Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Rare Metals
Erschienen in: Rare Metals 4/2021

04.07.2018

Enhancing hydrogen sorption in MgH2 by controlling particle size and contact of Ni catalysts

verfasst von: Ting-Zhi Si, Xue-Yang Zhang, Jing-Jing Feng, Xiao-Li Ding, Yong-Tao Li

Erschienen in: Rare Metals | Ausgabe 4/2021

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A comparative study based on MgH2 ball-milled with altered Ni particle sizes under different conditions was conducted to reveal the effect of close contact between hydrides and metal catalysts on their hydrogen sorption properties. It is found that the Mg + nano-Ni (5 at%) composites not only exhibit a substantial decreased onset desorption temperature by approximately 180 °C but also dramatically enhance the absorption kinetics by sixteen times in comparison with those of pure MgH2. This remarkable kinetics enhancement can be explained by the superior catalytic effect of Ni present in composites that highly depends on its particle size and its close contact with MgH2.
Vorheriger Artikel Experimental isothermal section phase diagram of Ho–Fe–In at 773 K and magnetic properties of Ho12Fe2.08In2.92 alloy
Nächster Artikel Cycling hydrogen desorption properties and microstructures of MgH2–AlH3–NbF5 hydrogen storage materials

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
[1]
Schlapbach L, Zuttel A. Hydrogen-storage materials for mobile applications. Nature. 2001;414:353.CrossRef
[2]
Li Y, Zhou G, Fang F, Yu X, Zhang Q, Ouyang L, Zhu M, Sun D. De-/re-hydrogenation features of NaAlH4 confined exclusively in nanopores. Acta Mater. 2011;59(4):1829.CrossRef
[3]
Takagi S, Iijima Y, Sato T, Saitoh H, Ikeda K, Otomo T, Miwa K, Ikeshoji T, Aoki K, Orimo S. True boundary for the formation of homoleptic transition-metal hydride complexes. Angew Chem Int Ed. 2015;54(19):5650.CrossRef
[4]
Li Y, Ding X, Zhang Q. Self-printing on graphitic nanosheets with metal borohydride nanodots for hydrogen storage. Sci Rep. 2016;6:31144.CrossRef
[5]
Wang HB, Wang Q, Dong C, Xu F, Sun L, Chen C. Microstructure and storage properties of low V-containing Ti–Cr–V hydrogen storage alloys prepared by arc melting and suction casting. Rare Met. 2013;32(4):354.CrossRef
[6]
Sun J, Xiao X, Zheng Z, Fan X, Xu C, Liu L, Li S, Chen L. Synthesis of nanoscale CeAl4 and its high catalytic efficiency for hydrogen storage of sodium alanate. Rare Met. 2017;36(2):77.CrossRef
[7]
Li Y, Fang F, Song Y, Li Y, Zhang Q, Ouyang LZ, Zhu M, Sun D. Enhanced dehydrogenation of ammonia borane by reaction with alkaline earth metal chlorides. Int J Hydrogen Energy. 2012;37(5):4274.CrossRef
[8]
[9]
Crivello JC, Dam B, Denys RV, Dornheim M, Grant DM, Huot J, Jensen TR, de Jongh P, Latrochel M, Milanese C, Milcius D, Walker GS, Webb CJ, Zlotea C, Yartys VA. Review of magnesium hydride-based materials: development and optimisation. Appl Phys A. 2016;122:97.CrossRef
[10]
Jensen TR, Andreasen A, Vegge T, Andreasen JW, Ståhl K, Pedersen AS, Nielsen MM, Molenbroek AM, Besenbacher F. Dehydrogenation kinetics of pure and nickel-doped magnesium hydride investigated by in situ time-resolved powder X-ray diffraction. Int J Hydrogen Energy. 2006;31(14):2052.CrossRef
[11]
Paskevicius M, Sheppard DA, Buckley CE. Thermodynamic changes in mechanochemically synthesized magnesium hydride nanoparticles. J Am Chem Soc. 2010;132(14):5077.CrossRef
[12]
Zhao B, Fang F, Sun D, Zhang Q, Wei S, Cao F, Sun H, Ouyang L, Zhu M. Formation of Mg2Ni with enhanced kinetics: using MgH2 instead of Mg as a starting material. J Solid State Chem. 2012;192:210.CrossRef
[13]
Lin H, Tang J, Yu Q, Wang H, Ouyang L, Zhao Y, Liu J, Wang W, Zhu M. Symbiotic CeH2.73/CeO2 catalyst: a novel hydrogen pump. Nano Energy. 2014;9:80.CrossRef
[14]
He D, Wang Y, Wu C, Li Q, Ding W, Sun C. Enhanced hydrogen desorption properties of magnesium hydride by coupling non-metal doping and nano-confinement. Appl Phys Lett. 2015;107(24):243907.CrossRef
[15]
Ouyang LZ, Cao ZJ, Wang H, Liu JW, Sun DL, Zhang QA, Zhu M. Enhanced dehydriding thermodynamics and kinetics in Mg(In)–MgF2 composite directly synthesized by plasma milling. J Alloys Compd. 2014;586(15):113.CrossRef
[16]
Zhong HC, Wang H, Liu JW, Sun DL, Zhu M. Altered desorption enthalpy of MgH2 by the reversible formation of Mg(In) solid solution. Scripta Mater. 2011;65(4):285.CrossRef
