nach oben

Erschienen in:

11.03.2019

Experimental evaluation of simulated moving bed reactor for transesterification reaction synthesis of glycol ether ester

verfasst von: Shan Tie, Balamurali Sreedhar, Megan Donaldson, Timothy Frank, Alfred K. Schultz, Andreas S. Bommarius, Yoshiaki Kawajiri

Erschienen in: Adsorption | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

This work presents an experimental evaluation of multi-column simulated moving bed reactor (SMBR) technology for transesterification of glycol ether ester for the first time. An industrially relevant solvent, propylene glycol methyl ether acetate (DOWANOL™ PMA) was produced using a laboratory-scale SMBR unit packed with a base catalyst. The catalyst selected in this study, a Type-II anion exchange resin, was found to be resistant to deactivation through our experimental runs. To design the SMBR process, single-column experiments were first carried out to develop a mathematical model and estimate model parameters. Using this model, the optimal SMBR process was found by a multi-objective optimization technique to maximize the productivity while achieving high conversions. The optimal operating conditions found in this manner were implemented in the lab-scale SMB unit, which achieved conversions ranging from 47.3 to 57.7%. Furthermore, using the experimental data obtained from these experimental runs, the prediction of the model was improved via Tikhonov regularization, which was successfully validated in an additional run at an even higher conversion of 74.6%.

Vorheriger Artikel Evaluation of simplified pressure swing adsorption cycles for bio-methane production

Nächster Artikel Measuring adsorption isotherms with a flowmeter and a pressure gauge

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Agrawal, G., Oh, J., Sreedhar, B., Tie, S., Donaldson, M.E., Frank, T.C., Schultz, A.K., Bommarius, A.S., Kawajiri, Y.: Optimization of reactive simulated moving bed systems with modulation of feed concentration for production of glycol ether ester. J. Chromatogr. A 1360, 196–208 (2014)CrossRefPubMed

Bentley, J., Sloan, C., Kawajiri, Y.: Simultaneous modeling and optimization of nonlinear simulated moving bed chromatography by the prediction–correction method. J. Chromatogr. A 1280, 51–63 (2013)CrossRefPubMed

Darnoko, D., Cheryan, M.: Kinetics of palm oil transesterification in a batch reactor. J. Am. Oil Chem. Soc. 77, 1263–1267 (2000)CrossRef

Fourer, R., Gay, D.M., Kernighan, W.: MPL. A Modeling Language for Mathematical Programming. Brooks/Cole Publishing Company, CA (2002)

Frank, T.C., Donaldson, M.E.: International Patent Application WO2014179706 (2016)

Fukuda, H., Kondo, A., Noda, H.: Biodiesel fuel production by transesterification of oils. J. Biosci. Bioeng. 92, 405–416 (2001)CrossRefPubMed

Geier, D., Soper, J.G.: United States Patent US 7828978B2, (2010)

Hansen, P.C., O’Leary, D.P.: The use of the L-curve in the regularization of discrete Ill-posed problems. SIAM J. Sci. Comput. 14, 1487–1503 (1993)CrossRef

He, B., Ren, Y., Cheng, Y., Li, J.: Deactivation and in situ regeneration of anion exchange resin in the continuous transesterification for biodiesel production. Energy Fuels 26, 3897–3902 (2012)CrossRef

Hsieh, C.-T., Lee, M.-J., Lin, H.: Multiphase equilibria for mixtures containing acetic acid, water, propylene glycol monomethyl ether, and propylene glycol methyl ether acetate. Ind. Eng. Chem. Res. 45, 2123–2130 (2006)CrossRef

Johnson, S.H., Wright, H.N.: United States Patent US 3700726A (1972)

Kametaka, N., Marumo, K., Tokuda, K., Sekiguchi, K.: United States Patent US 4260813A (1981)

Karayannidis, G.P., Achilias, D.S., Sideridou, I.D., Bikiaris, D.N.: Alkyd resins derived from glycolized waste poly(ethylene terephthalate). Eur. Polym. J. 41, 201–210 (2005)CrossRef

Kawajiri, Y., Biegler, L.T.: Nonlinear programming superstructure for optimal dynamic operations of simulated moving bed processes. Ind. Eng. Chem. Res. 45, 8503–8513 (2006)CrossRef

Kawase, M., Suzuki, T.B., Inoue, K., Yoshimoto, K., Hashimoto, K.: Increased esterification conversion by application of the simulated moving bed reactor. Chem. Eng. Sci. 51, 2971–2976 (1996)CrossRef

Martello, M.T., Burns, A., Hillmyer, M.: Bulk ring-opening transesterification polymerization of the renewable δ-decalactone using an organocatalyst. ACS Macro Lett 1, 131–135 (2012)CrossRef

Mazzotti, M., Neri, B., Gelosa, D., Morbidelli, M.: Dynamics of a chromatographic reactor: esterification catalyzed by acidic resins. Ind. Eng. Chem. Res. 36, 3163–3172 (1997)CrossRef

Meher, L.C., Sagar, V., Naik, D.: S.N.: Technical aspects of biodiesel production by transesterification—a review. Renew. Sust. Energ. Rev. 10, 248–268 (2006)CrossRef

