, M., Li, Z., Belarre, F.J., Arbiol, J., Khor, K.A., Zhu, D.P.B., Yan, Q., Xiong, Q.: Enhanced thermoelectric performance, of solution-derived bismuth telluride based nanocomposites via liquid-phase sintering. Nano Energy 30, 630–638 (2016)CrossRef
12.
R. Deng, X. Su, Z. Zheng, W. Liu, Y.Yan,Q. Zhang, V.P. Dravid, C. Uher, M.G. Kanatzidis, X. Tang, Thermal conductivity in Bi0.5Sb1.5Te3+xand the role of dense dislocation arrays at grain boundaries. Sci. Adv. 4(6), eaar5606 (2018)CrossRef
13.
D. Li, J.M. Li, J.C. Li, Y.S. Wang, J. Zhang, X.Y. Qin, Y. Cao, Y.S. Li, G.D. Tang, High thermoelectric performance of n-type Bi2Te2.7Se0.3 via nanostructure engineering. J. Mater. Chem. A 6, 9642–9649 (2018)CrossRef
14.
Y. Liu, Y. Zhang, S. Ortega, M. Ibáñez, K.H. Lim, A. Grau-Carbonell, S. Martí-Sánchez, K.M. Ng, J. Arbiol, M.V. Kovalenko, D. Cadavid, A. Cabot, Nano Lett. 18, 2557–2563 (2018)CrossRef
15.
J.R. Sootsman, D.Y. Chung, M.G. Kanatzidis, New and old concepts in thermoelectric materials. Angew. Chem. 48, 8616–8639 (2009)CrossRef
16.
D. Xie, J. Xu, Z. Liu, G. Liu, H. Shao, X. Tan, H. Jiang, J. Jiang, Stabilization of Thermoelectric properties of the Cu/Bi0.48Sb1.52Te3 composite for advantageous power generation. J. Electron. Mater. 46, 2746–2751 (2017)CrossRef
17.
F. Hao, P. Qiu, Y. Tang, S. Bai, T. Xing, H.-S. Chu, Q. Zhang, P. Lu, T. Zhang, D. Ren, J. Chen, X. Shi, L. Chen, High efficiency Bi2Te3-based materials and devices for thermoelectric power generation between 100 and 300 °C. Energy Environ. Sci. 9, 3120–3127 (2016)CrossRef
18.
C.-C. Lin, D. Ginting, R. Lydia, M.H. Lee, J.-S. Rhyee, Thermoelectric properties and extremely low lattice thermal conductivity in p-type Bismuth Tellurides by Pb-doping and PbTe precipitation. J. Alloys Comp. 671, 538–544 (2016)CrossRef
19.
K. Kim, G. Kim, S.I. Kim, K.H. Lee, W. Lee, Clarification of electronic and thermal transport properties of Pb-, Ag-, and Cu-doped p-type Bi0.52Sb1.48Te3. J. Alloys Compd. 772, 593–602 (2019)CrossRef
20.
B. Xu, M.T. Agne, T. Feng, T.C. Chasapis, X. Ruan, Y. Zhou, H. Zheng, J.H. Bahk, M.G. KanatzIDis, G.J. Snyder, Y. Wu, Nanocomposites from solution-synthesized PbTe-BiSbTe nanoheterostructure with unity figure of merit at low–medium temperatures (500–600 K). Adv. Mater. 29, 1605140 (2017)CrossRef
21.
C. Li, X. Qin, Y. Li, D. Li, J. Zhang, H. Guo, H. Xin, C. Song, Simultaneous increase in conductivity and phonon scattering in a graphene nanosheets/(Bi2Te3)0.2(Sb2Te3)0.8 thermoelectric nanocomposite. J. Alloys Compd. 661, 389–395 (2016)CrossRef
22.
R. Deng, X. Su, S. Hao, Z. Zheng, M. Zhang, H. Xie, W. Liu, Y. Yan, C. Wolverton, C. Uher, M.G. Kanatzidis, X. Tang, High thermoelectric performance in Bi0.46Sb1.54Te3 nanostructured with ZnTe. Energy Environ. Sci. 11, 1520–1535 (2018)CrossRef
23.
J.M. Song, J.U.R.J.Y. Cho, S. Lee, W.S. Seo, S. Kim, S. Kim, K.H. Lee, D. Roh., W.H. Shin, Chemically synthesized Cu2Te incorporated Bi-Sb-Te p-type thermoelectric materials for low temperature energy harvesting. Scr. Mater. 165, 78–83 (2019)CrossRef
24.
S. Wang, J. Yang, T. Toll, J. Yang, W. Zhang, X. Tang, Conductivity-limiting bipolar thermal conductivity in semiconductors. Sci. Rep. 5, 10136 (2015)CrossRef
25.
