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Journal of Materials Science

Erschienen in:

01.07.2014

Ester-functionalized single-walled carbon nanotubes via addition of haloformates

verfasst von: Mustafa K. Bayazit, Karl S. Coleman

Erschienen in: Journal of Materials Science | Ausgabe 14/2014

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Abstract

Herein, a versatile method to introduce ester functional groups to the surface of single-walled carbon nanotubes (SWCNTs) was defined. Ester-modified SWCNTs were prepared via the direct reaction of haloformates with reduced SWCNTs [(nBu–SWCNT ⁿ⁻ ) Li _n ⁺ ] generated by n-butyl lithium. Ultraviolet–Visible–near infrared and Raman spectroscopy verified the evidence of covalent surface functionalization. Solubility of functionalized SWCNTs (f-SWCNTs) enhanced compared to purified SWCNTs. Gold tagging to positively charged SWCNTs displayed the presence and distribution of functional groups, confirming the conversion of esters into amides. f-SWCNTs were further characterized by thermo-gravimetric analysis coupled with mass spectrometry and fourier-transform infrared spectroscopy.

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Titel: Ester-functionalized single-walled carbon nanotubes via addition of haloformates
verfasst von: Mustafa K. Bayazit
Karl S. Coleman
Publikationsdatum: 01.07.2014
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 14/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-014-8227-y

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