Noshadi, I., Amin, N.A.S., Parnas, R.S.: Continuous production of biodiesel from waste cooking oil in a reactive distillation column catalyzed by solid heteropolyacid: optimization using response surface methodology (RSM). Fuel 94, 156–164 (2012)CrossRef

Oh, J.: Development of reactive chromatography system for equilibrium-limited reactions. Ph.D. Thesis, School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, GA, USA (2016)

Oh, J., Agrawal, G., Sreedhar, B., Donaldson, M.E., Schultz, A.K., Frank, T.C., Bommarius, A.S., Kawajiri, Y.: Conversion improvement for catalytic synthesis of propylene glycol methyl ether acetate by reactive chromatography: experiments and parameter estimation. Chem. Eng. J. 259, 397–409 (2015)CrossRef

Oh, J., Sreedhar, B., Donaldson, M.E., Frank, T.C., Schultz, A.K., Bommarius, A.S., Kawajiri, Y.: Transesterification of propylene glycol methyl ether in chromatographic reactors using anion exchange resin as a catalyst. J. Chromatogr. A 1466, 84–95 (2016)CrossRefPubMed

Pöpken, T., Steinigeweg, S., Gmehling, J.: Synthesis and hydrolysis of methyl acetate by reactive distillation using structured catalytic packings: experiments and simulation. Ind. Eng. Chem. Res. 40, 1566–1574 (2001)CrossRef

Ren, Y., He, B., Yan, F., Wang, H., Cheng, Y., Lin, L., Feng, Y., Li, J.: Continuous biodiesel production in a fixed bed reactor packed with anion-exchange resin as heterogeneous catalyst. Bioresour. Technol. 113, 19–22 (2012)CrossRefPubMed

Sainio, T., Kaspereit, M., Kienle, A., Seidel-Morgenstern, A.: Thermal effects in reactive liquid chromatography. Chem. Eng. Sci. 62, 5674–5681 (2007)CrossRef

Seidel-Morgenstern, A., Keßler, L.C., Kaspereit, M.: New Developments in simulated moving bed chromatography. Chem. Eng. Technol. 31, 826–837 (2008)CrossRef

Shibasaki-Kitakawa, N., Honda, H., Kuribayashi, H., Toda, T., Fukumura, T., Yonemoto, T.: Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst. Bioresour. Technol. 98, 416–421 (2007)CrossRefPubMed

Shuit, S.H., Lee, K.T., Kamaruddin, A.H., Yusup, S.: Reactive extraction and in situ esterification of Jatropha curcas L. seeds for the production of biodiesel. Fuel 89, 527–530 (2010)CrossRef

Steinigeweg, S., Gmehling, J.: Transesterification processes by combination of reactive distillation and pervaporation. Chem. Eng. Process. 43, 447–456 (2004)CrossRef

The Dow Chemical Company, Product Safety Assessment: Propylene Glycol Methyl Ether Acetate http://msdssearch.dow.com/PublishedLiteratureDOWCOM/dh_096d/0901b8038096dbb5.pdf?filepath=productsafety/pdfs/noreg/233-00407.pdf&fromPage=GetDoc (2017) Accessed June 30 2017

Tie, S., Sreedhar, B., Agrawal, G., Oh, J., Donaldson, M.E., Frank, T.C., Schultz, A.K., Bommarius, A.S., Kawajiri, Y.: Model-based design and experimental validation of simulated moving bed reactor for production of glycol ether ester. Chem. Eng. J. 301, 188–199 (2016)CrossRef

Tie, S., Sreedhar, B., Donaldson, M., Frank, T., Schultz, A., Bommarius, A., Kawajiri, Y.: Process integration for simulated moving bed reactor for production of glycol ether acetate. Chemical engineering processing—process intensification (in press)

Tikhonov, A., Goncharsky, A., Stepanov, V., Yagola, A.: Numerical Methods for the Solution of Ill-Posed Problems. Kluwer Academic Publishers, Boston (1995)CrossRef

Wächter, A., Biegler, L.T.: On the implementation of an interior-point filter line-search algorithm for large-scale nonlinear programming. Math. Program. 106, 25–57 (2006)CrossRef

Zakaria, R., Harvey, A.P.: Direct production of biodiesel from rapeseed by reactive extraction/in situ transesterification. Fuel Process. Technol. 102, 53–60 (2012)CrossRef

Titel: Experimental evaluation of simulated moving bed reactor for transesterification reaction synthesis of glycol ether ester
verfasst von: Shan Tie
Balamurali Sreedhar
Megan Donaldson
Timothy Frank
Alfred K. Schultz
Andreas S. Bommarius
Yoshiaki Kawajiri
Publikationsdatum: 11.03.2019
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 4/2019
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-019-00048-y

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 4/2019

Investigation of CO2 capture using acetate-based ionic liquids incorporated into exceptionally porous metal–organic frameworks

DFT investigation of metal doped graphene capacity for adsorbing of ozone, nitrogen dioxide and sulfur dioxide molecules

Impact of water activity on double layer parameters at the mercury/chlorates(VII) interface in the presence of mixed adsorption layers of 6-mercaptopurine–Triton X-100

Removing Cs within a continuous flow set-up by an ionic exchanger material transformable into a final waste form

n-Hexane conversion on γ-alumina supported palladium–platinum catalysts

Adsorption selectivity of heavy metals by Na-clinoptilolite in aqueous solutions

Premium Partner

Marktübersichten