L.-P. Hu, T.-J. Zhu, Y.-G. Wang, H.-H. Xie, Z.-J. Xu, X.-B. Zhao, Shifting up the optimum figure of merit of p-type bismuth telluride-based thermoelectric materials for power generation by suppressing intrinsic conduction. NPG Asia Mater. 6, e88 (2014)CrossRef
26.
K.H. Lee, W.H. Shin, H.-S. Kim, K. Lee, J.W. Roh, J. Yoo, J. Kim, S.W. Kim, S. Kim, Synergetic effect of grain size reduction on electronic and thermal transport properties by selectively-suppressed minority carrier mobility and enhanced boundary scattering in Bi0.5Sb1.5Te3 alloys. Scr. Mater. 160, 15–19 (2019)CrossRef
27.
Z. Xu, H. Wu, T. Zhu, C. Fu, X. Liu, L. Hu, J. He, J. He, X. Zhao, Attaining high mid-temperature performance in (Bi,Sb)2Te3 thermoelectric materials via synergistic optimization. NPG Asia Mater. 8, e302 (2016)CrossRef
28.
A. Banik, B. Vishal, S. Perumal, R. Datta, K. Biswas, The origin of low thermal conductivity in Sn1 – xSbxTe: phonon scattering via layered intergrowth nanostructures. Energy Environ. Sci. 9, 2011–2019 (2016)CrossRef
29.
A.N. Gandi, H.N. Alshareef, U. Schwingenschlögl, Thermal response in van der Waals heterostructures. J. Phys. 29, 035504 (2017)
30.
G. Ding, C. Wang, G. Gao, K. Yao, C. Dun, C. Feng, D. Li, G. Zhang, Engineering of charge carriers via a twodimensional heterostructure to enhance the thermoelectric figure of merit. Nanoscale 10, 7077–7084 (2018)CrossRef
31.
R. Venkatasubramanian, E. Siivola, T. Colpitts, B. O’Quinn, Thin-film thermoelectric devices with high room-temperature figures of merit. Nature 413, 597–602 (2001)CrossRef
32.
C. Chang, Q. Tan, Y. Pei, Y. Xiao, X. Zhang, Y. Chen, L. Zheng, S. Gong, J. Li, J. He, L. Zhao, Raising thermoelectric performance of n-type SnSe via Br doping and Pb alloying. RSC Adv. 6, 98216–98220 (2016)CrossRef
33.
T. Plecháček, J. Navrátil, J. Horák, D. Bachan, A. Krejčová, P. Lošťák, Point and structural defects in Bi2PbxTe3 single crystals. Solid State Ionics 177, 3513–3519 (2007)CrossRef
34.
S.V. Eremeev, YuM Koroteev, E.V. Chulkov, On possible deep subsurface states in topological insulators: the PbBi4Te7 system. JETP Lett. 92, 161–165 (2010)CrossRef
35.
M. Předota, L. Beneš, J. Horák, On the incorporation of germanium atoms into the Bi2Te3 crystal lattice. Phys. Stat. SolIDi A 100, 401–404 (1987)CrossRef
36.
G.S. Nolas, J. Sharp, H.J. GoldsmID, Thermoelectrics: basic principles and new materials developments, in Thermoelectrics: Basic Principles and New Materials Developments, ed. by A. Zunger, R.M. Osgood Jr., R. Hull, H. Sakaki (Springer, New York, 2001), pp. 59–90CrossRef
37.
H.S. Kim, Z.M. Gibbs, Y. Tang, H. Wang, G.J. Snyder, Characterization of Lorenz number with Seebeck coefficient measurement. APL Mater. 3, 041506 (2015)CrossRef
38.
L.-D. Zhao, S. Lo, Y. Zhang, H. Sun, G. Tan, C. Uher, C. Wolverton, V.P. Dravid, M.G. Kanatzidis, Ultralow thermal conductivity and high thermoelectric figure of merit in SnSe crystals. Nature 508, 373–377 (2014)CrossRef
39.
X.B. Zhao, X.H. Ji, Y.H. Zhang, T.J. Zhu, J.P. Tu, X.B. Zhang, Bismuth telluride nanotubes and the effects on the thermoelectric properties of nanotube-containing nanocomposites. Appl. Phys. Lett. 86, 062111 (2005)CrossRef
40.
K. Kim, G. Kim, H. Lee, K.H. Lee, W. Lee, Band engineering and tuning thermoelectric transport properties of p-type Bi0.52Sb1.48Te3 by Pb doping for low-temperature power generation. Scr. Mater. 145, 41–44 (2018)CrossRef
Metadaten
Titel
Enhancement of thermoelectric performance through synergy of Pb acceptor doping and superstructure modulation for p-type Bi2Te3
verfasst von
Wei Wu
Wenxin Liu
Fengrong Yu
Publikationsdatum
03.12.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 2/2020
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-019-02631-z

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