[17]
Jeon K, Moon H, Ruminski AM, Jiang B, Kisielowski C, Bardhan R, Urban JJ. Air-stable magnesium nanocomposites provide rapid and high-capacity hydrogen storage without using heavy-metal catalysts. Nat Mater. 2011;10:286.CrossRef
[18]
Xia G, Tan Y, Chen X, Sun D, Guo Z, Liu H, Ouyang L, Zhu M, Yu X. Monodisperse magnesium hydride nanoparticles uniformly self-assembled on graphene. Adv Mater. 2016;27(39):5981.CrossRef
[19]
Cui J, Wang H, Sun D, Zhang Q, Zhu M. Realizing nano-confinement of magnesium for hydrogen storage using vapour transport deposition. Rare Met. 2016;35(5):401.CrossRef
[20]
Ma L, Kang X, Dai H, Liang Y, Fang Z, Wang P, Cheng H. Superior catalytic effect of TiF3 over TiCl3 in improving the hydrogen sorption kinetics of MgH2: catalytic role of fluorine anion. Acta Mater. 2009;57(7):2250.CrossRef
[21]
Friedrichs O, Klassen T, Sánchez-López JC, Bormann R, Fernández A. Hydrogen sorption improvement of nanocrystalline MgH2 by Nb2O5 nanoparticles. Scripta Mater. 2006;54(7):1293.CrossRef
[22]
Yao X, Wu C, Du A, Zou J, Zhu Z, Wang P, Cheng H, Smith S, Lu G. Metallic and carbon nanotube-catalyzed coupling of hydrogenation in magnesium. J Am Chem Soc. 2007;129(50):15650.CrossRef
[23]
German E, Gebauer R. Improvement of hydrogen vacancy diffusion kinetics in MgH2 by niobium- and zirconium-doping for hydrogen storage applications. J Phys Chem C. 2016;120(9):4806.CrossRef
[24]
Humphries TD, Kalantzopoulos GN, Llamas-Jansa I, Olsen JE, Hauback BC. Reversible hydrogenation studies of NaBH4 milled with Ni containing additives. J Phys Chem C. 2013;117(12):6060.CrossRef
[25]
Kalantzopoulos GN, Guzik M, Deledda S, Heyn M, Muller J, Hauback BC. Destabilization effect of transition metal fluorides on sodium borohydride. Phys Chem Chem Phys. 2014;16(38):20483.CrossRef
[26]
Liu Y, Du H, Zhang X, Yang Y, Gao M, Pan H. Superior catalytic activity derived from a two-dimensional Ti3C2 precursor towards the hydrogen storage reaction of magnesium hydride. Chem Commun. 2016;52(4):705.CrossRef
[27]
[28]
El-Eskandarany MS. Metallic glassy Zr70Ni20Pd10 powders for improving the hydrogenation/dehydrogenation behavior of MgH2. Sci Rep. 2016;6:26936.CrossRef
[29]
Shevlin SA, Guo ZX. MgH2 dehydrogenation thermodynamics: nanostructuring and transition metal doping. J Phys Chem C. 2013;117(21):10883.CrossRef
[30]
Cui C, Liu X, Wu N, Sun Y. Facile synthesis of core/shell-structured Sn/onion-like carbon nanocapsules as high-performance anode material for lithium-ion batteries. Mater Lett. 2015;143(15):35.CrossRef
[31]
An C, Liu G, Li L, Wang Y, Chen C, Wang Y, Jiao L, Yuan H. In situ synthesized one-dimensional porous Ni@C nanorods as catalysts for hydrogen storage properties of MgH2. Nanoscale. 2014;6(6):3223.CrossRef
[32]
Li Y, Zhang L, Zhang Q, Fang F, Sun D, Li K, Wang H, Ouyang LZ, Zhu M. In situ embedding of Mg2NiH4 and YH3 nanoparticles into bimetallic hydride NaMgH3 to inhibit phase segregation for enhanced hydrogen storage. J Phys Chem C. 2014;118(41):23635.CrossRef
[33]
Ding X, Li Y, Fang F, Sun D, Zhang Q. Hydrogen-induced magnesium–zirconium interfacial coupling: enabling fast hydrogen sorption at lower temperatures. J Mater Chem A. 2017;5(10):5067.CrossRef
Metadaten
Titel
Enhancing hydrogen sorption in MgH2 by controlling particle size and contact of Ni catalysts
verfasst von
Ting-Zhi Si
Xue-Yang Zhang
Jing-Jing Feng
Xiao-Li Ding
Yong-Tao Li
Publikationsdatum
04.07.2018
Verlag
Nonferrous Metals Society of China
Erschienen in
Rare Metals / Ausgabe 4/2021
Print ISSN: 1001-0521
Elektronische ISSN: 1867-7185
DOI
https://doi.org/10.1007/s12598-018-1087-x

Weitere Artikel der Ausgabe 4/2021

Rare Metals 4/2021 Zur Ausgabe

Review

Recent advance in single-atom catalysis

OriginalPaper

Surface-engineered gadolinium oxide nanorods and nanocuboids for bioimaging

Original Article

Improvement in irradiation resistance of FeCu alloy by pre-deformation through introduction of dense point defect sinks

OriginalPaper

Fabrication of nano-grained negative temperature coefficient thermistors with high electrical stability

OriginalPaper

Improving interface adhesion in TiNi wire/shape memory epoxy composites using carbon nanotubes

OriginalPaper

Partitioning behavior and lattice misfit of γ/γ′ phases in Ni-based superalloys with different Mo additions

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise